Volumetric studies of some electrolytes in water and in aqueous sodium dodecylsulfate solutions at different temperatures

2010 ◽  
Vol 141 (10) ◽  
pp. 1063-1068 ◽  
Author(s):  
Dulal Chandra Kabiraz ◽  
Tapan Kumar Biswas ◽  
M. Entazul Huque
ChemPhysChem ◽  
2003 ◽  
Vol 4 (10) ◽  
pp. 1065-1072 ◽  
Author(s):  
Patrick Fernandez ◽  
Simon Schrödle ◽  
Richard Buchner ◽  
Werner Kunz

1990 ◽  
Vol 68 (1) ◽  
pp. 33-35 ◽  
Author(s):  
Derek G. Leaist

Ternary interdiffusion coefficients have been measured for ten compositions of the system sodium dodecylsulfate (NaDS) + 1-butanol (BuOH) + water at 25 °C. The diffusivity of BuOH in this system is lower than in pure water because about one half of the alcohol is solubilized in the slowly-diffusing NaDS micelles. Yet, surprisingly, diffusion of the NaDS component transports only minor amounts of BuOH. Diffusion of the BuOH component, however, produces a substantial coupled flow of NaDS. Although added BuOH increases the solution viscosity and the size of the micelles, the diffusivity of the NaDS component does not change significantly. The Harned restricted diffusion method for the determination of electrolyte diffusivities is extended to electrolyte + nonelectrolyte solutes. Keywords: micelles, ionic; solubilization; diffusion, coupled.


1966 ◽  
Vol 44 (4) ◽  
pp. 521-525 ◽  
Author(s):  
A. Aboul-Seoud ◽  
M. Doheim

The distribution coefficients of aniline between n-heptane and aqueous sodium nitrate solutions were measured at different temperatures. The activity coefficients of aniline in aqueous sodium nitrate solutions were determined. The effect of sodium nitrate on the dissociation of the anilinium ion was studied at different temperatures by a modified distribution method. Attention was directed to the choice of the extracting solvent and of the analytical method. The effect of the presence of undissociated anilinium ions on the distribution coefficients was taken into consideration.K0, Kb, ΔH, ΔF, and ΔS for the dissociation of the anilinium ion were evaluated.


2013 ◽  
Vol 227 (12) ◽  
Author(s):  
Parampaul Kaur Banipal ◽  
Vickramjeet Singh ◽  
Tarlok Singh Banipal ◽  
Harpreet Singh

2017 ◽  
Vol Volume-2 (Issue-1) ◽  
pp. 652-661
Author(s):  
P. seethalakshmi ◽  
K. Renuka Devi ◽  
R.Seema | J. Benazir Jiya ◽  

Sign in / Sign up

Export Citation Format

Share Document