Electrochemical study of Meldola's blue, methylene blue and toluidine blue immobilized on a SiO 2 /Sb 2 O3 binary oxide matrix obtained by the sol-gel processing method

2003 ◽  
Vol 7 (10) ◽  
pp. 665-670 ◽  
Author(s):  
E. S. Ribeiro ◽  
S. S. Rosatto ◽  
Y. Gushikem ◽  
L. T. Kubota
2005 ◽  
Vol 30 (1) ◽  
pp. 51-58 ◽  
Author(s):  
C. U. Ferreira ◽  
J. E. Gonçalves ◽  
Y. V. Kholin ◽  
Y. Gushikem

The porous mixed oxide SiO2/TiO2/Sb2O5 obtained by the sol-gel processing method presented a good ion exchange property and a high exchange capacity towards the Li+, Na+ and K+ ions. In the H+/M+ ion exchange process, the H+ / Na+ could be described as presenting an ideal character. The ion exchange equilibria of Li+ and K+ were quantitatively described with the help of the model of fixed tetradentate centers. The results of simulation evidence that for the H+ / Li+ exchange the usual situation takes place: the affinity of the material to the Li+ ions is decreased with increasing the degree of ion exchange. On the contrary, for K+ the effects of positive cooperativity, that facilitate the H+ / K+ exchange, were revealed.


2004 ◽  
Vol 177 (7) ◽  
pp. 2432-2439 ◽  
Author(s):  
Maria Suzana P Francisco ◽  
Richard Landers ◽  
Yoshitaka Gushikem

2012 ◽  
Vol 512-515 ◽  
pp. 1673-1676 ◽  
Author(s):  
Wei Zhao ◽  
Jian Jun Yao ◽  
Jing Ya ◽  
Lei E ◽  
Zhi Feng Liu ◽  
...  

A sol-gel processing technology was employed to synthesize fine SrTiO3 powder by using strontium nitrate (Sr(NO3)2) , butyl titanate (Ti(OC4H9)4) as precursors, citric acid (C6H8O6) as complexing agent and (ethylene) glycol (C2H6O2) as stabilizer. Prepared the precursors in liquid phase and then calcined the precursors to achieve nano-sized SrTiO3 powders. The microstructure and composition of the as-synthesized samples were characterized by X-ray diffraction (XRD), Scan Electron Microscopy (SEM), and the photocatalytic activity was studied. The results showed that all the SrTiO3 particles were identified as perovskite phase. The pH values, the content of the acetic acid, the heat treat temperature play important roles on the synthesis of the SrTiO3 photocatalyst. When the pH=1, n(Sr(NO3)2 ) : n(Ti(OC4H9)4) = 1 : 1, n(Sr(NO3)2 ) : n(C6H8O6)=1:1.7, the product has better rate of photodegradation for the Methylene Blue under the ultraviolet condition.


1994 ◽  
Vol 170 (3) ◽  
pp. 234-242 ◽  
Author(s):  
S. Acosta ◽  
R.J.P. Corriu ◽  
D. Leclercq ◽  
P. Lefèvre ◽  
P.H. Mutin ◽  
...  

2001 ◽  
Vol 16 (11) ◽  
pp. 3179-3183 ◽  
Author(s):  
A-D. Li ◽  
C. L. Mak ◽  
K. H. Wong ◽  
D. Wu ◽  
Naiben Ming

A novel sol-gel processing method has been developed to fabricate epitaxial (SrBa)Nb2O6 (SBN) thin films on MgO substrates. It involves the introduction of a SBN self-template layer on MgO by pulsed laser deposition (PLD). Effects of the SBN self-template layer on the structural and morphological properties of the sol-gel-derived SBN films were investigated. Compared to the sol-gel-derived SBN films without a self-template layer, our new technique produces SBN films of excellent epitaxy and more dense grains with uniform distribution. This can be explained by the self-template-layer-induced homoepitaxial growth. The innovative processing method with combination of PLD and sol-gel is a promising technique in preparing high-quality, thick epitaxial SBN films for electro-optics device applications.


2007 ◽  
Vol 32 (2) ◽  
pp. 41-45 ◽  
Author(s):  
J. E. Gonçalves ◽  
U.P. R. Filho ◽  
D.W. Franco ◽  
Y. Gushikem

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