Electrochemical deposition and characterization of iridium oxide films on Ti2AlC support for oxygen evolution reaction

Author(s):  
N. R. Elezović ◽  
P. Zabinski ◽  
U. Č. Lačnjevac ◽  
M. N. Krstajić Pajić ◽  
V. D. Jović
2005 ◽  
Vol 885 ◽  
Author(s):  
M.Z. Figueroa Torres ◽  
M. Hesiquio Garduño ◽  
E. M. Arce Estrada ◽  
J. R. Vargas García

ABSTRACTRuthenium-iridium oxide films were prepared in an horizontal hot-wall MOCVD apparatus and their electrocatalytic activity was investigated in the oxygen evolution reaction. Metal-acetylacetonates were used as precursors and oxygen as the reactant gas. Appropriate deposition conditions for obtaining bi-metallic oxide films were found to be deposition temperature (Tdep), 673 K and total pressure (Ptot), 133.32 Pa. X-Ray diffraction (XRD), Rietveld refinement and scanning electron microscopy (SEM) results demonstrated that the MOCVD method is a viable alternative to grow RuxIr1−xO2 films consisted of a single-phase with a very homogeneous distribution of elements. The electrocatalytic activity of the RuxIr1−xO2 films was investigated by cyclic voltammetry and anodic polarization curves in a 0.5 M H2SO4 solution at room temperature. The single-phase Ru0.4Ir0.6O2 films showed to be very promising for the oxygen evolution reaction due to a synergistic effect.


ACS Catalysis ◽  
2021 ◽  
pp. 10043-10057
Author(s):  
Steffen Czioska ◽  
Alexey Boubnov ◽  
Daniel Escalera-López ◽  
Janis Geppert ◽  
Alexandra Zagalskaya ◽  
...  

Author(s):  
Takahiro Naito ◽  
Tatsuya Shinagawa ◽  
Takeshi Nishimoto ◽  
Kazuhiro Takanabe

Recent spectroscopic and computational studies concerning the oxygen evolution reaction over iridium oxides are reviewed to provide the state-of-the-art understanding of its reaction mechanism.


2021 ◽  
Vol 143 (38) ◽  
pp. 15616-15623
Author(s):  
Fang Zhao ◽  
Bo Wen ◽  
Wenhan Niu ◽  
Zhu Chen ◽  
Chao Yan ◽  
...  

2018 ◽  
Vol 61 (20) ◽  
pp. 2152-2160 ◽  
Author(s):  
Kelsey A. Stoerzinger ◽  
Marco Favaro ◽  
Philip N. Ross ◽  
Zahid Hussain ◽  
Zhi Liu ◽  
...  

ChemSusChem ◽  
2018 ◽  
Vol 11 (15) ◽  
pp. 2554-2561 ◽  
Author(s):  
Carsten Walter ◽  
Prashanth W. Menezes ◽  
Stefan Loos ◽  
Holger Dau ◽  
Matthias Driess

2020 ◽  
Vol 13 (7) ◽  
pp. 2153-2166 ◽  
Author(s):  
Tobias Schuler ◽  
Taro Kimura ◽  
Thomas J. Schmidt ◽  
Felix N. Büchi

The reaction order of water and the electro-kinetic parameters are determined for the oxygen evolution reaction on iridium oxide.


2019 ◽  
Vol 9 (14) ◽  
pp. 3697-3702 ◽  
Author(s):  
Bo Jiang ◽  
Jeonghun Kim ◽  
Yanna Guo ◽  
Kevin C. W. Wu ◽  
Saad M. Alshehri ◽  
...  

Amorphous iridium oxide (IrOx) is a promising catalyst that has high activity in the oxygen evolution reaction (OER) over a broad range of pH values.


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