Characterization of organic matter in cross-margin sediment transects of an upwelling region in the Campos Basin (SW Atlantic, Brazil) using lipid biomarkers

2012 ◽  
Vol 112 (1-3) ◽  
pp. 311-327 ◽  
Author(s):  
Dulce R. P. Oliveira ◽  
Lívia G. M. S. Cordeiro ◽  
Renato S. Carreira

2016 ◽  
Vol 168 ◽  
pp. 1-9 ◽  
Author(s):  
R.S. Carreira ◽  
L.G.M.S. Cordeiro ◽  
M.C. Bernardes ◽  
V. Hatje


2010 ◽  
Vol 59 (1) ◽  
pp. 99-108 ◽  
Author(s):  
M. Takács ◽  
Gy. Füleky

The Hot Water Percolation (HWP) technique for preparing soil extracts has several advantages: it is easily carried out, fast, and several parameters can be measured from the same solution. The object of this study was to examine the possible use of HWP extracts for the characterization of soil organic matter. The HPLC-SEC chromatograms, UV-VIS and fluorescence properties of the HWP extracts were studied and the results were compared with those of the International Humic Substances Society (IHSS) Soil Humic Acid (HA), IHSS Soil Fulvic Acid (FA) and IHSS Suwannee Natural Organic Matter (NOM) standards as well as their HA counterparts isolated by traditional extraction methods from the original soil samples. The DOM of the HWP solution is probably a mixture of organic materials, which have some characteristics similar to the Soil FA fractions and NOM. The HWP extracted organic material can be studied and characterized using simple techniques, like UV-VIS and fluorescence spectroscopy.



2002 ◽  
Vol 66 (1) ◽  
pp. 129 ◽  
Author(s):  
Benny Chefetz ◽  
Jorge Tarchitzky ◽  
Ashish P. Deshmukh ◽  
Patrick G. Hatcher ◽  
Yona Chen


Agronomy ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1067
Author(s):  
Aleksandra Ukalska-Jaruga ◽  
Romualda Bejger ◽  
Guillaume Debaene ◽  
Bożena Smreczak

The objective of this paper was to investigate the molecular characterization of soil organic matter fractions (humic substances (HS): fulvic acids-FAs, humic acids-HAs, and humins-HNs), which are the most reactive soil components. A wide spectrum of spectroscopic (UV–VIS and VIS–nearIR), as well as electrochemical (zeta potential, particle size diameter, and polydispersity index), methods were applied to find the relevant differences in the behavior, formation, composition, and sorption properties of HS fractions derived from various soils. Soil material (n = 30) used for the study were sampled from the surface layer (0–30 cm) of agricultural soils. FAs and HAs were isolated by sequential extraction in alkaline and acidic solutions, according to the International Humic Substances Society method, while HNs was determined in the soil residue (after FAs and HAs extraction) by mineral fraction digestion using a 0.1M HCL/0.3M HF mixture and DMSO. Our study showed that significant differences in the molecular structures of FAs, Has, and HNs occurred. Optical analysis confirmed the lower molecular weight of FAs with high amount of lignin-like compounds and the higher weighted aliphatic–aromatic structure of HAs. The HNs were characterized by a very pronounced and strong condensed structure associated with the highest molecular weight. HAs and HNs molecules exhibited an abundance of acidic, phenolic, and amine functional groups at the aromatic ring and aliphatic chains, while FAs mainly showed the presence of methyl, methylene, ethenyl, and carboxyl reactive groups. HS was characterized by high polydispersity related with their structure. FAs were characterized by ellipsoidal shape as being associated to the long aliphatic chains, while HAs and HNs revealed a smaller particle diameter and a more spherical shape caused by the higher intermolecular forcing between the particles. The observed trends directly indicate that individual HS fractions differ in behavior, formation, composition, and sorption properties, which reflects their binding potential to other molecules depending on soil properties resulting from their type. The determined properties of individual HS fractions are presented as averaged characteristics over the examined soils with different physico-chemical properties.





Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1863
Author(s):  
Luciana Cristina de Carvalho Santa-Rosa ◽  
Sibelle Trevisan Disaró ◽  
Violeta Totah ◽  
Silvia Watanabe ◽  
Ana Tereza Bittencourt Guimarães

Living benthic foraminifera (>63 µm) were studied to characterize the continental slope of the Potiguar Basin (SW Atlantic). Foraminifers from the surface (0–2 cm), subsurface (2–5 cm), and integrated (0–5 cm) sediment layers were analyzed to verify their contribution to environmental characterization. It was also estimated if and which changes occur when the subsurface is added. Sampling stations were distributed in five transects in four isobaths (150, 400, 1000, and 2000 m). Sediment samples were fixed with 4% buffered formaldehyde and stained with Bengal rose. Were recorded 396 species in the surface layer, 228 in the subsurface, and 449 in integrating both layers. This study did not include tubular agglutinated species. The assemblages from 150 m isobath indicated the upper slope, from 400 m indicated the middle slope and the ones from the 2000 m indicated the lower slope. The surface layer’s assemblage at 1000 m isobath was more similar to the middle slope; in contrast, its subsurface layer´s assemblage had more similarity with the lower slope. Rarefaction curves, Permanova, and NMDS routines indicated a high resemblance between surface and integrated layers. Therefore, the first two centimeters were sufficient to characterize this region based on living benthic foraminifera.





2021 ◽  
Vol 238 ◽  
pp. 103714
Author(s):  
Arka Rudra ◽  
Hamed Sanei ◽  
H.P. Nytoft ◽  
H.I. Petersen ◽  
Carlette Blok ◽  
...  




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