Geochemical characterization of the organic matter in the Devonian Pimenteiras Formation, Parnaiba Basin, Brazil – Implications for depositional environment and the potential of hydrocarbon generation

2021 ◽  
Vol 201 ◽  
pp. 108461
Author(s):  
Agostinho Mussa ◽  
Wolfgang Kalkreuth ◽  
Ana Maria Pimentel Mizusaki ◽  
Marcos Müller Bicca ◽  
Jørgen A. Bojesen-Koefoed
1972 ◽  
Vol 12 (1) ◽  
pp. 125
Author(s):  
T.G. Powell ◽  
D.M. McKirdy

Australian oils are generally light by world standards. They have API gravities greater than 35°, low sulphur and asphalt contents, and are of paraffinic or naphthenic base. The geochemical similarity of oils from the Bowen-Surat Basin, with the notable exception of the Conloi crude, is most marked in the fraction boiling above 250 °C. Oils from the Cooper, Gippsland and Otway Basins are probably derived from terrestrial organic material, but differ in their degree of maturation as indicated by n-alkane patterns. Samples from the Perth Basin exhibit a similar variation in maturity. In the Carnarvon Basin, the Windalia crude differs from those in deeper reservoirs in containing a higher proportion of oxygen-bearing, nitrogen-bearing, and sulphur-bearing compounds, another sign of a less mature oil. The East Mereenie oil displays an odd-even predominance in its n-alkane distribution which is characteristic of some Lower Palaeozoic crudes. A Papuan Basin condensate is the only available sample produced from a limestone reservoir. This probably accounts for its higher sulphur content. Two seeps obtained from the Papuan Highlands are inspissated residues which may have suffered microbiological alteration.A major control of the composition of Australian crude oils appears to be the depositional environment of the source rock. Most of the oils show evidence of having been generated, at least in part, from terrestrial (as opposed to marine) organic matter. The location of all but one of the reservoirs within sequences dominated by the sandstone - shale association is consistent with the likely contribution of land plant detritus to their source environment. Likewise, low sulphur and asphalt values reflect the scarcity of favourable carbonate-evaporite source and reservoir situations in Australia.


2017 ◽  
Vol 5 (2) ◽  
pp. SF109-SF126 ◽  
Author(s):  
Yuxi Yu ◽  
Xiaorong Luo ◽  
Ming Cheng ◽  
Yuhong Lei ◽  
Xiangzeng Wang ◽  
...  

Shale oil and gas have been discovered in the lacustrine Zhangjiatan Shale in the southern Ordos Basin, China. To study the distribution of extractable organic matter (EOM) in the Zhangjiatan Shale ([Formula: see text] ranges from 1.25% to 1.28%), geochemical characterization of core samples of different lithologies, scanning electron microscope observations, low-pressure [Formula: see text] and [Formula: see text] adsorption, and helium pycnometry were conducted. The content and saturation of the EOM in the pores were quantitatively characterized. The results show that the distribution of the EOM in the shale interval is heterogeneous. In general, the shale layers have a higher EOM content and saturation than siltstone layers. The total organic content and the original storage capacity control the EOM content in the shale layers. For the siltstone layers, the EOM content is mainly determined by the original storage capacity. On average, 75% of the EOM occurs in the mesopores, followed by 14% in the macropores, and 11% in the micropores. The EOM saturation in the pores decreases with the increase in pore diameter. The distribution of EOM in the shale pores is closely related to the pore type. Micropores and mesopores developed in the kerogens and pyrobitumens and the clay-mineral pores coated with organic matter are most favorable for EOM retention and charging.


2020 ◽  
Vol 123 (4) ◽  
pp. 587-596
Author(s):  
A. Emanuel ◽  
C.H. Kasanzu ◽  
M. Kagya

Abstract Triassic to mid-Jurassic core samples of the Mandawa basin, southern Tanzania (western coast of the Indian Ocean), were geochemically analyzed in order to constrain source rock potentials and petroleum generation prospects of different stratigraphic formations within the coastal basin complex. The samples were collected from the Mihambia, Mbuo and Nondwa Formations in the basin. Geochemical characterization of source rocks intersected in exploration wells drilled between 503 to 4042 m below surface yielded highly variable organic matter contents (TOC) rated between fair and very good potential source rocks (0.5 to 8.7 wt%; mean ca. 2.3 wt%). Based on bulk geochemical data obtained in this study, the Mandawa source rocks are mainly Type I, Type II, Type III, mixed Types II/III and Type IV kerogens, with a predominance of Type II, Type III and mixed Type II/III. Based on pyrolysis data (Tmax 417 to 473oC; PI = 0.02 to 0.47; highly variable HI = 13 to 1 000 mg/gTOC; OI = 16 to 225 mg/g; and VR values of between 0.24 to 0.95% Ro) we suggest that the Triassic Mbuo Formation and possibly the mid-Jurassic Mihambia Formation have a higher potential for hydrocarbon generation than the Nondwa Formation as they are relatively thermally mature.


Author(s):  
M. Fernández ◽  
J.I. Carreto ◽  
J. Mora ◽  
A. Roux

The benthic system of the Golfo San Jorge was characterized from physico-chemical parameters based on samplings obtained during seasonal research cruises carried out on board the INIDEP vessels from springtime 1999 through wintertime 2000. Spatial and seasonal variations of temperature, salinity, density, oxygen content and chlorophyll-a in bottom water and concentration of total organic matter, total organic carbon, total nitrogen, chlorophyll-a and phaeopigments in sediments were analysed. The origin and nutritional value of the deposited organic matter were also assessed. The behaviour of the physico-chemical characteristics of the benthic habitat, studied applying statistical techniques, defined three sectors with particular characteristics and minimum seasonal variations: sector 1, the largest and deepest one, comprises the central area of the gulf and corresponds to a depositional environment; sector 2 comprises the areas next to the extremes of the gulf and corresponds to a flow or erosive environment; sector 3 includes the coastal area and south-east part of the gulf and belongs to a transitional environment.


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