Quantitatively loaded ultra-small Ag nanoparticles on molecularly imprinted mesoporous silica for highly efficient catalytic reduction process

2019 ◽  
Vol 55 (4) ◽  
pp. 1475-1488 ◽  
Author(s):  
Hang Huo ◽  
Yanqiu Jiang ◽  
Tingting Zhao ◽  
Zhe Wang ◽  
Yanjing Hu ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Ag Nanoparticles ◽  
Catalytic Reduction ◽  
Reduction Process ◽  
Molecularly Imprinted ◽  
Highly Efficient

Multiple Silver Nanoparticles Anchored Hollow Mesoporous Silica Nanospheres by Polyacrylic Acid Aggregate Templating Approach for Catalytic Reduction of p-Nitrophenol

2018 ◽  
Vol 18 (12) ◽  
pp. 8307-8312 ◽  
Author(s):  
Peng Xu ◽  
Nannan Chen ◽  
Huan Lin ◽  
Changli Cen ◽  
Zhenguo Wu ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Mesoporous Silica ◽  
Polyacrylic Acid ◽  
Ag Nanoparticles ◽  
Catalytic Reduction ◽  
Metal Catalyst ◽  
Silica Nanospheres ◽  
One Pot ◽  
Hollow Mesoporous Silica ◽  
Mesoporous Silica Nanospheres

Anchoring metal cores inside porous shells can endow metal catalyst with high selectivity and stability. Herein, multiple silver nanoparticles were successfully anchored in hollow mesoporous silica nanospheres (Ag@HMSNs) through a facile one-pot method. Polyacrylic acid aggregates self-assembled in water/ethanol solvent were used as core templates and Ag nanoparticles captors, and hexadecyl trimethoxysilane (C16TMS) was used as the pore-making agent. The hollow cavity, encapsulated multiple Ag nanoparticles, and mesoporous silica shell of the Ag@HMSNs were confirmed by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and nitrogen sorption analysis. Just as expected, Ag nanoparticles (2–5 nm) were encapsulated in the cavity of hollow mesoporous silica nanospheres with the size of about 200 nm. The fabricated Ag@HMSNs showed excellent performance for catalytic reduction of p-nitrophenol (4-NP). Also, catalytic activity of the Ag@HMSNs for 4-NP reduction was increased with the addition amount of the pore-making agents and surface areas. The superior catalytic performance was attributed to the unique structural features of Ag@HMSNs architecture, in which the mesoporous shell provided readily accessible pathway for fast transport of reactants to the encapsulated Ag nanoparticles.

Fe3O4 Nanoparticles Coated with EDTA and Ag Nanoparticles for the Catalytic Reduction of Organic Dyes from Wastewater

2019 ◽  
Vol 2 (8) ◽  
pp. 5310-5319 ◽  
Author(s):  
Hafiz Muhammad Adeel Sharif ◽  
Asif Mahmood ◽  
Hao-Yi Cheng ◽  
Ridha Djellabi ◽  
Jafar Ali ◽  
...  
Keyword(s):  
Fe3o4 Nanoparticles ◽  
Ag Nanoparticles ◽  
Catalytic Reduction ◽  
Organic Dyes

In situ controllable synthesis of graphene oxide-based ternary magnetic molecularly imprinted polymer hybrid for efficient enrichment and detection of eight microcystins

2015 ◽  
Vol 3 (45) ◽  
pp. 23042-23052 ◽  
Author(s):  
Sheng-Dong Pan ◽  
Xiao-Hong Chen ◽  
Xiao-Ping Li ◽  
Mei-Qiang Cai ◽  
Hao-Yu Shen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Molecularly Imprinted Polymer ◽  
Sensitive Detection ◽  
Imprinted Polymer ◽  
Controllable Synthesis ◽  
Molecularly Imprinted ◽  
Magnetic Molecularly Imprinted Polymer ◽  
Highly Efficient ◽  
Polymer Hybrid

A novel graphene oxide-based ternary magnetic molecularly imprinted polymer hybrid was synthesized for highly efficient enrichment and sensitive detection of microcystins.

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