scholarly journals Surface-Modified Colloid CdTe/CdS Quantum Dots by a Biocompatible Thiazolidine Derivative as Promising Platform for Immobilization of Glucose Oxidase: Application to Fluorescence Sensing of Glucose

Author(s):  
Rahman Hallaj ◽  
Zahra Hosseinchi
2021 ◽  
Author(s):  
Rahman Hallaj ◽  
Zahra Hosseinchi

Abstract This work focuses on the synthesis of novel modified core-shell CdTe/CdS quantum dots (QDs) and develops as a fluorescence sensor for glucose determination. The (E)-2,2'-(4,4'-dioxo-2,2'-dithioxo-2H,2'H-[5,5'-bithiazolylidene]-3,3'(4H,4'H)-diyl)bis(3- mercaptopropanoic acid) (DTM) as a new derivative of thiazolidine was synthesized and characterized and used to surface-modification of CdTe/CdS QDs. DTM-capped CdTe/CdS QDs used to immobilization of glucose oxidase (GOD). The intensity fluorescence emission of the CdSe/CdS-DTM/GOD is highly sensitive to the concentration of H2O2 as a byproduct of the catalytic oxidation of glucose. The experimental results showed that the quenched fluorescence was proportional to the glucose concentration within the range of 10 nM − 0.32 µM under optimized experimental conditions. The limit of detection of this system was found to be 4.3 nM. Compared with most of the existing methods, this newly developed system possesses many advantages, including simplicity, low cost, and good sensitivity.


2003 ◽  
Vol 437 (1-2) ◽  
pp. 217-222 ◽  
Author(s):  
Yong Yang ◽  
Jianlin Shi ◽  
Shugang Dai ◽  
Xueguo Zhao ◽  
Xianghua Wang

2016 ◽  
Vol 8 (14) ◽  
pp. 2967-2970 ◽  
Author(s):  
Liyun Ding ◽  
Bingyu Zhang ◽  
Chuang Xu ◽  
Jun Huang ◽  
Zhilin Xia

The core/shell quantum dots–glucose oxidase complex has been synthesized and proved as a potential fluorescence probe for glucose detection.


Author(s):  
Mingming Liu ◽  
Li Xu ◽  
Weiqing Cheng ◽  
Yu Zeng ◽  
Zhengyu Yan

Talanta ◽  
2012 ◽  
Vol 93 ◽  
pp. 398-403 ◽  
Author(s):  
Guang-Li Wang ◽  
Huan-Jun Jiao ◽  
Xiao-Ying Zhu ◽  
Yu-Ming Dong ◽  
Zai-Jun Li

2014 ◽  
Vol 50 (5) ◽  
pp. 2318-2326 ◽  
Author(s):  
Kalaiyar Swarnalatha ◽  
Alagesan Muthuvinothini

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