Two-photon absorption and third-order nonlinear optical characterization of pyrrolo-tetrathiafulvalene derivatives

2013 ◽  
Vol 46 (1) ◽  
pp. 165-170 ◽  
Author(s):  
A. Karakas ◽  
T. Dag ◽  
H. El Ouazzani ◽  
K. Sebiaai ◽  
Y. Boughaleb
1986 ◽  
Vol 4 (4) ◽  
pp. 2034-2039 ◽  
Author(s):  
D. G. Seiler ◽  
S. W. McClure ◽  
R. J. Justice ◽  
M. R. Loloee ◽  
D. A. Nelson

2002 ◽  
Vol 209 (4-6) ◽  
pp. 461-466 ◽  
Author(s):  
I. Fuks-Janczarek ◽  
J-M. Nunzi ◽  
B. Sahraoui ◽  
I.V. Kityk ◽  
J. Berdowski ◽  
...  

2008 ◽  
Vol 108 (5) ◽  
pp. 3218-3224 ◽  
Author(s):  
Seetharam Shettigar ◽  
G. Umesh ◽  
K. Chandrasekharan ◽  
Ganesh Rai ◽  
B. Kalluraya

2007 ◽  
Vol 16 (02) ◽  
pp. 247-254 ◽  
Author(s):  
ASLI KARAKAS ◽  
AYHAN ELMALI

To provide an insight into the optical limiting (OL) behavior of a series of 3 metallated 1,4,8,11,15,18,22,25-octaalkylphthalocyanines; the third-order nonlinear optical (NLO) properties, one-photon absorption (OPA) and two-photon absorption (TPA) characterizations have been theoretically investigated by means of AM1, ZINDO and configuration interaction (CI) methods. The highest values for the TPA cross-section (δ(ω)) are exhibited by derivatives metallated with indium and lead. It is also seen that the nickel-metallated compound might be a passive optical limiter of the series, indicating the weakest δ(ω) and second hyperpolarizability (γ). Our calculated results are in good agreement with the previous experimental observations on the examined molecules.


2009 ◽  
Vol 18 (01) ◽  
pp. 161-166 ◽  
Author(s):  
ALEJANDRA ORTEGA ◽  
ANA LAURA PEREZ-MARTINEZ ◽  
TAKESHI OGAWA ◽  
FRANCIS SMITH ◽  
ARDIE WALSER ◽  
...  

A highly-conjugated polar dye with three aromatic rings connected with azo groups was prepared and it was incorporated in polycinnamate. It showed a third-order nonlinear susceptibility of 8 × 10-10 esu determined by a Z-scan technique. The unpoled and poled films show the same susceptibility indicating the polymer film could not be poled. The open aperture Z-scan showed negligible two-photon absorption at 1064 nm.


Materials ◽  
2022 ◽  
Vol 15 (1) ◽  
pp. 389
Author(s):  
Aya M. Abu Baker ◽  
Ganjaboy S. Boltaev ◽  
Mazhar Iqbal ◽  
Mikhail Pylnev ◽  
Nasser M. Hamdan ◽  
...  

Mixed (FAPbI3)0.92(MAPbBr3)0.08 perovskite thin films exhibit strong nonlinear optical responses, rendering them promising candidates for applications in photonics and optical communications. In this work, we present a systematic study on the ultrafast third-order nonlinear optical processes in mixed perovskite nanocrystals (NCs) by exploring the generation of third harmonic radiation and giant two-photon absorption-based photoluminescence (PL) when excited by femtosecond laser pulses of a 1030 nm central wavelength. A comparative analysis of the coherent third harmonic generation in the thin-film-containing perovskite nanocrystals has shown a 40× enhancement of the third harmonic signal compared to the signal generated in the pure quartz substrate. The cubic dependence of the third-nonlinear optical response of the (FAPbI3)0.92(MAPbBr3)0.08 perovskites on the intensity of the driving radiation was identified using broadband 38 femtosecond driving pulses. The positive nonlinear refractive index (γ = +1.4 × 10−12 cm2·W−1) is found to play an important role in improving the phase-matching conditions of the interacting pulses by generating a strong third order harmonic. The giant two-photon absorption (TPA)-assisted PL peak was monitored and a blue shift of the PL was obtained in the higher intensity range of the laser pulses, with the absorption coefficient β estimated to be~+7.0 cm·MW−1 at a 1030 nm laser wavelength.


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