Three-way catalyst emissions control technologies for spark-ignition engines—recent trends and future developments

2007 ◽  
Vol 42-43 (1-4) ◽  
pp. 323-332 ◽  
Author(s):  
Neil R. Collins ◽  
Martyn V. Twigg
2020 ◽  
Vol 9 (1) ◽  
Author(s):  
Khaled Abouemara ◽  
Samer Fikry

This paper extensively discusses a review of the latest technologies considered to control emissions in spark-ignition engines in addition to the background and history of the industry. Moreover, the paper discusses in detail the major pollutants affecting the environment negatively, which are Carbon Monoxide (CO), Hydrocarbons (HC), Oxides of Nitrogen (NOx), Sulfur Oxides (SOx), Carbon Dioxide (CO2), and Particulates. Furthermore, the crankcase emissions, the fuel system, and the exhaust system are discussed which are considered to be the main sources of pollution coming from a conventional spark-ignition engine. Also, the major emission control technologies in spark-ignition engines among numerous methods could be shortlisted in the following factors: modifications in the engine design and operating parameters, treatment of exhaust products of combustion, and modification of the fuels. Each technology has its branches and subcategories. In this paper, mainly the most prominent, up to date, and effective technologies were reviewed and discussed, which are lean combustion, design of a muffler, automatic hot air intake system, engine compression ratio, modification of combustion chamber, modification of the fuels, treatment of exhaust products of combustion, three-way, and four-way catalytic converters, exhaust gas recirculation (EGR), total emissions control packages, pre-combustion control; (Positive Crankcase Ventilation (PCV), and valve gear design. The points covered were related but not limited to the three main categories mentioned above. Finally, a conclusion and recommendations for future work are considered.


Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 4034
Author(s):  
Paolo Iodice ◽  
Massimo Cardone

Among the alternative fuels existing for spark-ignition engines, ethanol is considered worldwide as an important renewable fuel when mixed with pure gasoline because of its favorable physicochemical properties. An in-depth and updated investigation on the issue of CO and HC engine out emissions related to use of ethanol/gasoline fuels in spark-ignition engines is therefore necessary. Starting from our experimental studies on engine out emissions of a last generation spark-ignition engine fueled with ethanol/gasoline fuels, the aim of this new investigation is to offer a complete literature review on the present state of ethanol combustion in last generation spark-ignition engines under real working conditions to clarify the possible change in CO and HC emissions. In the first section of this paper, a comparison between physicochemical properties of ethanol and gasoline is examined to assess the practicability of using ethanol as an alternative fuel for spark-ignition engines and to investigate the effect on engine out emissions and combustion efficiency. In the next section, this article focuses on the impact of ethanol/gasoline fuels on CO and HC formation. Many studies related to combustion characteristics and exhaust emissions in spark-ignition engines fueled with ethanol/gasoline fuels are thus discussed in detail. Most of these experimental investigations conclude that the addition of ethanol with gasoline fuel mixtures can really decrease the CO and HC exhaust emissions of last generation spark-ignition engines in several operating conditions.


Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 779
Author(s):  
Ashraf Elfasakhany

Biofuels are receiving increased scientific attention, and recently different biofuels have been proposed for spark ignition engines. This paper presents the state of art of using biofuels in spark ignition engines (SIE). Different biofuels, mainly ethanol, methanol, i-butanol-n-butanol, and acetone, are blended together in single dual issues and evaluated as renewables for SIE. The biofuels were compared with each other as well as with the fossil fuel in SIE. Future biofuels for SIE are highlighted. A proposed method to reduce automobile emissions and reformulate the emissions into new fuels is presented and discussed. The benefits and weaknesses of using biofuels in SIE are summarized. The study established that ethanol has several benefits as a biofuel for SIE; it enhanced engine performance and decreased pollutant emissions significantly; however, ethanol showed some drawbacks, which cause problems in cold starting conditions and, additionally, the engine may suffer from a vapor lock situation. Methanol also showed improvements in engine emissions/performance similarly to ethanol, but it is poisonous biofuel and it has some sort of incompatibility with engine materials/systems; its being miscible with water is another disadvantage. The lowest engine performance was displayed by n-butanol and i-butanol biofuels, and they also showed the greatest amount of unburned hydrocarbons (UHC) and CO emissions, but the lowest greenhouse effect. Ethanol and methanol introduced the highest engine performance, but they also showed the greatest CO2 emissions. Acetone introduced a moderate engine performance and the best/lowest CO and UHC emissions. Single biofuel blends are also compared with dual ones, and the results showed the benefits of the dual ones. The study concluded that the next generation of biofuels is expected to be dual blended biofuels. Different dual biofuel blends are also compared with each other, and the results showed that the ethanol–methanol (EM) biofuel is superior in comparison with n-butanol–i-butanol (niB) and i-butanol–ethanol (iBE).


2020 ◽  
pp. 146808742097290
Author(s):  
CP Ranasinghe ◽  
W Malalasekera

A flame front is quenched when approaching a cold wall due to excessive heat loss. Accurate computation of combustion rate in such situations requires accounting for near wall flame quenching. Combustion models, developed without considering wall effects, cannot be used for wall bounded combustion modelling, as it leads to wall flame acceleration problem. In this work, a new model was developed to estimate the near wall combustion rate, accommodating quenching effects. The developed correlation was then applied to predict the combustion in two spark ignition engines in combination with the famous Bray–Moss–Libby (BML) combustion model. BML model normally fails when applied to wall bounded combustion due to flame wall acceleration. Results show that the proposed quenching correlation has significantly improved the performance of BML model in wall bounded combustion. As a second step, in order to further enhance the performance, the BML model was modified with the use of Kolmogorov–Petrovski–Piskunov analysis and fractal theory. In which, a new dynamic formulation is proposed to evaluate the mean flame wrinkling scale, there by accounting for spatial inhomogeneity of turbulence. Results indicate that the combination of the quenching correlation and the modified BML model has been successful in eliminating wall flame acceleration problem, while accurately predicting in-cylinder pressure rise, mass burn rates and heat release rates.


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