Increased production of hydrogen with in situ CO2 capture through the process of water splitting using magnetic core/shell structures as novel photocatalysts

2020 ◽  
Vol 28 (3) ◽  
pp. 3566-3578
Author(s):  
Mohamed S.A. Darwish ◽  
Ahmed M.A. El Naggar ◽  
Asmaa S. Morshedy ◽  
Nils Haneklaus
Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2497
Author(s):  
Xinxin Long ◽  
Huanyu Chen ◽  
Tijun Huang ◽  
Yajing Zhang ◽  
Yifeng Lu ◽  
...  

A novel core-shell magnetic Prussian blue-coated Fe3O4 composites (Fe3O4@PB) were designed and synthesized by in-situ replication and controlled etching of iron oxide (Fe3O4) to eliminate Cd (II) from micro-polluted water. The core-shell structure was confirmed by TEM, and the composites were characterized by XRD and FTIR. The pore diameter distribution from BET measurement revealed the micropore-dominated structure of Fe3O4@PB. The effects of adsorbents dosage, pH, and co-existing ions were investigated. Batch results revealed that the Cd (II) adsorption was very fast initially and reached equilibrium after 4 h. A pH of 6 was favorable for Cd (II) adsorption on Fe3O4@PB. The adsorption rate reached 98.78% at an initial Cd (II) concentration of 100 μg/L. The adsorption kinetics indicated that the pseudo-first-order and Elovich models could best describe the Cd (II) adsorption onto Fe3O4@PB, indicating that the sorption of Cd (II) ions on the binding sites of Fe3O4@PB was the main rate-limiting step of adsorption. The adsorption isotherm well fitted the Freundlich model with a maximum capacity of 9.25 mg·g−1 of Cd (II). The adsorption of Cd (II) on the Fe3O4@PB was affected by co-existing ions, including Cu (II), Ni (II), and Zn (II), due to the competitive effect of the co-adsorption of Cd (II) with other co-existing ions.


2007 ◽  
Vol 52 (5) ◽  
pp. 1865-1870 ◽  
Author(s):  
Xiliang Luo ◽  
Anthony J. Killard ◽  
Aoife Morrin ◽  
Malcolm R. Smyth

2017 ◽  
Vol 12 (1) ◽  
pp. 78-86 ◽  
Author(s):  
Komail Boustani ◽  
Saber Farjami Shayesteh ◽  
Mojtaba Salouti ◽  
Atefeh Jafari ◽  
Alireza Ahadpour Shal

2020 ◽  
Vol 59 (18) ◽  
pp. 8571-8580
Author(s):  
Joseph G. Yao ◽  
Matthew E. Boot-Handford ◽  
Zili Zhang ◽  
Geoffrey C. Maitland ◽  
Paul S. Fennell

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