Effect of carrier liquid on electrorheological performance and stability of oxalate group-modified TiO2 suspensions

2017 ◽  
Vol 32 (4) ◽  
pp. 854-861 ◽  
Author(s):  
Ning Ma ◽  
Xufeng Dong
Keyword(s):  
Author(s):  
M.D. Bentzon ◽  
J. v. Wonterghem ◽  
A. Thölén

We report on the oxidation of a magnetic fluid. The oxidation results in magnetic super lattice crystals. The “atoms” are hematite (α-Fe2O3) particles with a diameter ø = 6.9 nm and they are covered with a 1-2 nm thick layer of surfactant molecules.Magnetic fluids are homogeneous suspensions of small magnetic particles in a carrier liquid. To prevent agglomeration, the particles are coated with surfactant molecules. The magnetic fluid studied in this work was produced by thermal decomposition of Fe(CO)5 in Declin (carrier liquid) in the presence of oleic acid (surfactant). The magnetic particles consist of an amorphous iron-carbon alloy. For TEM investigation a droplet of the fluid was added to benzine and a carbon film on a copper net was immersed. When exposed to air the sample starts burning. The oxidation and electron irradiation transform the magnetic particles into hematite (α-Fe2O3) particles with a median diameter ø = 6.9 nm.


1988 ◽  
Vol 11 (1) ◽  
pp. 384-391 ◽  
Author(s):  
Thomas Riede ◽  
Ernst Ulrich Schlünder

2021 ◽  
Vol 54 (3) ◽  
Author(s):  
Abdeslam Benamara ◽  
Alexandre Pierre ◽  
Abdelhak Kaci ◽  
Yannick Melinge

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 703 ◽  
Author(s):  
Chen Zheng ◽  
Qi Lei ◽  
Jia Zhao ◽  
Xiaopeng Zhao ◽  
Jianbo Yin

By using different conductivity of polyaniline as filler, a kind of poly(ionic liquid)/polyaniline composite particles was synthesized to investigate the influence of dielectric polarization rate difference between filler and matrix on the electrorheological response and flow stability of composite-based electrorheological fluids under simultaneous effect of shear and electric fields. The composite particles were prepared by a post ion-exchange procedure and then treated by ammonia or hydrazine to obtain different conductivity of polyaniline. Their electrorheological response was measured by dispersing these composite particles in insulating carrier liquid under electric fields. It showed that the composite particles treated by ammonia had the strongest electrorheological response and most stable flow behavior in a broad shear rate region from 0.5 s−1 to 1000 s−1. By using dielectric spectroscopy, it found that the enhanced electrorheological response with stable flow depended on the matching degree of the dielectric polarization rates between poly(ionic liquid) matrix and polyaniline filler. The closer their polarization rates are, the more stable the flow curves are. These results are helpful to design optimal composite-based electrorheological materials with enhanced and stable ER performance.


2007 ◽  
Vol 334-335 ◽  
pp. 193-196
Author(s):  
Jae Lim You ◽  
B.J. Park ◽  
I.B. Jang ◽  
Hyoung Jin Choi

To enhance dispersion stability of magnetorheological (MR) fluids, hybrid magnetic particles of carbonyl iron (CI)/ poly(vinyl butyral) (PVB) with core/shell microstrcutre (CI-PVB) were prepared, since pure magnetic CI based MR fluid systems show severe sedimentation of the CI particles due to the large density mismatch with the carrier liquid and difficulties in redispersion after caking. The composite particles of CI-PVB have a lower density than that of the pure CI particles, while exhibiting almost original magnetic property of the CI. Both CI and CI-PVB particles were dispersed in mineral oil (20 vol%) and their MR characteristics were examined via a rotational rheometer with a magnetic field supplier. Various characterizations of the CI-PVB particles were performed via SEM, TEM and FT-IR. Both yield stress and flow curve of shear stress as a function of shear rate of the MR fluids were investigated under applied magnetic field strengths.


2010 ◽  
Vol 455 ◽  
pp. 161-164
Author(s):  
W.D. Li ◽  
Ming Lv ◽  
Sheng Qiang Yang

Fluid magnetic abrasivetool(FMA) is one kind of latest finishing abrasivetool which is a sort of suspended fluid composed by magnetic particles, nonmagnetic abrasive particles, surfactants in a non-magnetizable carrier liquid. After a period of working time, the performance-life of the abrasivetool ended because of the cutting- blade of the abrasives particles being passive. While the most costly component- the magnetic particles (carbonyl iron particles) can be reused. This paper has made up two recovery flows to separated carbonyl iron particles from others.


2010 ◽  
Vol 288 (18) ◽  
pp. 1739-1744 ◽  
Author(s):  
Fenghua Liu ◽  
Gaojie Xu ◽  
Jinghua Wu ◽  
Yuchuan Cheng ◽  
Jianjun Guo ◽  
...  

Author(s):  
Huanwu Sun ◽  
Shichun Yang

The fluid magnetic abrasive (FMA) is a new type of precision finishing abrasives, which is typically prepared by dispersing the magnetic particles, nonmagnetic abrasives, surfactants in a non-magnetizable carrier liquid. As the functional particles, the characteristics of magnetic particles have a great impact on the properties of FMA. In our experiment, the micron-sized carbonyl-iron (CI) particles (typical size: 3 μm–5 μm) are found to be ideally suited for the preparation of FMA. In this paper, the selections of micron-sized carbonyl-iron particles suitable for the FMA, the preparation techniques, the finishing mechanism and finishing process are presented. Some key parameters of FMA that may affect the finishing efficiency and the final surface roughness are analyzed theoretically. The experimental results are discussed as well in this paper.


1956 ◽  
Vol 60 (548) ◽  
pp. 543-544
Author(s):  
R. J. Stalker

The “ China-Film ” technique was developed by Murphy and Phinney from the “ China Clay” technique for indicating transition originated by Richards and Burstall. It consists in applying a suspension of china clay in a volatile liquid to a surface subsequently subjected to air flow. Not only is transition indicated, but when all the liquid has evaporated, the china clay remains deposited on the surface in patterns which may be interpreted to yield information on the direction of air flow near the surface and the incidence of shocks thereon.Experiments were carried out, at supersonic and subsonic air speeds, to determine the process by which the patterns form and to establish the aerodynamic meaning of the “ flow lines ” of the pattern. The influence of the viscosity of the carrier liquid was also studied. Indications of flow direction were found to be unreliable near a trailing edge, on a vertical surface at low speeds and in regions where the surface shear stress is only of the same order of magnitude as the product of pressure gradient and film thickness.


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