Correlation of Rheological Properties of Ferrofluid-Based Magnetorheological Fluids Using Some Dimensionless Numbers Defined in Magnetorheology

In this paper we investigated from rheological point of view some samples of ferrofluid-based magnetorheological fluids (FF-MRFs) with different volumic fractions of Fe microparticles, but with the same ferrofluid used as carrier liquid. We correlated the dimensionless flow curves, measured at different values of the magnetic field induction, using either Mason number or Casson number. It has been shown that in this approach, data sets measured under different conditions collapse on a single curve. This master curve is useful for controlling the concentration of Fe particles, so that the magnetic and magnetorheological properties of FF-MRF to be adapted to obtain high-performance applications.

Numerical Modelling of Heat Transfer in Fine Dispersive Slurry Flow

Slurry flows commonly appear in the transport of minerals from a mine to the processing site or from the deep ocean to the surface level. The process of heat transfer in solid–liquid flow is especially important for the long pipeline distance. The paper is focused on the numerical modelling and simulation of heat transfer in a fine dispersive slurry, which exhibits yield stress and damping of turbulence. The Bingham rheological model and the apparent viscosity concept were applied. The physical model was formulated and then the mathematical model, which constitutes conservative equations based on the time average approach for mass, momentum, and internal energy. The slurry flow in a pipeline is turbulent and fully developed hydrodynamically and thermally. The closure problem was solved by taking into account the Boussinesque hypothesis and a suitable turbulence model, which includes the influence of the yield shear stress on the wall damping function. The objective of the paper is to develop a new correlation of the Nusselt number for turbulent flow of fine dispersive slurry that exhibits yield stress and damping of turbulence. Simulations were performed for turbulent slurry flow, for solid volume concentrations 10%, 20%, 30%, and for water. The mathematical model for heat transfer of the carrier liquid flow has been validated. The study confirmed that the slurry velocity profiles are substantially different from those of the carrier liquid and have a significant effect on the heat transfer process. The highest rate of decrease in the Nusselt number is for low solid concentrations, while for C > 10% the decrease in the Nusselt number is gradual. A new correlation for the Nusselt number is proposed, which includes the Reynolds and Prandtl numbers, the dimensionless yield shear stress, and solid concentration. The new Nusselt number is in good agreement with the numerical predictions and the highest relative error was obtained for C = 10% and Nu = 44.3 and is equal to −12%. Results of the simulations are discussed. Conclusions and recommendations for further research are formulated.

Structure and dynamics of small-scale turbulence in vaporizing two-phase flows

Improving our fundamental understanding of multiphase turbulent flows will be beneficial for analyses of a wide range of industrial and geophysical processes. Herein, we investigate the topology of the local flow in vaporizing forced homogeneous isotropic turbulent two-phase flows. The invariants of the velocity-gradient, rate-of-strain, rate-of-rotation tensors, and scalar gradient were computed and conditioned for different distances from the liquid–gas surface. A Schur decomposition of the velocity gradient tensor into a normal and non-normal parts was undertaken to supplement the classical double decomposition into rotation and strain tensors. Using direct numerical simulations results, we show that the joint probability density functions of the second and third invariants have classical shapes in all carrier-gas regions but gradually change as they approach the carrier-liquid interface. Near the carrier-liquid interface, the distributions of the invariants are remarkably similar to those found in the viscous sublayer of turbulent wall-bounded flows. Furthermore, the alignment of both vorticity and scalar gradient with the strain-rate field changes spatially such that its universal behaviour occurs far from the liquid–gas interface. We found also that the non-normal effects of the velocity gradient tensor play a crucial role in explaining the preferred alignment.

Physical impact of thermo-diffusion and diffusion-thermo on Marangoni convective flow of hybrid nanofluid (MnZiFe2O4–NiZnFe2O4–H2O) with nonlinear heat source/sink and radiative heat flux

The objective of this study is to illustrate the influence of Marangoni convection, nonlinear heat sink/source, thermal radiation, viscous dissipation, activation energy, Soret and Dufour effects on magnetohydrodynamics flow of nanofluid generated by rotating disk. Further, the entropy generation equation is derived as a function of velocity, concentration, and thermal gradients. The governing equations of the model along with associated boundary constraints are reduced to ordinary differential equations by adopting suitable similarity transformation. Later, these equations are tackled numerically by means of shooting technique. The whole examination is performed by using two distinctive nanoparticles of ferrites in particular, manganese zinc ferrite (MnZnFe2O4) and nickel zinc ferrite (NiZnFe2O4) in a carrier liquid [Formula: see text]. The physical characteristics of velocity, thermal, concentration entropy generation, skin friction, and Nusselt number against numerous pertinent parameters are discussed in detail and deliberated graphically. Result reveals that thermal gradient shows substantial enhancement for advanced values of heat sink/source parameter. The entropy production increases with an augmentation in the Brinkman number and Marangoni ratio values. The escalation in Marangoni ratio and Dufour number improves the rate of heat transference.

Modular Type III Porous Liquids based on Porous Organic Cage Microparticles

The dispersion of particulate porous solids in size-excluded liquids has emerged as a method to create Type III porous liquids, mostly using insoluble microporous materials such as metal-organic frameworks (MOFs) and zeolites. Here, we present the first examples of Type III porous liquids based on porous organic cages (POCs). By exploiting the solution processability of the POCs, racemic and quasiracemic cage microparticles were formed by chiral recognition. Dispersion of these porous microparticles in a range of size-excluded liquids, including oils and ionic liquids, formed stable POC-based Type III porous liquids. The flexible pairing between the solid POC particles and a carrier liquid allows the formation of a range of compositions, pore sizes, and other physicochemical properties to suit different applications and operating conditions. For example, we show that it is possible to produce porous liquids with relatively low viscosities (7-14 mpa∙s) or high thermal stability (325 °C). A 12.5 wt. % Type III porous liquid comprising racemic POC microparticles and an ionic liquid, [BPy][NTf₂], shows a CO₂ working capacity (104.30 μmol/g_L) that is significantly higher than the neat ionic liquid (37.27 μmol/g_L) between 25 °C and 100 °C. This liquid is colloidally stable and can be recycled at least 10 times without loss of CO₂ capacity.

Modular Type III Porous Liquids based on Porous Organic Cage Microparticles

The dispersion of particulate porous solids in size-excluded liquids has emerged as a method to create Type III porous liquids, mostly using insoluble microporous materials such as metal-organic frameworks (MOFs) and zeolites. Here, we present the first examples of Type III porous liquids based on porous organic cages (POCs). By exploiting the solution processability of the POCs, racemic and quasiracemic cage microparticles were formed by chiral recognition. Dispersion of these porous microparticles in a range of size-excluded liquids, including oils and ionic liquids, formed stable POC-based Type III porous liquids. The flexible pairing between the solid POC particles and a carrier liquid allows the formation of a range of compositions, pore sizes, and other physicochemical properties to suit different applications and operating conditions. For example, we show that it is possible to produce porous liquids with relatively low viscosities (7-14 mpa∙s) or high thermal stability (325 °C). A 12.5 wt. % Type III porous liquid comprising racemic POC microparticles and an ionic liquid, [BPy][NTf₂], shows a CO₂ working capacity (104.30 μmol/g_L) that is significantly higher than the neat ionic liquid (37.27 μmol/g_L) between 25 °C and 100 °C. This liquid is colloidally stable and can be recycled at least 10 times without loss of CO₂ capacity.

Modular Type III Porous Liquids based on Porous Organic Cage Microparticles

The dispersion of particulate porous solids in size-excluded liquids has emerged as a method to create Type III porous liquids, mostly using insoluble microporous materials such as metal-organic frameworks (MOFs) and zeolites. Here, we present the first examples of Type III porous liquids based on porous organic cages (POCs). By exploiting the solution processability of the POCs, racemic and quasiracemic cage microparticles were formed by chiral recognition. Dispersion of these porous microparticles in a range of size-excluded liquids, including oils and ionic liquids, formed stable POC-based Type III porous liquids. The flexible pairing between the solid POC particles and a carrier liquid allows the formation of a range of compositions, pore sizes, and other physicochemical properties to suit different applications and operating conditions. For example, we show that it is possible to produce porous liquids with relatively low viscosities (7-14 mpa∙s) or high thermal stability (325 °C). A 12.5 wt. % Type III porous liquid comprising racemic POC microparticles and an ionic liquid, [BPy][NTf₂], shows a CO₂ working capacity (104.30 μmol/g_L) that is significantly higher than the neat ionic liquid (37.27 μmol/g_L) between 25 °C and 100 °C. This liquid is colloidally stable and can be recycled at least 10 times without loss of CO₂ capacity.

Mathematical Analysis of Two Phase Saturated Nanofluid Influenced by Magnetic Field Gradient

Nanofluids are composed of nano-sized particles dispersed in a carrier liquid. The present investigation’s aim is to examine theoretically the magneto-thermomechanical coupling phenomena of a heated nanofluid on a stretched surface in the presence of magnetic dipole impact. Fourier’s law of heat conduction is used to evaluate the heat transmission rate of the carrier fluids ethylene glycol and water along with suspended nanoparticles of a cobalt–chromium–tungsten–nickel alloy and magnetite ferrite. A set of partial differential equations is transformed into a set of non-linear ordinary differential equations via a similarity approach. The computation is performed in Matlab by employing the shooting technique. The effect of the magneto-thermomechanical interaction on the velocity and temperature boundary layer profiles with the attendant effect on the skin friction and heat transfer is analyzed. The maximum and minimum thermal energy transfer rates are computed for the H2O-Fe3O4 and C2H6O2-CoCr20W15Ni magnetic nanofluids. Finally, the study’s results are compared with the previously available data and are found to be in good agreement.