Structure Transition Mechanism in Undercooled CuNi Alloys

2021 ◽  
Vol 36 (6) ◽  
pp. 880-883
Author(s):  
Hongen An ◽  
Nancy Julius Siambun ◽  
Bih-Lii Chuab ◽  
Melvin Gan Jet Hong ◽  
Hongtao Li
Author(s):  
Wai-Kee Li ◽  
Hung Kay Lee ◽  
Dennis Kee Pui Ng ◽  
Yu-San Cheung ◽  
Kendrew Kin Wah Mak ◽  
...  

The First Edition of this book, which appeared in 2013, serves as a problem text for Part I (Fundamentals of Chemical Bonding) and Part II (Symmetry in Chemistry) of the book Advanced Structural Inorganic Chemistry published by Oxford University Press in 2008. A Chinese edition was published by Peking University Press in August in the same year. Since then the authors have received much feedback from users and reviewers, which prompted them to prepare a Second Edition for students ranging from freshmen to senior undergraduates who aspire to attend graduate school after finishing their first degree in Chemistry. Four new chapters are added to this expanded Second Edition, which now contains over 400 problems and their solutions. The topics covered in 13 chapters follow the sequence: electronic states and configurations of atoms and molecules, introductory quantum chemistry, atomic orbitals, hybrid orbitals, molecular symmetry, molecular geometry and bonding, crystal field theory, molecular orbital theory, vibrational spectroscopy, crystal structure, transition metal chemistry, metal clusters: bonding and reactivity, and bioinorganic chemistry. The problems collected in this volume originate from examination papers and take-home assignments that have been part of the teaching program conducted by senior authors at The Chinese University of Hong Kong over nearly a half-century. Whenever appropriate, source references in the chemical literature are given for readers who wish to delve deeper into the subject. Eight Appendices and a Bibliography listing 157 reference books are provided to students and teachers who wish to look up comprehensive presentations of specific topics.


Reactions ◽  
2021 ◽  
Vol 2 (3) ◽  
pp. 227-257
Author(s):  
Arash Yahyazadeh ◽  
Ajay K. Dalai ◽  
Wenping Ma ◽  
Lifeng Zhang

Light olefins as one the most important building blocks in chemical industry can be produced via Fischer–Tropsch synthesis (FTS) from syngas. FT synthesis conducted at high temperature would lead to light paraffins, carbon dioxide, methane, and C5+ longer chain hydrocarbons. The present work focuses on providing a critical review on the light olefin production using Fischer–Tropsch synthesis. The effects of metals, promoters and supports as the most influential parameters on the catalytic performance of catalysts are discussed meticulously. Fe and Co as the main active metals in FT catalysts are investigated in terms of pore size, crystal size, and crystal phase for obtaining desirable light olefin selectivity. Larger pore size of Fe-based catalysts is suggested to increase olefin selectivity via suppressing 1-olefin readsorption and secondary reactions. Iron carbide as the most probable phase of Fe-based catalysts is proposed for light olefin generation via FTS. Smaller crystal size of Co active metal leads to higher olefin selectivity. Hexagonal close-packed (HCP) structure of Co has higher FTS activity than face-centered cubic (FCC) structure. Transition from Co to Co3C is mainly proposed for formation of light olefins over Co-based catalysts. Moreover, various catalysts’ deactivation routes are reviewed. Additionally, techno-economic assessment of FTS plants in terms of different costs including capital expenditure and minimum fuel selling price are presented based on the most recent literature. Finally, the potential for global environmental impacts associated with FTS plants including atmospheric and toxicological impacts is considered via lifecycle assessment (LCA).


2020 ◽  
Vol 30 (11) ◽  
pp. 1825-1848
Author(s):  
Yannan Zhou ◽  
Yu Yang ◽  
Zhouying Song ◽  
Ze He ◽  
Siyou Xia ◽  
...  

Land ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 41
Author(s):  
Yi Lou ◽  
Guanyi Yin ◽  
Yue Xin ◽  
Shuai Xie ◽  
Guanghao Li ◽  
...  

In the rapid process of urbanization in China, arable land resources are faced with dual challenges in terms of quantity and quality. Starting with the change in the coupling coordination relationship between the input and output on arable land, this study applies an evaluation model of the degree of coupling coordination between the input and output (D_CCIO) on arable land and deeply analyzes the recessive transition mechanism and internal differences in arable land use modes in 31 provinces on mainland China. The results show that the total amount and the amount per unit area of the input and output on arable land in China have presented different spatio-temporal trends, along with the mismatched movement of the spatial barycenter. Although the D_CCIO on arable land increases slowly as a whole, 31 provinces show different recessive transition mechanisms of arable land use, which is hidden in the internal changes in the input–output structure. The results of this study highlight the different recessive transition patterns of arable land use in different provinces of China, which points to the outlook for higher technical input, optimized planting structure, and the coordination of human-land relationships.


Author(s):  
Joseph Najnudel ◽  
Bálint Virág

AbstractThe bead process introduced by Boutillier is a countable interlacing of the $${\text {Sine}}_2$$ Sine 2 point processes. We construct the bead process for general $${\text {Sine}}_{\beta }$$ Sine β processes as an infinite dimensional Markov chain whose transition mechanism is explicitly described. We show that this process is the microscopic scaling limit in the bulk of the Hermite $$\beta $$ β corner process introduced by Gorin and Shkolnikov, generalizing the process of the minors of the Gaussian Unitary and Orthogonal Ensembles. In order to prove our results, we use bounds on the variance of the point counting of the circular and the Gaussian beta ensembles, proven in a companion paper (Najnudel and Virág in Some estimates on the point counting of the Circular and the Gaussian Beta Ensemble, 2019).


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