Corrosion and Wear Properties of Zn-Based Composite Coatings

2020 ◽  
Vol 29 (8) ◽  
pp. 5360-5365
Author(s):  
Ion-Dragos Utu ◽  
Roxana Muntean ◽  
Ion Mitelea
2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
M. Darabara ◽  
L. Bourithis ◽  
S. Diplas ◽  
G. D. Papadimitriou

Titanium diboride (TiB2) and titanium carbonitride (Ti(C,N)) coatings are widely used as reinforcing materials in applications demanding high corrosion and wear resistance. In this paper, plain carbon steel has been surface alloyed with TiB2 by plasma transferred arc (PTA) technique using two different gas atmospheres. The first metal matrix composite (MMC) is produced with TiB2 particles and argon as shielding and plasma gas. In addition, a mixture of Ar and 5% N2 was used as shielding and plasma gas for producing of second MMC coating. The microstructure of both alloyed layers consists of primary titanium boride particles surrounded by a eutectic matrix, containing ferrite, eutectic boride, and titanium carbonitrides. The presence of these carbonitrides is more intense in the case of the N-enriched alloyed layer, as it was also proved via X-ray Diffraction. The alloyed layers are susceptible to pitting corrosion in 3.5% NaCl or 1 N H2SO4. The alloyed layer produced with nitrogen mixture gas is slightly more noble than the one produced with pure Ar. The metallic-ferritic matrix corrodes in 6% FeCl3∗6H2O leaving TiB2 particles protruding from the matrix. The wear performance of both TiB2 MMC depends on the counterbody (tool steel or alumina ball).


2016 ◽  
Vol 24 (05) ◽  
pp. 1750066 ◽  
Author(s):  
HAMED RAHMANI ◽  
MAHMOOD ALIOFKHAZRAEI ◽  
ABDOSSALAM KARIMZADEH

Nanocomposite Ni–Zn coatings containing 80 wt.% Al2O3, 5 wt.% Y2O3 and 15 wt.% graphene were fabricated by pulsed electrodeposition method in nickel–zinc sulphate-based electrolyte and effects of pulse current parameters on nickel and other element contents, microstructure, resistance to corrosion and tribological properties of the coatings were investigated. The pulsed current with duty cycle from 10% to 50% was applied to different samples and frequency changed gradually from 500 to 4000[Formula: see text]Hz in five steps during coating process. Increasing the duty cycle led to decrease of absorbed nanoparticles in the surface of the coatings from 4.4 vol% to 3.58 vol% The sample coated with 10% duty cycle had utmost alumina content in the coating surface, 3.5 vol% in first layer up to 4.4 vol% in fifth layer. The sample coated with 30% duty cycle had higher corrosion resistance with passive current density of 2.5[Formula: see text]mA/cm2. Furthermore, the results showed that by increasing the duty cycle, wear rate had been increased up to 1.3[Formula: see text][Formula: see text][Formula: see text]10[Formula: see text][Formula: see text]mm2/N[Formula: see text]m.


2021 ◽  
Vol 63 (7) ◽  
pp. 630-638
Author(s):  
Mustafa Kaptanoglu ◽  
Mehmet Eroglu

Abstract In the study for this contribution, production of in situ synthesized TiB2 particles in iron-based composite coatings using four different submerged arc welding powders (fluxes) containing increasing amounts of ferrotitanium and ferroboron with S1 welding wire, were targeted. For this purpose, coating deposition was carried out to improve the hardness and wear properties of the AISI 1020 steel surfaces using hybrid submerged arc welding. In hybrid submerged arc welding, the welding pool is protected by both welding powders and an argon gas atmosphere. To examine the composite coatings, visual, chemical, microstructural analyses and hardness and wear tests were carried out. With the use of increasing amounts of ferrotitanium and ferroboron in the welding powders, it was observed that the microstructure of the coatings changed in terms of TiB2 particle geometries such as rectangular and hexagonal; volume fractions of TiB2 particles in the coating microstructures increased; hardness values of coatings were enhanced from 34 HRC to 41 HRC; the wear resistance of the coatings improved, and worn surface images of the coatings caused by the counter body changed from continuous with deep scratches to discontinuous with fine scratches and crater cavities.


2017 ◽  
Vol 32 (19) ◽  
pp. 3732-3743
Author(s):  
Karuna Ratnakaran Athul ◽  
Amirthalingam Srinivasan ◽  
Uma Thanu Subramonia Pillai

Abstract


2008 ◽  
Vol 368-372 ◽  
pp. 1194-1197 ◽  
Author(s):  
Chen Ma ◽  
Ying Hui Wang ◽  
Mu Qin Li ◽  
Li Jie Qu

Rare earth/calcium phosphate composite coatings were fabricated on the surface of Ti-6Al-4V by micro-arc oxidation (MAO) technique. The wear properties and corrosion resistant of rare earth/ calcium phosphate composite coatings in the simulated body fluid (SBF) have been investigated and the bioactivity of the composite coatings were evaluated. The results show that the friction coefficient of the composite coatings in the SBF is only 0.15~0.18 and the anode polarization potential of the coating has been obviously enhanced about 0.18V compared with that of coatings of calcium phosphate coatings. So the composite coatings have excellent wear and corrosion resistant properties. XRD analysis indicates that the composite coatings can induce hydroxyapatite to form on its surface after soaked in SBF for 9d, which shows that the composite coatings own good bioactivity.


2021 ◽  
Author(s):  
Linlin ZHANG ◽  
Dawei ZHANG

Ni-Co-W composite coatings modified by different contents of Co-based alloy powder in the Ni-based alloy with 35 wt.% WC (Ni35WC) were deposited on stainless steel by laser cladding. The influence of compositional and microstructural modification on the wear properties has been comparatively investigated by XRD, SEM, and EDS techniques. It was found that the austenite dendrites in the modified coating adding 50 wt.% Co-based alloy were refined and a lot of Cr23C6 or M23(C, B)6 compounds with fine lamellar feature were formed around austenitic grain boundaries or in the intergranular regions. The contribution of element Co to the modification of Ni35WC coating is that it cannot only promote the formation of more hard compounds to refine austenite grains, but also refine the size of precipitates, and change the phase type of eutectic structure as a result of disappeared Cr boride brittle phases. A noticeable improvement in wear resistance is obtained in the Ni35WC coating with 50 wt.% Co-based alloy, which makes the wear rate decreased by about 53 % and 30% by comparison to that of the substrate and the Ni35WC coating, respectively. It is suggested that the improvement is closely related to the composite coating being strengthened owing to the increase of coating hardness, formation of a fine-grained microstructure caused by Co, and fine hard precipitate phases in the eutectic structure.


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