Synthesis of hollow Prussian blue cubes as an electrocatalyst for the reduction of hydrogen peroxide

2017 ◽  
Vol 11 (2) ◽  
pp. 147-154 ◽  
Author(s):  
Qinglin Sheng ◽  
Dan Zhang ◽  
Yu Shen ◽  
Jianbin Zheng
2013 ◽  
Vol 4 ◽  
pp. 649-654 ◽  
Author(s):  
Maria A Komkova ◽  
Angelika Holzinger ◽  
Andreas Hartmann ◽  
Alexei R Khokhlov ◽  
Christine Kranz ◽  
...  

We report here a way for improving the stability of ultramicroelectrodes (UME) based on hexacyanoferrate-modified metals for the detection of hydrogen peroxide. The most stable sensors were obtained by electrochemical deposition of six layers of hexacyanoferrates (HCF), more specifically, an alternating pattern of three layers of Prussian Blue and three layers of Ni–HCF. The microelectrodes modified with mixed layers were continuously monitored in 1 mM hydrogen peroxide and proved to be stable for more than 5 h under these conditions. The mixed layer microelectrodes exhibited a stability which is five times as high as the stability of conventional Prussian Blue-modified UMEs. The sensitivity of the mixed layer sensor was 0.32 A·M−1·cm−2, and the detection limit was 10 µM. The mixed layer-based UMEs were used as sensors in scanning electrochemical microscopy (SECM) experiments for imaging of hydrogen peroxide evolution.


2020 ◽  
Vol 59 (35) ◽  
pp. 15556-15564
Author(s):  
Ying He ◽  
Xitong Zhou ◽  
Liya Zhou ◽  
Xiaoning Zhang ◽  
Li Ma ◽  
...  

RSC Advances ◽  
2013 ◽  
Vol 3 (36) ◽  
pp. 15987 ◽  
Author(s):  
Pengjuan Ni ◽  
Yue Zhang ◽  
Yujing Sun ◽  
Yan Shi ◽  
Haichao Dai ◽  
...  

2011 ◽  
Vol 19 (7) ◽  
pp. 673-678 ◽  
Author(s):  
Meng Lin ◽  
Jiao Yang ◽  
Misuk Cho ◽  
Youngkwan Lee

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