Enhanced corrosion resistance and weathering resistance of waterborne epoxy coatings with polyetheramine-functionalized graphene oxide

2019 ◽  
Vol 17 (1) ◽  
pp. 171-180 ◽  
Author(s):  
Jing Li ◽  
Wenwen Shan ◽  
Jincan Cui ◽  
Hanxun Qiu ◽  
Guangzhi Yang ◽  
...  
Coatings ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 844 ◽  
Author(s):  
Xuepei Miao ◽  
An Xing ◽  
Lifan He ◽  
Yan Meng ◽  
Xiaoyu Li

In this paper, hyperbranched polyether functionalized graphene oxide (EHBPE-GO) was prepared by a facile one-step method. Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), thermogravimetric analyzer (TGA), and trans-mission electron microscopy (TEM) results confirmed the formation of EHBPE-GO. Then, EHBPE-GO was cured with phenolic amides at room temperature to prepare epoxy coatings. The corrosion resistance of epoxy coatings was investigated systematically by using electrochemical and traditional immersion methods. Results show that a small amount of EHBPE-GO (8 wt % of Diglycidyl ether of bisphenol A (DGEBA)) in epoxy coating achieves 50% higher improvement in acid-resistance than unmodified neat DGEBA resin. For the nanocomposite epoxy coating, the superior acid-resistance is attributed to the increased crosslink density and the impermeable 2D structure of EHBPE-GO. This work provides a facile strategy to develop the effective improved corrosion resistance nanofiller for epoxy coating.


2020 ◽  
Vol 383 ◽  
pp. 125227 ◽  
Author(s):  
Yuqin Tian ◽  
Yuhui Xie ◽  
Fei Dai ◽  
Haowei Huang ◽  
Li Zhong ◽  
...  

2014 ◽  
Vol 293 ◽  
pp. 124-131 ◽  
Author(s):  
Mohana Marimuthu ◽  
Murugan Veerapandian ◽  
Subramaniyan Ramasundaram ◽  
Seok Won Hong ◽  
P. Sudhagar ◽  
...  

Coatings ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 46 ◽  
Author(s):  
Chunling Zhang ◽  
Xueyan Dai ◽  
Yingnan Wang ◽  
Guoen Sun ◽  
Peihong Li ◽  
...  

Improving the corrosion resistance of epoxy resin coatings has become the focus of current research. This study focuses on synthesizing a functionalized silane coupling agent (2-(3,4-epoxycyclohexyl)ethyl triethoxysilane) to modify the surface of graphene oxide to address nanomaterial agglomeration and enhance the coating resistance of the epoxy resin coating to corrosion by filling the coating with functionalized graphene oxide. Functionalized graphene oxide and coatings filled with functionalized graphene oxide were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy. The corrosion performance of each coating was studied by electrochemical impedance spectroscopy and a salt spray test. Results showed that the incorporation of functionalized graphene oxide enhances the corrosion protection performance of the epoxy composite coating, and the composite coating exhibited the best anticorrosion performance when the amount of functionalized graphene oxide was 0.7 wt %.


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