Design of fluorinated hyperbranched polyether copolymers for 19F MRI nanotheranostics

19F MRI contrast agents and drug nanocarriers based on fluorinated hyperbranched polyether copolymers.

One-Step Preparation of Hyperbranched Polyether Functionalized Graphene Oxide for Improved Corrosion Resistance of Epoxy Coatings

In this paper, hyperbranched polyether functionalized graphene oxide (EHBPE-GO) was prepared by a facile one-step method. Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), thermogravimetric analyzer (TGA), and trans-mission electron microscopy (TEM) results confirmed the formation of EHBPE-GO. Then, EHBPE-GO was cured with phenolic amides at room temperature to prepare epoxy coatings. The corrosion resistance of epoxy coatings was investigated systematically by using electrochemical and traditional immersion methods. Results show that a small amount of EHBPE-GO (8 wt % of Diglycidyl ether of bisphenol A (DGEBA)) in epoxy coating achieves 50% higher improvement in acid-resistance than unmodified neat DGEBA resin. For the nanocomposite epoxy coating, the superior acid-resistance is attributed to the increased crosslink density and the impermeable 2D structure of EHBPE-GO. This work provides a facile strategy to develop the effective improved corrosion resistance nanofiller for epoxy coating.

Synthesis of Novel pH-Tunable Thermoresponsive Hydroxyl-Terminated Hyperbranched Polyether

In this study, a new pH-tunable thermoresponsive hydroxyl-terminated hyperbranched polyether (HTHP 2) was successfully prepared via a one-pot cationic polymerization technique and postmodification. In the first step, hydroxyl-terminated hyperbranched polyether containing double bonds (HTHP 1) were synthesized. Then, through thiol-ene “click” reaction, pH-responsive carboxyl groups were introduced to the target polymer of HTHP 2. The products were characterized via Fourier-transform infrared spectra (FTIR), nuclear magnetic resonance (NMR), and size-exclusion chromatography-multiangle laser light scattering (SEC-MALLS). Moreover, dynamic light scattering (DLS) and UV–Vis spectroscopy was employed to study the pH- and thermoresponsiveness in detail. Results showed that HTHP 2 possessed typical pH-controllable thermoresponsive behavior. By regulating the solution pH value range 3.0–5.4, LCST of HTHP 2 could be changed from 12.8 to 68.0 °C. Meanwhile, the cell viabilities of A549 cells were more than 80% for in vitro cytotoxicity tests of HTHP 2, suggested that HTHP 2 polymers are of good biocompatibility for up to 24 h.

Novel waterborne UV-curable coatings based on hyperbranched polymers via electrophoretic deposition

Two modified types of polymer were based on hyperbranched polyether (HBPE) and used for UV-curable EPD coatings. The properties of the coatings were analyzed from the perspective of hyperbranched structures.