Enhanced LPG sensing property of sol–gel synthesized ZnO nanoparticles-based gas sensors

2021 ◽  
Vol 44 (2) ◽  
Author(s):  
A Muthuvinayagam ◽  
Soumen Dhara
Sensor Review ◽  
2017 ◽  
Vol 37 (3) ◽  
pp. 364-370 ◽  
Author(s):  
Xuehai Guo ◽  
Guofeng Pan ◽  
Xin Ma ◽  
Xiangzhou Li ◽  
Ping He ◽  
...  

Purpose The purpose of this research is to synthesize Al2O3-ZnO thick films, study the effect of doping and optical excitation on their sensing properties and introduce an attractive candidate for acetone detection in practice. Design/methodology/approach ZnO nanoparticles doped with Al2O3 were prepared by sol-gel method and characterized via X-ray diffraction and field-emission scanning electron microscopy. The sensing properties to acetone were investigated with an irradiation of UV. The sensing mechanism was also discussed with UV-Vis spectroscopy. Findings The doping of Al2O3 promoted the sensing response and stability of ZnO nanoparticles. The optimum performance was obtained by 4.96 Wt.% Al2O3-ZnO. The response to acetone (1,000 ppm) was significantly increased to 241.81, even just at an operating temperature of 64°C. It was also demonstrated that optical excitation with UV irradiation greatly enhanced the sensing response and the sensitivity can reach up to 305.14. Practical implications The sensor fabricated from 4.96 Wt.% Al2O3-ZnO exhibited excellent acetone-sensing characteristics. It is promising to be applied in low power and miniature acetone gas sensors. Originality/value In the present research, the optimum performance was obtained by 4.96 Wt.% Al2O3-ZnO at a low operating temperature of 64°C. The sensing properties were enhanced significantly with optical excitation, and the sensing mechanism was discussed with UV-Vis spectroscopy which has been reported rarely before.


Sensor Review ◽  
2018 ◽  
Vol 38 (3) ◽  
pp. 311-320 ◽  
Author(s):  
Yuxin Miao ◽  
Guofeng Pan ◽  
Caixuan Sun ◽  
Ping He ◽  
Guanlong Cao ◽  
...  

PurposeThe purpose of this paper is to study the effect of doping, annealing temperature and visible optical excitation on CuO-ZnO nanocomposites’ acetone sensing properties and introduce an attractive candidate for acetone detection at about room temperature.Design/methodology/approachZnO nanoparticles doped with CuO were prepared by sol-gel method, and the structure and morphology were characterized via X-ray diffraction, scanning electron microscope, energy dispersive spectroscopy and Brunauer-Emmett-Teller. The photoelectric responses of CuO-ZnO nanocomposites to cetone under the irradiation of visible light were investigated at about 30°C. The photoelectric response mechanism was also discussed with the model of double Schottky.FindingsThe doping of CuO enhanced performance of ZnO nanoparticles in terms of the photoelectric responses and the gas response and selectivity to acetone of ZnO nanoparticles, in addition, decreasing the operating temperature to about 30ºC. The optimum performance was obtained by 4.17% CuO-ZnO nanocomposites. Even at the operating temperature, about 30ºC, the response to 1,000 ppm acetone was significantly increased to 579.24 under the visible light irradiation.Practical implicationsThe sensor fabricated by 4.17% CuO-ZnO nanocomposites exhibited excellent acetone-sensing characteristics at about 30ºC. It is promising to be applied in low power and miniature acetone gas sensors.Originality/valueIn the present research, a new nanocomposite material of CuO-ZnO was prepared by Sol-gel method. The optimum gas sensing properties to acetone were obtained by 4.17% CuO-ZnO nanocomposites at about 30ºC operating temperature when it was irradiated by visible light with the wavelength more than 420 nm.


2020 ◽  
Vol 5 (3) ◽  
pp. 236-251
Author(s):  
Eshwara I. Naik ◽  
Halehatty S.B. Naik ◽  
Ranganaik Viswanath

Background: Various interesting consequences are reported on structural, optical, and photoluminescence properties of Zn1-xSmxO (x=0, 0.01, 0.03 and 0.05) nanoparticles synthesized by sol-gel auto-combustion route. Objective: This study aimed to examine the effects of Sm3+-doping on structural and photoluminescence properties of ZnO nanoparticles. Methods: Zn1-xSmxO (x=0, 0.01, 0.03 and 0.05) nanoparticles were synthesized by sol-gel auto combustion method. Results: XRD patterns confirmed the Sm3+ ion substitution through the undisturbed wurtzite structure of ZnO. The crystallite size was decreased from 24.33 to 18.46 nm with Sm3+ doping. The hexagonal and spherical morphology of nanoparticles was confirmed by TEM analysis. UV-visible studies showed that Sm3+ ion doping improved the visible light absorption capacity of Sm3+ iondoped ZnO nanoparticles. PL spectra of Sm3+ ion-doped ZnO nanoparticles showed an orange-red emission peak corresponding to 4G5/2→6HJ (J=7/2, 9/2 and 11/2) transition of Sm3+ ion. Sm3+ ion-induced PL was proposed with a substantial increase in PL intensity with a blue shift in peak upon Sm3+ content increase. Conclusion: Absorption peaks associated with doped ZnO nanoparticles were moved to a longer wavelength side compared to ZnO, with bandgap declines when Sm3+ ions concentration was increased. PL studies concluded that ZnO emission properties could be tuned in the red region along with the existence of blue peaks upon Sm3+ ion doping, which also results in enhancing the PL intensity. These latest properties related to Sm3+ ion-doped nanoparticles prepared by a cost-efficient process appear to be interesting in the field of optoelectronic applications, which makes them a prominent candidate in the form of red light-emitting diodes.


Sensors ◽  
2021 ◽  
Vol 21 (6) ◽  
pp. 2103 ◽  
Author(s):  
Tae-Hee Han ◽  
So-Young Bak ◽  
Sangwoo Kim ◽  
Se Hyeong Lee ◽  
Ye-Ji Han ◽  
...  

This paper introduces a method for improving the sensitivity to NO2 gas of a p-type metal oxide semiconductor gas sensor. The gas sensor was fabricated using CuO nanowires (NWs) grown through thermal oxidation and decorated with ZnO nanoparticles (NPs) using a sol-gel method. The CuO gas sensor with a ZnO heterojunction exhibited better sensitivity to NO2 gas than the pristine CuO gas sensor. The heterojunction in CuO/ZnO gas sensors caused a decrease in the width of the hole accumulation layer (HAL) and an increase in the initial resistance. The possibility to influence the width of the HAL helped improve the NO2 sensing characteristics of the gas sensor. The growth morphology, atomic composition, and crystal structure of the gas sensors were analyzed using field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy, and X-ray diffraction, respectively.


2014 ◽  
Vol 152 (1) ◽  
pp. 29-35 ◽  
Author(s):  
Ying Zhang ◽  
Qian-Qian Jia ◽  
Hui-Ming Ji ◽  
Jian-Jun Yu

2013 ◽  
Vol 481 ◽  
pp. 133-136 ◽  
Author(s):  
T.N. Myasoedova ◽  
G.E. Yalovega ◽  
N.K. Plugotarenko ◽  
M. Brzhezinskaya ◽  
V.V. Petrov ◽  
...  

Copper oxides films as promising materials for gas sensors applications were studied. Copper oxide films were deposited onto Si/SiO2substrates using a citrate sol-gel method with the subsequent temperature treatment at 150-5000C. These films were characterized by means of secondary electron microscopy (SEM) and X-ray-absorption near-edge structure (XANES) spectroscopy. The prepared films were utilized in NO2sensors. The dependences of the NO2response on the operating temperature and NO2concentration (10-200 ppm) were investigated. The maximum NO2response was achieved for the film annealed at 2500C.


2022 ◽  
pp. 131384
Author(s):  
Xiaowei Ren ◽  
Ze Xu ◽  
Di Liu ◽  
Yutong Li ◽  
Zhongtai Zhang ◽  
...  

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