scholarly journals Textures and compositions of cobalt pentlandite and cobaltian mackinawite from the Madan-Kudan copper deposit, Khetri Copper Belt, Rajasthan, India

2018 ◽  
Vol 127 (4) ◽  
Author(s):  
Abu Saeed Baidya ◽  
Atlanta Sen ◽  
Dipak C Pal
Keyword(s):  
Copper Deposit ◽  
Khetri Copper Belt

SEM analysis of the change in the reaction rates with deposit structures in the copper-iron cementation system

1978 ◽  
Vol 36 (1) ◽  
pp. 456-457
Author(s):  
V. Annamalai ◽  
L.E. Murr
Keyword(s):  
Structural Characteristics ◽  
Secondary Electron Emission ◽  
Copper Deposit ◽  
Reaction Rates ◽  
Sem Analysis ◽  
Experimental Conditions ◽  
Major Drawback ◽  
Emission Mode ◽  
Scrap Iron ◽  
Image Position

Economical recovery of copper metal from leach liquors has been carried out by the simple process of cementing copper onto a suitable substrate metal, such as scrap-iron, since the 16th century. The process has, however, a major drawback of consuming more iron than stoichiometrically needed by the reaction.Therefore, many research groups started looking into the process more closely. Though it is accepted that the structural characteristics of the resultant copper deposit cause changes in reaction rates for various experimental conditions, not many systems have been systematically investigated. This paper examines the deposit structures and the kinetic data, and explains the correlations between them.A simple cementation cell along with rotating discs of pure iron (99.9%) were employed in this study to obtain the kinetic results The resultant copper deposits were studied in a Hitachi Perkin-Elmer HHS-2R scanning electron microscope operated at 25kV in the secondary electron emission mode.

Electrochemical nucleation and growth of copper on iron and aluminum: A TEM study of industrial copper cementation

1978 ◽  
Vol 36 (1) ◽  
pp. 454-455
Author(s):  
L.E. Murr ◽  
V. Annamalai
Keyword(s):  
Metal Surface ◽  
Copper Deposit ◽  
Nucleation And Growth ◽  
16Th Century ◽  
Electrochemical Reactions ◽  
Mine Shaft ◽  
De Re ◽  
Copper Precipitation ◽  
Electrochemical Nucleation ◽  
Interesting System

Georgius Agricola in 1556 in his classical book, “De Re Metallica”, mentioned a strange water drawn from a mine shaft near Schmölnitz in Hungary that eroded iron and turned it into copper. This precipitation (or cementation) of copper on iron was employed as a commercial technique for producing copper at the Rio Tinto Mines in Spain in the 16th Century, and it continues today to account for as much as 15 percent of the copper produced by several U.S. copper companies.In addition to the Cu/Fe system, many other similar heterogeneous, electrochemical reactions can occur where ions from solution are reduced to metal on a more electropositive metal surface. In the case of copper precipitation from solution, aluminum is also an interesting system because of economic, environmental (ecological) and energy considerations. In studies of copper cementation on aluminum as an alternative to the historical Cu/Fe system, it was noticed that the two systems (Cu/Fe and Cu/Al) were kinetically very different, and that this difference was due in large part to differences in the structure of the residual, cement-copper deposit.

scholarly journals Ore Genesis at the Jinchang Gold–Copper Deposit in Heilongjiang Province, Northeastern China: Evidence from Geology, Fluid Inclusions, and H–O–S Isotopes

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 99 ◽  
Author(s):  
Shunda Li ◽  
Xuebing Zhang ◽  
Lingling Gao
Keyword(s):  
Fluid Inclusions ◽  
Copper Deposit ◽  
Northeastern China ◽  
Heilongjiang Province ◽  
Quartz Veins ◽  
Daughter Mineral ◽  
Rich Liquid ◽  
Three Stages ◽  
Stage 1 ◽  
Late Stages

The Jinchang gold–copper deposit is located in Eastern Heilongjiang Province,Northeastern China. The orebody comprises primarily hydrothermal breccias, quartz veins, anddisseminated ores within granite, diorite, and granodiorite. Three paragenetic stages are identified:early quartz–pyrite–arsenopyrite (Stage 1), quartz–pyrite–chalcopyrite (Stage 2), and latequartz–pyrite–galena–sphalerite (Stage 3). Gold was deposited during all three stages and Stage 1was the major gold-producing stage. Copper is associated with the mineralization but has loweconomic value. Fluid inclusions (FIs) within the deposit are liquid-rich aqueous, vapor-rich aqueous,and daughter-mineral-bearing types. Microthermometric data for the FIs reveal decreasinghomogenization temperatures (Th) and salinities of the ore-forming fluids over time. The Th forStages 1–3 of the mineralization are 421–479, 363–408, and 296–347 °C, respectively. Stage 1 fluidsin vapor-rich and daughter-mineral-bearing inclusions have salinities of 5.7–8.7 and 49.8–54.4 wt%NaCl equivalent, respectively. Stage 2 fluids in vapor-rich, liquid-rich, and daughter-mineral-bearinginclusions have salinities of 1.2–5.4, 9.5–16.0, and 43.3–48.3 wt% NaCl, respectively. Stage 3 fluids inliquid-rich and daughter-mineral-bearing inclusions have salinities of 7.9–12.6 and 38.3–42.0 wt% NaClequivalent, respectively. The estimated trapping pressures are 160–220 bar, corresponding toan entrapment depth of 1.6–1.2 km in the paleo-water table. Oxygen and hydrogen isotope data(δ18OV-SMOW = 8.6‰ to 11.4‰; δDV-SMOW = −92.2‰ to −72.1‰) suggest that the ore-forming fluidswere derived from magmatic fluids during the early stages of mineralization and subsequentlyincorporated meteoric water during the late stages. The sulfide minerals have δ34SVCDT values of0.2‰–3.5‰, suggesting that the sulfur has a magmatic origin. The Jinchang deposit is a typicalgold-rich gold–copper porphyry deposit.

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