Dibenzothiophenes, phenyldibenzothiophenes, and benzo[b]naphthothiophenes in crude oils and source rock extracts from the Niger Delta Basin, Nigeria, and their applications as source facies, depositional environments, and thermal maturity indicators

2021 ◽  
Vol 14 (7) ◽  
Author(s):  
Abiodun B. Ogbesejana ◽  
Oluwasesan M. Bello ◽  
Oluwadurotimi O. Akintade ◽  
Oluwole Joshua Okunola ◽  
Paul M. Osamudiamen ◽  
...  
2017 ◽  
Vol 5 (2) ◽  
pp. SF225-SF242 ◽  
Author(s):  
Xun Sun ◽  
Quansheng Liang ◽  
Chengfu Jiang ◽  
Daniel Enriquez ◽  
Tongwei Zhang ◽  
...  

Source-rock samples from the Upper Triassic Yanchang Formation in the Ordos Basin of China were geochemically characterized to determine variations in depositional environments, organic-matter (OM) source, and thermal maturity. Total organic carbon (TOC) content varies from 4 wt% to 10 wt% in the Chang 7, Chang 8, and Chang 9 members — the three OM-rich shale intervals. The Chang 7 has the highest TOC and hydrogen index values, and it is considered the best source rock in the formation. Geochemical evidence indicates that the main sources of OM in the Yanchang Formation are freshwater lacustrine phytoplanktons, aquatic macrophytes, aquatic organisms, and land plants deposited under a weakly reducing to suboxic depositional environment. The elevated [Formula: see text] sterane concentration and depleted [Formula: see text] values of OM in the middle of the Chang 7 may indicate the presence of freshwater cyanobacteria blooms that corresponds to a period of maximum lake expansion. The OM deposited in deeper parts of the lake is dominated by oil-prone type I or type II kerogen or a mixture of both. The OM deposited in shallower settings is characterized by increased terrestrial input with a mixture of types II and III kerogen. These source rocks are in the oil window, with maturity increasing with burial depth. The measured solid-bitumen reflectance and calculated vitrinite reflectance from the temperature at maximum release of hydrocarbons occurs during Rock-Eval pyrolysis ([Formula: see text]) and the methylphenanthrene index (MPI-1) chemical maturity parameters range from 0.8 to [Formula: see text]. Because the thermal labilities of OM are associated with the kerogen type, the required thermal stress for oil generation from types I and II mixed kerogen has a higher and narrower range of temperature for hydrocarbon generation than that of OM dominated by type II kerogen or types II and III mixed kerogen deposited in the prodelta and delta front.


2020 ◽  
Author(s):  
Abiodun B. Ogbesejana ◽  
Oluwasesan M. Bello ◽  
Tijjani Ali ◽  
Uduma A. Uduma ◽  
Kamaluddeen S. Kabo ◽  
...  

2020 ◽  
Vol 4 (1) ◽  
pp. 1-13
Author(s):  
Aboglila S

Drill cutting samples (n = 92) from the Devonian Awaynat Wanin Formation and Silurian Tanezzuft Formation, sampled from three wells F1, G1 and H1, locate in the northern edge of the Murzuq basin (approximately 700 kilometers south of Tripoli). The studied samples were analyzed in the objective of their organic geochemical assessment such as the type of organic matter, depositional conditions and thermal maturity level. A bulk geochemical parameters and precise biomarkers were estimated, using chromatography-mass spectrometry (GC-MS) to reveal a diversity of their geochemical characterizations. The rock formations are having varied organic matter contents, ranged from fair to excellent. The total organic carbon (TOC) reached about 9.1 wt%, ranging from 0.6 to 2.93 wt% (Awaynat Wanin), 0.5 to 2.54 wt% (Tanezzuft) and 0.52 to 9.1 wt% (Hot Shale). The cutting samples are ranged oil-prone organic matter (OM) of hydrogen index (HI) ranged between 98 –396 mg HC/g TOC, related kerogen types are type II and II/III, with oxygen index (OI): 6 - 190 with one sample have value of 366 mg CO2/g. Thermal maturity of these source rocks is different, ranging from immature to mature and oil window in the most of Tanezzuft Formation and Hot Shale samples, as reflected from the production index data (PI: 0.08 - 034). Tmax and vitrinite reflectance Ro% data (Tmax: 435 – 454 & Ro%: 0.46 - 1.38) for the Awaynat Wanin. Biomarker ratios of specific hydrocarbons extracted from represented samples (n = 9), were moreover used to study thermal maturity level and depositional environments. Pristine/Phytane (Pr/Ph) ratios of 1.65 - 2.23 indicated anoxic to suboxic conditions of depositional marine shale and lacustrine source rock.


2021 ◽  
Vol 2 (6) ◽  
pp. 53-57
Author(s):  
Godwin O. Aigbadon ◽  
Goriola O. Babatunde ◽  
Mu’awiya B. Aminu ◽  
Changde A. Nanfa ◽  
Simon D. Christopher

This study was carried out by using well logs to evaluate the depositional environments and hydrocarbon reservoirs in the Otuma oil field, Niger Delta basin. The gamma motif/model within- study interval in the drilled well shows blocky, symmetrical, and serrated shapes which suggest a deltaic front with mouth bar to a regressive - transgressive shoreface delta respectively. A correlation was done on the well logs across the wells and the ten well logs were used to evaluate the petrophysical characteristics of the reservoirs. The reservoirs showed highly porous and permeable channels where the wells were used for the characterization. The ten reservoirs were mapped at a depth range of 2395 m to 2919 m with thicknesses varying from 4m to 135m. The petrophysical results of the field showed that the porosity of the reservoirs ranges between 0.10 to 0.30, and permeability from 48 md to 290 md; the water saturation ranges from 0.39 to 0.52, and hydrocarbon saturation from the field 0.48 to 0.61. The By-passed hydrocarbons identified in low resistivity pay sands D4 and D3 at depth 2649 m to 2919 m, respectively were also evaluated and will be put to production in the field.


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