Effect of 2-mercaptobenzothiazole concentration on sour-corrosion behavior of API X60 pipeline steel: Electrochemical parameters and adsorption mechanism

2022 ◽  
Vol 29 (2) ◽  
pp. 271-282
Author(s):  
Masoud Sabzi ◽  
Amir Hayati Jozani ◽  
Farzad Zeidvandi ◽  
Majid Sadeghi ◽  
Saeid Mersagh Dezfuli
Author(s):  
Kaikai Li ◽  
Wei Wu ◽  
Guangxu Cheng ◽  
Yun Li ◽  
Haijun Hu ◽  
...  

Natural gas transmission pipeline is prone to internal corrosion due to the combination of corrosive impurities in the pipe (such as CO2, H2S and chlorides) and applied pressure of the pipeline, which seriously affects the safe operation of the pipeline. In this work, the corrosion behavior of a typical X70 pipeline steel was investigated by using potentiodynamic polarization and electrochemical impendence spectroscopy (EIS). The polarization and EIS data under different CO2 partial pressures (0–1 atm), H2S concentrations (0–150 ppm), chloride concentrations (0–3.5 wt%) and tensile stress (0–400 MPa) were obtained. The results show that corrosion rate increases with the increase of CO2 partial pressure and chloride concentration, respectively, while first increases and then decreases with the increase H2S concentrations. The corrosion rate is less affected by elastic tensile stress. In addition, a quantitative prediction model for corrosion rate of natural gas pipeline based on adaptive neuro-fuzzy inference system (ANFIS) was established by fitting the experimental data which maps the relationship between the key influencing factors (i.e. CO2 partial pressure, H2S concentration, chloride concentration and tensile stress) and the corrosion rate. The prediction results show that the relative percentage errors of the predicted and experimental values are relatively small. The prediction accuracy of the model satisfies the engineering application requirement.


2017 ◽  
Vol 26 (8) ◽  
pp. 3775-3783 ◽  
Author(s):  
Paul C. Okonkwo ◽  
Mostafa H. Sliem ◽  
R. A. Shakoor ◽  
A. M. A. Mohamed ◽  
Aboubakr M. Abdullah

2019 ◽  
Vol 28 (3) ◽  
pp. 1698-1706 ◽  
Author(s):  
M. Zhu ◽  
Y. F. Yuan ◽  
S. M. Yin ◽  
G. H. Yu ◽  
S. Y. Guo ◽  
...  

2012 ◽  
Vol 36 ◽  
pp. 54-57 ◽  
Author(s):  
Yun Xie ◽  
Lining Xu ◽  
Chunliang Gao ◽  
Wei Chang ◽  
Minxu Lu

Author(s):  
Dongxu Sun ◽  
Ming Wu ◽  
Fei Xie ◽  
Ke Gong

Abstract In this study, a three-dimensional finite element model was constructed to study the stress corrosion behavior of pipeline steel. Stress analysis and electrochemical calculation were incorporated into the model through multiphysics field coupling technique. Tensile property and electrochemical corrosion behavior of X70 pipeline steel were measured by experiments to formulate the model. The modeling results show that the corrosion is accelerated on the surface of corrosion defect where the stress tends to concentrate because of mechanoelectrochemical effect. The effect of elastic strain on corrosion enhancement is not obvious. The plastic deformation on defect bottom increases the corrosion rate significantly, especially for the conditions with high operating pressure or large defect depth. The corrosion current distribution indicated that the “self-acceleration effect” exists on corrosion defect. This effect makes the corrosion develop to depth and the shape of corrosion defects is more likely to cause stress concentration, and finally induces corrosion perforation or cracking. The two directions, i.e. axial and circumferential direction, have the different stress corrosion behaviors. The “self-acceleration effect” is more obvious on circumferential direction than that on axial direction, which can explain the phenomenon that there are mostly axial stress corrosion cracks on the pipeline in field.


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