Corrosion behavior of pipeline steel welds in simulated produced water with different CO2 partial pressures under high temperature

2017 ◽  
Vol 59 (4) ◽  
pp. 348-354 ◽  
Author(s):  
Yongxin Lu ◽  
Hongyang Jing ◽  
Yongdian Han ◽  
Lianyong Xu
Author(s):  
Wenliang Zhang ◽  
Lining Xu ◽  
Shaoqiang Guo ◽  
Lei Zhang ◽  
Minxu Lu ◽  
...  

CO2 corrosion is frequently encountered in oil and gas industry. The search for new sources of oil and gas has pushed the operational activities to harsher environment and this requires new tubing and pipeline materials which can endure tough circumstances. Low alloy steel containing Chromium, which fills the gap between carbon steels and corrosion resistant alloys in terms of cost and corrosion resistance, has aroused significant interest from steel enterprises and scholars. At present, these studies mainly focus on 3%–5%Cr steel, and little study concerns the 2%Cr steel, which is more economic and weldable. In this paper, novel Cr2MoNbTi steel was developed and the microstructure and mechanical properties were studied. Corrosion behavior of the Cr2MoNbTi steel immersed in the CO2-containing solutions, which corresponded to the environment of bottom-of-line corrosion (BLC), was studied using high temperature-high pressure autoclave. In addition, dynamic high temperature-high pressure condensation autoclave was employed to simulate the top-of-line corrosion (TLC) environment and the corrosion behavior of the Cr2MoNbTi steel under wet gas environment was investigated. The composition and morphology of the corrosion scale were characterized by energy dispersive spectroscopy and scanning electron microscopy analyses. The results show that the Cr2MoNbTi steel exhibited uniform corrosion and presented good resistance to CO2 corrosion compared with X65 pipeline steel.


2014 ◽  
Vol 789 ◽  
pp. 466-470
Author(s):  
Qing Hao Shi ◽  
Bing Ying Wang ◽  
Bin Zhao

The corrosion mechanism of organic silicon modified polyurea composite coating under different CO2 partial pressures was studied using high-temperature autoclave, combined with scanning electron microscopy (SEM), adhesion tests and electrochemical impedance spectroscopy (EIS) technology. The experimental results showed that: there was no corrosion product formed on the surface of coating sample after high-temperature high-pressure corrosion test, and with the increasing of CO2 partial pressure, the coating adhesion and impedance values decline increases. Moreover CO2 partial pressure increases accelerated the failure process of polyurea composite coating system.


2011 ◽  
Vol 696 ◽  
pp. 272-277 ◽  
Author(s):  
Toto Sudiro ◽  
Tomonori Sano ◽  
Akira Yamauchi ◽  
Shoji Kyo ◽  
Osamu Ishibashi ◽  
...  

The objective of this study is to develop an excellent corrosion resistant alloy for high temperature coating applications. The Si-containing alloys consisting of CoNiCrAlY and CrSi2 alloys with varying Si and Ni content respectively were prepared by spark plasma sintering (SPS) technique. The corrosion behavior of these alloys was investigated in the gas phase of air-(Na2SO4+25.7mass%NaCl) at elevated temperatures of 923, 1073 and 1273K. The results showed that CoNiCrAlY alloy with 30mass% Si content and CrSi2 alloy with 10mass% Ni content were the most effective materials for application in the gas phase of air-(Na2SO4+25.7mass%NaCl) due to the formation of protective Al2O3/SiO2 and SiO2 scale, respectively. Therefore, it is realized that CoNiCrAlY-30mass% Si and CrSi2-10mass% Si coating are very effective for improving of high temperature corrosion resistance of STBA21 steel.


2018 ◽  
Vol 27 (3) ◽  
pp. 500-511 ◽  
Author(s):  
Reza Jafari ◽  
Esmaeil Sadeghimeresht ◽  
Taghi Shahrabi Farahani ◽  
Matti Huhtakangas ◽  
Nicolaie Markocsan ◽  
...  

Author(s):  
Kaikai Li ◽  
Wei Wu ◽  
Guangxu Cheng ◽  
Yun Li ◽  
Haijun Hu ◽  
...  

Natural gas transmission pipeline is prone to internal corrosion due to the combination of corrosive impurities in the pipe (such as CO2, H2S and chlorides) and applied pressure of the pipeline, which seriously affects the safe operation of the pipeline. In this work, the corrosion behavior of a typical X70 pipeline steel was investigated by using potentiodynamic polarization and electrochemical impendence spectroscopy (EIS). The polarization and EIS data under different CO2 partial pressures (0–1 atm), H2S concentrations (0–150 ppm), chloride concentrations (0–3.5 wt%) and tensile stress (0–400 MPa) were obtained. The results show that corrosion rate increases with the increase of CO2 partial pressure and chloride concentration, respectively, while first increases and then decreases with the increase H2S concentrations. The corrosion rate is less affected by elastic tensile stress. In addition, a quantitative prediction model for corrosion rate of natural gas pipeline based on adaptive neuro-fuzzy inference system (ANFIS) was established by fitting the experimental data which maps the relationship between the key influencing factors (i.e. CO2 partial pressure, H2S concentration, chloride concentration and tensile stress) and the corrosion rate. The prediction results show that the relative percentage errors of the predicted and experimental values are relatively small. The prediction accuracy of the model satisfies the engineering application requirement.


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