Water circulation in karst systems: comparing physicochemical and environmental isotopic data interpretation

2018 ◽  
Vol 77 (11) ◽  
Author(s):  
Joseph Asante ◽  
Sam Dotson ◽  
Evan Hart ◽  
David K. Kreamer
2021 ◽  
Author(s):  
Jianfei Ma ◽  
Xiangquan Li ◽  
Feng Liu ◽  
Changchang Fu ◽  
Chunchao Zhang ◽  
...  

Abstract Understanding of the recharge origin, runoff channels, and discharge characteristics of karst groundwater is very important for construction of underground projects and identification of water supply targets. Complex structural systems, lithological differences, and extreme heterogeneity of aquifers combine to create a complex karst aquifer structure in alpine and gorge areas; however, because of the topography, direct investigation of aquifer structure is difficult. In this study, field survey, hydrochemical, and isotopic data are analyzed to reveal the development of karst groundwater and to describe the karst water cycle in Genie Mountain, Qinghai–Xizang Plateau. The results show that atmospheric precipitation and melting ice and snow are the groundwater recharge sources, and groundwater circulation is shallow, with groundwater ages generally no more than 60 yr. The groundwater cycle can be divided into three levels: epikarst water circulation; mid to deep karst water circulation; and deep geothermal water circulation. The karst springs located in the outlet of the Huolong gully contain markedly higher levels of Na + and SO 4 2 − than other karst springs because of the leaching effect of groundwater on mirabilite. The presence of evaporites also indicates that the groundwater of Huolong gully is influenced by evaporation. The runoff of thermal springs undergoes deep circulation and is controlled by faults. This water mainly dissolves carbonate rock, with little influence of evaporation. This study shows that hydrochemical and isotopic methods can be used to discriminate different water types, and can be applied to study the characteristics of complex groundwater runoff in alpine and gorge areas.


Author(s):  
Kevin D. Webster ◽  
Agnieszka Drobniak ◽  
Giuseppe Etiope ◽  
Maria Mastalerz ◽  
Peter E. Sauer ◽  
...  

The air in subterranean karst cavities is often depleted in methane (CH4) relative to the atmosphere. Karst is considered a potential sink for the atmospheric greenhouse gas CH4 because its subsurface drainage networks and solution-enlarged fractures facilitate atmospheric exchange. Karst landscapes cover about 14% of earth’s continental surface, but observations of CH4 concentrations in cave air are limited to localized studies in Gibraltar, Spain, Indiana (USA), Vietnam, Australia, and by incomplete isotopic data. To test if karst is acting as a global CH4 sink, we measured the CH4 concentrations, δ13CCH4, and δ2HCH4 values of cave air from 33 caves in the USA and three caves in New Zealand. We also measured CO2 concentrations, δ13CCO2, and radon (Rn) concentrations to support CH4 data interpretation by assessing cave air residence times and mixing processes. Among these caves, 35 exhibited subatmospheric CH4 concentrations in at least one location compared to their local atmospheric backgrounds. CH4 concentrations, δ13CCH4, and δ2HCH4 values suggest that microbial methanotrophy within caves is the primary CH4 consumption mechanism. Only 5 locations from 3 caves showed elevated CH4 concentrations compared to the atmospheric background and could be ascribed to local CH4 sources from sewage and outgassing swamp water. Several associated δ13CCH4 and δ2HCH4 values point to carbonate reduction and acetate fermentation as biochemical pathways of limited methanogenesis in karst environments and suggest that these pathways occur in the environment over large spatial scales. Our data show that karst environments function as a global CH4 sink.


Author(s):  
H.A. Cohen ◽  
T.W. Jeng ◽  
W. Chiu

This tutorial will discuss the methodology of low dose electron diffraction and imaging of crystalline biological objects, the problems of data interpretation for two-dimensional projected density maps of glucose embedded protein crystals, the factors to be considered in combining tilt data from three-dimensional crystals, and finally, the prospects of achieving a high resolution three-dimensional density map of a biological crystal. This methodology will be illustrated using two proteins under investigation in our laboratory, the T4 DNA helix destabilizing protein gp32*I and the crotoxin complex crystal.


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