scholarly journals Thermochemical equilibrium study of ash transformation during combustion and gasification of sewage sludge mixtures with agricultural residues with focus on the phosphorus speciation

Author(s):  
Thomas Karl Hannl ◽  
Hamid Sefidari ◽  
Matthias Kuba ◽  
Nils Skoglund ◽  
Marcus Öhman
2019 ◽  
Vol 10 (1) ◽  
pp. 1-12 ◽  
Author(s):  
David Stan Aribike ◽  
Mohammed Awwalu Usman ◽  
Mojirade M. Oloruntoba

AbstractCombustion of fossil fuels gives rise to sulfur oxides, which are harmful to the environment. Adsorptive desulfurization (ADS) of diesel was conducted using sewage sludge activated with H2O2 as the oxidizing agent. A full 22 central composite response surface design was employed to determine optimum conditions for the production of activated sewage sludge (ASS). The adsorbent (ASS) was characterized using SEM, EDX and FTIR and the results of the analysis showed that it has the capacity to desulfurize diesel significantly. The ASS was subsequently used to conduct batch ADS of diesel with a view to investigate the kinetics, equilibrium and thermodynamics of the process. The optimum conditions established for the production of ASS using H2O2 as the oxidizing agent were: temperature 400 °C and holding time 60 min. The Elovich model gave the best fit to the kinetic data of the ADS of diesel using ASS, while the equilibrium study showed that the Freundlich isotherm fitted the data at 35 °C better than Temkin and Langmuir isotherms. The positive values of the free energy and enthalpy changes revealed that the process was non-spontaneous and endothermic, respectively, while the negative entropy change is evidence of decrease in randomness of the adsorbed species. 33% desulfurization was achieved in 100 min during ADS of diesel showing that the adsorbent developed by activating SS with H2O2 was very good and effective. Thus, ASS can be used to gain more insight into kinetics, equilibrium and thermodynamics of the ADS of middle-distillate petroleum fractions.


2019 ◽  
Vol 87 ◽  
pp. 71-77 ◽  
Author(s):  
Qiang Liu ◽  
Zheng Fang ◽  
Yuan Liu ◽  
Yangyang Liu ◽  
Yunfeng Xu ◽  
...  

Author(s):  
Mariana DUMITRU

The paper presents the advantages of using biogas as an alternative source of energy, especially in rural areas and insists on its specific advantages, compared to other alternative fuels, such as bio-ethanol and bio-diesel, which are very significant fuels which can be used in the future, but are contested from the social point of view, because they use as raw materials plants, some of them being used as food sources for mankind. The main advantage of biogas is that it is obtained from residues and wastes, so it has the ability to transform waste material into a valuable resource in the conditions in which many countries are facing enormous problems associated with overproduction of organic wastes from industry, agriculture and households. Biogas production is an excellent way to comply with increasingly restrictive national and European regulations in this domain and to use organic wastes for energy production, which is followed by recycling of the digested substrate as fertilizer. In the paper is emphasized the fact that a biogas plant is not only a supplier of energy. The digested substrate is a valuable soil fertiliser, rich in nitrogen, potassium, phosphorus and micronutrients, which can be applied on soils with the usual equipments for application of liquid manure. A wide range of biomass types can be used as substrates for the production of biogas. The most common biomass categories used in European biogas production are : animal manure and slurry, agricultural residues and by-products, digestible organic wastes from food and agro- industries, organic fraction of municipal waste and from catering, sewage sludge, dedicated energy crops (maize, miscanthus, sorghum, clover). One main advantage of biogas production is the ability to use “wet biomass” types as feedstock, all characterised by moisture content higher than 60- 70% (such as sewage sludge, animal slurries, flotation sludge from food processing etc.). In the late years, a number of energy crops (grains, maize, rapeseed), have been largely used as feedstock for biogas production in countries like Austria or Germany. Besides energy crops, all kinds of agricultural residues, damaged crops, unsuitable for food or resulting from unfavourable growing and weather conditions, can be used to produce biogas and fertiliser. A number of animal by-products, not suitable for human consumption, can also be processed in biogas plants.


2021 ◽  
pp. 107102
Author(s):  
Thomas Karl Hannl ◽  
Gustav Häggström ◽  
Ali Hedayati ◽  
Nils Skoglund ◽  
Matthias Kuba ◽  
...  

2017 ◽  
Vol 69 ◽  
pp. 353-359 ◽  
Author(s):  
Marco Grigatti ◽  
Elisa Boanini ◽  
Giampaolo Di Biase ◽  
Claudio Marzadori ◽  
Claudio Ciavatta

Author(s):  
Gustav Häggström ◽  
Thomas Karl Hannl ◽  
Ali Hedayati ◽  
Matthias Kuba ◽  
Nils Skoglund ◽  
...  

2014 ◽  
Vol 40 (3) ◽  
Author(s):  
Elżbieta Bezak-Mazur ◽  
Agnieszka Mazur ◽  
Renata Stoińska

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