Microchemical determination of organic nitrogen with nessler reagent

1971 ◽  
Vol 43 (2) ◽  
pp. 527-532 ◽  
Author(s):  
George R. Morrison
Author(s):  
Sharon A. Gordon ◽  
A. Fleck ◽  
Jean Bell

A technique for optimising reagent concentrations on the AutoAnalyzer has been applied to the estimation of ammonia by the Berthelot reaction in the determination of urea and organic nitrogen. Comparison of the use of phenol and salicylate revealed that the optimum concentration of the latter is about four times that of the former. The optimum concentration of hypochlorite is five times greater with salicylate than with phenol, and for the catalyst, sodium nitroprusside, the factor is two. The precision obtained with the different methods is similar.


1967 ◽  
Vol 7 (26) ◽  
pp. 266 ◽  
Author(s):  
R Wetselaar

The mineralization coefficient (M.C.) (the amount of nitrate nitrogen formed in one season in sift, by bare fallowing the soil, as a percentage of the amount of organic nitrogen in the topsoil at the onset of the season) was measured on two soils at Katherine, N.T. The determination of M.C. is regarded as useful in evaluating the 'true' decomposition constant of a soil under annual cropping conditions. Its relation to the 'apparent' decomposition constant is discussed. Tippera clay loam had a mean M.C. of 4.80 per cent, and the fluctuations around the mean were positively related to amount of rainfall. The M.C. for Blain sand dropped from 12.5 per cent in the first year of cultivation to 5.0 per cent in the third and fourth years. The data indicate that the initial high nitrogen yields on the sandy soil will in time decline to a low level unless a legume crop is incorporated in the cropping system.


1965 ◽  
Vol 48 (6) ◽  
pp. 1111-1115
Author(s):  
W G Burch ◽  
J A Brabson

Abstract With a Raney catalyst powder containing 10% Co, 40%; Ni, and 50% Al, nitrates are reduced to ammonia in 8N sulfuric acid in 10 minutes. Neither chlorides nor organic nitrogen compounds interfere with the reduction, and the reduction passed Youden’s ruggedness test. Results of analyses of fertilizers for total nitrogen that included reduction with the powder were in good agreement with those of accepted methods.


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