Topological dependence of ferromagnetic coupling strength in some π-conjugated radicals

1995 ◽  
Vol 246 (3) ◽  
pp. 221-227 ◽  
Author(s):  
Shuhua Li ◽  
Jing Ma ◽  
Yuansheng Jiang
2005 ◽  
Vol 290-291 ◽  
pp. 974-980 ◽  
Author(s):  
J. Fontcuberta ◽  
D. Rubi ◽  
C. Frontera ◽  
J.L. García-Muñoz ◽  
M. Wojcik ◽  
...  

ChemInform ◽  
2005 ◽  
Vol 36 (34) ◽  
Author(s):  
J. Fontcuberta ◽  
D. Rubi ◽  
C. Frontera ◽  
J. L. Garcia-Munoz ◽  
M. Wojcik ◽  
...  

1995 ◽  
Vol 384 ◽  
Author(s):  
J.F. Cochran ◽  
K. Totland ◽  
B. Heinrich ◽  
D. Venus ◽  
S. Govorkov

ABSTRACTBrillouin light scattering (BLS) and magneto-optic Kerr effect have been carried out on a series of specimens consisting of a Fe(001) whisker substrate upon which thin Cr(001) and Fe(001) layers have been deposited by means of molecular beam epitaxy in ultrahigh vacuum. The Fe film was 20 monolayers (ML) thick, and the Cr(001) films were grown having various thicknesses. It is demonstrated that BLS thin film frequencies measured in the saturated magnetic state with the thin film magnetization parallel with the applied magnetic field can be used to obtain the exchange coupling strength between the thin film and whisker magnetizations both for antiferromagnetic coupling and for ferromagnetic coupling, provided that the ferromagnetic coupling is not too strong. It is also shown that the coupling strength is extremely sensitive to the quality of the chromium growth: a small deterioration in the growth conditions has been found to reduce the exchange coupling by nearly a factor of two.


2020 ◽  
Author(s):  
Evgeny Tretyakov ◽  
Svetlana Zhivetyeva ◽  
Pavel Petunin ◽  
Dmitry Gorbunov ◽  
Nina Gritsan ◽  
...  

<p>Verdazyl-nitroxide diradicals were synthesized using the palladium-catalyzed cross-coupling reaction of the corresponding iodoverdazyls with a nitronyl nitroxide-2-ide gold(I) complex with high yields (up to 82%). The synthesized diradicals were found to be highly thermally stable and have a singlet (D<i>E</i><sub>ST</sub> » -64 cm<sup>–1</sup>) or triplet ground state (D<i>E</i><sub>ST</sub> ³ 25 and 100 cm<sup>–1</sup>), depending on which canonical hydrocarbon diradical type they belong to. Upon crystallization, triplet diradicals form unique one-dimensional (1D) spin <i>S</i> = 1 chains of organic diradicals with intrachain ferromagnetic coupling of <i>J</i>′/<i>k</i><sub>B</sub> from 3 to 6 K.</p>


Author(s):  
Jean-Pierre Launay ◽  
Michel Verdaguer

After preliminaries about electron properties, and definitions in magnetism, one treats the magnetism of mononuclear complexes, in particular spin cross-over, showing the role of cooperativity and the sensitivity to external perturbations. Orbital interactions and exchange interaction are explained in binuclear model systems, using orbital overlap and orthogonality concepts to explain antiferromagnetic or ferromagnetic coupling. The phenomenologically useful Spin Hamiltonian is defined. The concepts are then applied to extended molecular magnetic systems, leading to molecular magnetic materials of various dimensionalities exhibiting bulk ferro- or ferrimagnetism. An illustration is provided by Prussian Blue analogues. Magnetic anisotropy is introduced. It is shown that in some cases, a slow relaxation of magnetization arises and gives rise to appealing single-ion magnets, single-molecule magnets or single-chain magnets, a route to store information at the molecular level.


Author(s):  
Chuyang Liu ◽  
Tao Jiang ◽  
Tian Gao ◽  
Guangxian Xia ◽  
Yufan Cao ◽  
...  

It is well known that both hard/soft magnetic exchange-coupling and ferroelectric-ferromagnetic coupling could facilitate the microwave absorption behavior. Herein, we propose the BaZrxFe12-xO19/Fe3O4/BaZrO3 composites to integrate the advantages of the...


2021 ◽  
Vol 2021 (6) ◽  
Author(s):  
Mustafa A. Amin ◽  
Andrew J. Long ◽  
Zong-Gang Mou ◽  
Paul M. Saffin

Abstract We investigate the production of photons from coherently oscillating, spatially localized clumps of axionic fields (oscillons and axion stars) in the presence of external electromagnetic fields. We delineate different qualitative behaviour of the photon luminosity in terms of an effective dimensionless coupling parameter constructed out of the axion-photon coupling, and field amplitude, oscillation frequency and radius of the axion star. For small values of this dimensionless coupling, we provide a general analytic formula for the dipole radiation field and the photon luminosity per solid angle, including a strong dependence on the radius of the configuration. For moderate to large coupling, we report on a non-monotonic behavior of the luminosity with the coupling strength in the presence of external magnetic fields. After an initial rise in luminosity with the coupling strength, we see a suppression (by an order of magnitude or more compared to the dipole radiation approximation) at moderately large coupling. At sufficiently large coupling, we find a transition to a regime of exponential growth of the luminosity due to parametric resonance. We carry out 3+1 dimensional lattice simulations of axion electrodynamics, at small and large coupling, including non-perturbative effects of parametric resonance as well as backreaction effects when necessary. We also discuss medium (plasma) effects that lead to resonant axion to photon conversion, relevance of the coherence of the soliton, and implications of our results in astrophysical and cosmological settings.


2020 ◽  
Vol 2 (1) ◽  
Author(s):  
Isabella Boventer ◽  
Christine Dörflinger ◽  
Tim Wolz ◽  
Rair Macêdo ◽  
Romain Lebrun ◽  
...  
Keyword(s):  

Sign in / Sign up

Export Citation Format

Share Document