In view of troubles during the operation of desulfurization device for Pangang 260 m2 sintering machine, influence on absorption/desorption capacity of the desulfurization solution was investigated, including concentrations of Na+, SO42- and desulfurization solution. The results showed that it was beneficial for sulfur dioxide (SO2) absorption and there was no significant effect on desorption efficiency, when Na+ and SO42- concentration was lower than 15 g/L and 67 g/L, respectively. When the concentration of desulfurization solution reached 113 g/L, Na+ and SO42-concentrations had no significant effect on absorption/desorption of the desulfurization solution. The results also indicated that desorption was more difficult with higher of the desulfurization solution concentration. The desorption efficiency of 113 g/L desulfurization solution was 10 %-17 % lower than that of 69 g/L desulfurization solution.