Dissolution kinetics of Zn2SiO4 powders: Effects of polymorphs, temperature, particle size, and Fe2+ presence

1994 ◽  
Vol 58 (17) ◽  
pp. 3583-3593 ◽  
Author(s):  
Lin Chung-Cherng ◽  
Shen Pouyan
2017 ◽  
Vol 53 (1) ◽  
pp. 198-205 ◽  
Author(s):  
Hikmet Sis ◽  
Ismail Bentli ◽  
Nizamettin Demirkiran ◽  
Ahmet Ekmekyapar

Author(s):  
Yuksel Abali ◽  
Salih U Bayca ◽  
Ayse E Guler

In this study, the dissolution kinetics of tincal in phosphoric acid solutions was investigated. The effects of reaction temperature, acid concentration, solid to liquid ratio, particle size and stirring speed were determined in the experiments. The results showed that the dissolution rate increased with increasing acid concentration, reaction temperature, stirring speed and increased with decreasing particle size and solid to liquid ratio. The dissolution rate was found to be based on the first order pseudo homogenous reaction model. The activation energy of the tincal in phosphoric acid solution was determined as 42.28 kJ.mol-1.


2019 ◽  
Vol 55 (1) ◽  
pp. 9-19
Author(s):  
Olfa Lachkar-Zamouri ◽  
Khemaies Brahim ◽  
Faten Bennour ◽  
Ismail Khattech

A mixture of phosphoric and sulfuric acid was used to investigate the dissolution kinetics of phosphate ore by Differential Reaction Calorimetry (DRC). The effect of the solid-to-iquid ratio, concentration, stirring speed, particle size and temperature of the reaction is examined. It was established that the dissolution rate increased with stirring speed and particle size. However, rising the olid-to-iquid ratio, temperature and concentration decreased the dissolution rate. It was determined that the dissolution rate fits in the first order of the pseudo-homogeneous reaction model. Two negative values of apparent activation energies were found in the range of 25 to 60?C. The experimental data were tested by graphical and statistical methods and it was found that the following models were best fitted for the experimental data and an empirical equation for the process was developed. -ln (1 ? x) = [2,2 E-09((S/L)0.75C -0.461G0.447(SS) 0.471exp (2671/T)]t. T? 40?C -ln (1 ? x) = [2,2 E-09((S/L)0.75C -0.461G0.447(SS) 0.471exp (6959/T)]t. T > 45?C


2014 ◽  
Vol 997 ◽  
pp. 651-654 ◽  
Author(s):  
Biao Wu ◽  
He Shang ◽  
Wen Cheng Gao ◽  
Jian Kang Wen

A new improved method is proposed for the leaching and extraction of niobium from a low-grade refractory niobium–tantalum ore.The ore was roasted and decomposed with concenrated H2SO4 then leached with dilute sulfuric acid. The effects of various factors, such as roasting temperature and time, acid to ore mass ratios,as well as particle size, on the dissolution kinetics of niobium were comprehensively investigated. The optimal conditions were particle size-38μm, roasting temperature 300°C,reacting time 2h and acid to ore mass ratio 1:1. The roasting residue reacted for 2 h with sulfuric acid in the ore/acid weight ratio of 3:1 at 90°C, the niobium was recoveried as high as 90.3%.


Chemosphere ◽  
2012 ◽  
Vol 88 (5) ◽  
pp. 591-597 ◽  
Author(s):  
Mark E. Fuller ◽  
Charles E. Schaefer ◽  
Christina Andaya ◽  
Volha Lazouskaya ◽  
Steve Fallis ◽  
...  

2006 ◽  
Vol 64 (2) ◽  
pp. 239-246 ◽  
Author(s):  
Qi Wang ◽  
Peter R. Ellis ◽  
Simon B. Ross-Murphy

1998 ◽  
Vol 76 (2) ◽  
pp. 233-238 ◽  
Author(s):  
Ferida Jendoubi ◽  
Arbi Mgaidi ◽  
Mohamed El Maaoui

1996 ◽  
Vol 35 (2) ◽  
pp. 465-474 ◽  
Author(s):  
Evagelos D. Economou ◽  
Nicholaos P. Evmiridis ◽  
Athanasios G. Vlessidis

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Nadeem Raza ◽  
Zafar Iqbal Zafar ◽  
Najam-ul-Haq

Ascorbic acid was used as leaching agent to investigate the dissolution kinetics of natural magnesite ore. The effects of various reaction parameters such as acid concentration, liquid-solid ratio, particle size, stirring speed, and temperature were determined on dissolution kinetics of the magnesite ore. It was found that the dissolution rate increased with increase in acid concentration, liquid-solid ratio, stirring speed, and temperature and decrease in the particle size of the ore. The graphical and statistical methods were applied to analyze the kinetic data, and it was evaluated that the leaching process was controlled by the chemical reaction, that is, . The activation energy of the leaching process was found to be 57.244 kJ mol−1 over the reaction temperature range from 313 to 343 K.


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