Dissolution of some polymers in aqueous solutions of urea, of its related compounds, and of tetraalkylammonium salts

1967 ◽  
Vol 25 (4) ◽  
pp. 531-536 ◽  
Author(s):  
Shuji Saito ◽  
Toshihiko Otsuka
1981 ◽  
Vol 46 (3) ◽  
pp. 693-700 ◽  
Author(s):  
Milan Strašák ◽  
Jaroslav Majer

The kinetics of oxidation of alkenes by thallic sulphate in aqueous solutions, involving the two reaction steps-the hydroxythallation and the dethallation - was studied, and the effect of salts on the kinetics was examined; this made it possible to specify more precisely the reaction mechanism and to suggest a qualitative model of the reaction coordinate. It was found that in homogeneous as well as in heterogeneous reaction conditions, the reaction can be accelerated appreciably by adding tetraalkylammonium salts. These salts not only operate as catalysts of the phase transfer, but also exert a significant kinetic effect, which can be explained with a simplification in terms of a stabilization of the transition state of the reaction.


1974 ◽  
Vol 47 (4) ◽  
pp. 1003-1007 ◽  
Author(s):  
Hiroji Aiba ◽  
Akira Yokoyama ◽  
Hisashi Tanaka

Langmuir ◽  
1996 ◽  
Vol 12 (2) ◽  
pp. 423-430 ◽  
Author(s):  
Zoltán Király ◽  
Imre Dékány ◽  
Erwin Klumpp ◽  
Hans Lewandowski ◽  
Hans D. Narres ◽  
...  

2021 ◽  
Vol 22 (11) ◽  
pp. 508-512
Author(s):  
A.P Mikhailovskaya ◽  
◽  
I.V Elokhin ◽  
S.S Lysova ◽  
◽  
...  

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