Absolute intensity measurements in the v4-fundamental band of 12CH4 at planetary atmospheric temperatures

1989 ◽  
Vol 41 (5) ◽  
pp. 345-349 ◽  
Author(s):  
P. Varanasi ◽  
S. Chudamani
1972 ◽  
Vol 27 (6) ◽  
pp. 989-995 ◽  
Author(s):  
G. Pletsch

Abstract Using a mixture of chlorine with krypton the continuous spectrum resulting from electron attachment to chlorine atoms is produced in a shock tube. Absolute intensity measurements lead to the detachment cross-section of the negative chlorine ion in the wavelength region between the long-wave threshold at 3434 Å and 2700 Å. The cross-section is compared with known experimental and theoretical values.


2017 ◽  
Vol 13 (S332) ◽  
pp. 332-345 ◽  
Author(s):  
Nadine Wehres ◽  
Bettina Heyne ◽  
Frank Lewen ◽  
Marius Hermanns ◽  
Bernhard Schmidt ◽  
...  

AbstractWe present first results of a new heterodyne spectrometer dedicated to high-resolution spectroscopy of molecules of astrophysical importance. The spectrometer, based on a room-temperature heterodyne receiver, is sensitive to frequencies between 75 and 110 GHz with an instantaneous bandwidth of currently 2.5 GHz in a single sideband. The system performance, in particular the sensitivity and stability, is evaluated. Proof of concept of this spectrometer is demonstrated by recording the emission spectrum of methyl cyanide, CH3CN. Compared to state-of-the-art radio telescope receivers the instrument is less sensitive by about one order of magnitude. Nevertheless, the capability for absolute intensity measurements can be exploited in various experiments, in particular for the interpretation of the ever richer spectra in the ALMA era. The ease of operation at room-temperature allows for long time integration, the fast response time for integration in chirped pulse instruments or for recording time dependent signals. Future prospects as well as limitations of the receiver for the spectroscopy of complex organic molecules (COMs) are discussed.


1984 ◽  
Vol 23 (22) ◽  
pp. 4067 ◽  
Author(s):  
V. Malathy Devi ◽  
Curtis P. Rinsland ◽  
D. Chris Benner

1979 ◽  
Vol 2 (4) ◽  
pp. 473-487 ◽  
Author(s):  
B. Baschiera ◽  
G. Basini ◽  
H. Bilokon ◽  
B. D'Ettorre Piazzoli ◽  
G. Mannocchi ◽  
...  

1981 ◽  
Vol 59 (10) ◽  
pp. 1367-1372 ◽  
Author(s):  
G. Chandraiah ◽  
G. R. Hébert

The absolute intensity A2–0 of the 2–0 band of carbon monoxide has been measured with helium and argon as pressure broadening gases at pressures up to 600 amagat. A separate band intensity value has been derived from the measurements of several P-branch line intensity data and the Herman–Wallis formula. The best value obtained is A2–0 = (2.11 ± 0.08) cm−2 amagat−1. The square of the rotationless matrix element, [Formula: see text] has been found to be (4.39 ± 0.02)10−5 D2, as estimated from the measured line intensity values.


The high temperature pyrolysis of simple organic molecules, CH 4 , CF 4 , CCl 4 and C 2 H 2 has been studied in a shock tube. Under conditions where the molecules are almost entirely dissociated into atoms, C 2 is observed to rise sharply to a peak concentration and then decline logarithmically with time. Concurrent observations in the infrared and of atomic carbon radiation are interpreted to indicate that the C 2 decay rate is apparently somehow coupled to the overall decomposition rate of the organic material. A simple steady state analysis is devloped to support this view and the overall rates of decomposition of the organic compounds, highly diluted with argon, are given. Absolute intensity measurements of the peak C 2 emission indicate that as much as 20% of the carbon atoms originally in the organic material form C 2 . The C 2 formation can be explained in terms of the reaction CX + C → C 2 + X, and in C 2 H 2 by direct decomposition.


1983 ◽  
Vol 22 (23) ◽  
pp. 3805 ◽  
Author(s):  
Curtis P. Rinsland ◽  
D. Chris Benner ◽  
Donald J. Richardson ◽  
R. A. Toth

1976 ◽  
Vol 19 (8) ◽  
pp. 780-786
Author(s):  
N. M. Tseitlin ◽  
L. V. Dmitrenko ◽  
D. A. Dmitrenko ◽  
E. A. Miller ◽  
V. V. Snegireva ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document