Maturation and bulk chemical properties of a suite of solid hydrocarbons

1995 ◽  
Vol 36 (3) ◽  
pp. 171
1995 ◽  
Vol 22 (1) ◽  
pp. 137-149 ◽  
Author(s):  
Charles R. Landis ◽  
John R. Castaño

1984 ◽  
Vol 40 ◽  
Author(s):  
P. O. Hahn ◽  
G. W. Rubloff ◽  
J. W. Bartha ◽  
F. Legoues ◽  
R. Tromp ◽  
...  

AbstractThis paper summarizes recent studies on metal-polymer interfaces for Cu, Ni and Cr on a high temperature polymer, polyimide. First some surface and bulk chemical properties of polyimide are described briefly, as measured with surface spectroscopies and verified by theoretical molecular orbital calculations. Then the chemical bonding and reactivity of the three interfaces are described and discussed in light of experimental observations of electronic structure, composition and interface morphology. The chemical trend of increasing reactivity of the interface is illustrated by comparing results from Cu to Cr.


2020 ◽  
Vol 641 ◽  
pp. A87
Author(s):  
Vanesa Ramírez ◽  
Alexander J. Cridland ◽  
Paul Mollière

Deciphering the bulk elemental abundances of exoplanetary atmospheres is not an easy task, yet it is crucial to understanding the formation history of planets. The purpose of this work is to show that the observability of TiO features at optical wavelengths in the transmission spectra of hot Jupiter atmospheres is sensitive to the bulk chemical properties of the atmosphere. To this end, we ran a grid of chemical models, which include TiO formation and destruction, for the ultra-hot Jupiter WASP-19b and an ultra-hot version of HD 209458b. We take into account non-equilibrium chemistry and changes in the temperature and pressure structure of these atmospheres caused by different C/O ratios. We calculated synthetic transmission spectra for these models, and studied the relative strengths of TiO and H2O features quantitatively. To compare with observations, we used a model-independent metric for molecular abundances, ΔZTiO−H2O/Heq, which has previously been used in observational studies of exoplanetary atmospheres. We find that with this metric we can differentiate between different chemical models and place constraints on the bulk carbon and oxygen abundances of the atmosphere. From chemical considerations, we expected the TiO abundance to depend on the bulk nitrogen. However, we find that changes in N/H do not result in changes in the resulting TiO. We applied our method to a set of known exoplanets that have been observed in the relevant optical wavelengths and find good agreement between low-resolution observations and our model for WASP-121b, marginally good agreement with WASP-79b, WASP-76b, and WASP-19b, and poorer agreement with HD 209458b. Our method will be particularly helpful for indirect studies of the bulk abundances of carbon and oxygen.


2017 ◽  
Vol 46 (14) ◽  
pp. 4554-4570 ◽  
Author(s):  
Eva-Maria Köck ◽  
Michaela Kogler ◽  
Thomas Götsch ◽  
Lukas Schlicker ◽  
Maged F. Bekheet ◽  
...  

Phase-pure stable structurally defective tetragonal ZrO2 with surprising surface and bulk chemical properties.


2018 ◽  
Author(s):  
Yunhua Chang ◽  
Yanlin Zhang ◽  
Jiarong Li ◽  
Chongguo Tian ◽  
Linlin Song ◽  
...  

Abstract. The interpretation of tropospheric cloud formation rests on understanding the sources and processes affecting aerosol constituents of the atmosphere that are preserved in cloudwater. However, this challenge is difficult to be quantitatively addressed based on the sole use of bulk chemical properties. Nitrogenous aerosols, mainly ammonium (NH4+) and nitrate (NO3−), play an important role in tropospheric cloud formation. Here we collected cloudwater samples at the summit of Mt. Tai (1545 m above sea level) in Eastern China during a long-lasting biomass burning (BB) event, and measured for the first time the isotopic compositions (mean ± 1σ) of cloudwater nitrogen species (δ15N-NH4+ = −6.53 ± 4.96 ‰, δ15N-NO3− = −2.35 ± 2.00 ‰, δ18O-NO3− = 57.80 ± 4.23 ‰), allowing insights into their sources and potential transformation mechanism within the clouds. Large contributions of BB to the cloudwater NH4+ (32.9 ± 4.6 %) and NO3− (28.2 ± 2.7 %) inventories were confirmed through a Bayesian isotopic mixing model, coupled with our newly-developed computational quantum chemistry module. Despite an overall reduction in total anthropogenic NOx emission due to effective emission control actions and stricter emission standards for vehicles, the observed cloud δ15N-NO3− values suggest that NOx emissions from transportation may have exceeded emissions from coal combustion. δ18O-NO3− values imply that the reaction of OH with NO2 is the dominant pathway of NO3− formation (57 ± 11 %), yet the contribution of heterogeneous hydrolysis of dinitrogen pentoxide was almost as important (43 ± 11 %).


Author(s):  
Stewart Brown

Clustered together in the centre of the Periodic Table lie six remarkable elements, six metals without which the world would be a completely different place. Think about the food you eat, your computer, your car, your mobile phone or even the clothes you wear. At some stage during their production one or more of these six rare metals has been utilised, whether as a catalyst or perhaps in the end product itself. The platinum group metals (pgms) play an essential role in our modern lifestyles.Platinum, palladium, rhodium, ruthenium, iridium and osmium are rare, expensive and have a unique combination of incredibly useful properties. For example, high thermal stability, corrosion and oxidation resistance and the ability to catalyse a broad range of chemical reactions make them indispensable in processes such as petroleum refining, nitric acid, bulk chemical production and glass manufacture. They are also to be found in a diverse range of products such as the hard disk drives in computers and data storage centres, the airbag in your car or the jet engine that carries you to your holiday destination. Apart from their chemical properties the pgms and platinum and palladium in particular have found favour in both the jewellery and investment markets. Platinum has for many years been marketed as a premium jewellery metal, rarer and more precious even than gold.


1983 ◽  
Vol 27 ◽  
Author(s):  
Marc-A. Nicolet ◽  
T. C. Banwell ◽  
B. M. Paine

ABSTRACTWe consider ion mixing in the low temperature regime, where it is insensitive to temperature. Mixing of most thin markers is Gaussian, independent of irradiation flux, and varies linearly with fluence. However, the mixing in some media varies widely between markers of similar mass and appears to correlate with thermal diffusion constants. In bilayer systems, the profile of long-range mixing is exponential, and the number of mixed atoms scales linearly with fluence. This can be modeled successfully with simple collisional theory. Short range mixing scales with the square root of the fluence, but again shows strong correlations with known bulk chemical properties. We conclude that chemical driving forces and low energy transport mechanisms such as interstitial migration play major roles in ion mixing, even at low temperatures.


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