Спектральные оптические свойства керамических нанопористых мембран на основе анодного оксида алюминия и покрытия из серебра в парах аммиака

Spectral optical properties of synthesized ceramic nanoporous membranes based on anodic aluminum oxide coated silver in saturated ammonia gas flow have been experimentally investigated. Based on the measured transmission spectra and detected interference part of the spectra in wavelength range from 550 to 900 nm, temporal and spectral dependencies of the effective optical thickness and its changes in non-equilibrium conditions were obtained due to adsorption of ammonia molecules on silver film surface. According to detected and measured interference maximum shifts up to 14 nm in transmission spectra of Al2O3 + Ag membranes in ammonia gas flow, the possibility of constructing a selective interferometric optical sensors with 10 − 15 min response time is shown.

Исследование магнитных свойств ферроборатов неодима и самария методом спектроскопического эрбиевого зонда

Iron borates NdFe3(BO3)4 and SmFe3(BO3)4 activated with 1% erbium, with a huntite structure (space symmetry group R32) were investigated by the method of erbium spectroscopic probe. From an analysis of the temperature dependence of the transmission spectra in the region of the 4I15/2→4I13/2 transition in the Er3+ ion, it was found that both studied compounds order antiferromagnetically at TN ≈ 33 K into an easy-plane magnetic structure. No other phase transitions were found.

Химическое сжатие, структурная нестабильность и ИК-активные фононы в ряду редкоземельных аналогов францисита Cu-=SUB=-3-=/SUB=-RE(SeO-=SUB=-3-=/SUB=-)-=SUB=-2-=/SUB=-O-=SUB=-2-=/SUB=-Cl

ATR and transmission spectra of a series of rare-earth francisite-like phases Cu3RE(SeO3)2O2Cl (RE is a rare earth element, RE = Nd, Sm, Eu, Gd, Dy, Ho, Tm, Yb) were studied. The frequencies of the IR-active phonons of the crystals under study were determined. In the dependences of phonon frequencies on the ionic radius in a series of isostructural compounds, two tendencies are observed: a hardening of frequencies due to an increase in chemical pressure and a softening of the vibration frequencies, in which rare-earth ions are involved, due to an increase in the mass of a specific rare-earth ion. In the Cu3Dy(SeO3)2O2Cl crystal, an anomalous softening of low-frequency phonons at low temperatures was observed, which was apparently associated with the structural instability of the compound.

Оптические и фотолюминесцентные свойства тонкой пленки оксида цинка на подложке из тантала лития

Presents the results of the study of the structural, optical and photo luminescent properties of the thin films ZnO on LiNbO3 substrate. The results of X-ray structural analysis of a zinc oxide film synthesized on a single-crystal LiTaO3 substrate and on a KU-1 quartz substrate are presented. Present the transmission spectra, reflection spectra and the spectral dependence of zinc oxide thin films on substrate LiTaO3 and the structure of ZnO-SiO2 in the ultraviolet and visible spectral ranges.

Growing of bulk β-(Al x Ga1-x )2O3 crystals from the melt by Czochralski method and investigation of their structural and optical properties

Bulk (Al x Ga1-x )2O3 crystals with an Al fraction x in the range from 0.0 to 0.23 were successfully grown by the Czochralski method. An increase in the band gap from 4.7 eV to 5.1 eV with the rise of the Al content was demonstrated by analyzing optical transmission spectra. The crystal quality of the obtained samples was controlled by X-ray diffractometry. The appearance of crystal`s mosaic blockness was found for the Al fraction x above 0.05.

Deep Learning on Synthesized Sensor Characteristics and Transmission Spectra Enabling MEMS-Based Spectroscopic Gas Analysis beyond the Fourier Transform Limit

Miniaturized Fourier transform infrared spectrometers serve emerging market needs in many applications such as gas analysis. The miniaturization comes at the cost of lower performance than bench-top instrumentation, especially for the spectral resolution. However, higher spectral resolution is needed for better identification of the composition of materials. This article presents a convolutional neural network (CNN) for 3X resolution enhancement of the measured infrared gas spectra using a Fourier transform infrared (FTIR) spectrometer beyond the transform limit. The proposed network extracts a set of high-dimensional features from the input spectra and constructs high-resolution outputs by nonlinear mapping. The network is trained using synthetic transmission spectra of complex gas mixtures and simulated sensor non-idealities such as baseline drifts and non-uniform signal-to-noise ratio. Ten gases that are relevant to the natural and bio gas industry are considered whose mixtures suffer from overlapped features in the mid-infrared spectral range of 2000–4000 cm−1. The network results are presented for both synthetic and experimentally measured spectra using both bench-top and miniaturized MEMS spectrometers, improving the resolution from 60 cm−1 to 20 cm−1 with a mean square error down to 2.4×10−3 in the transmission spectra. The technique supports selective spectral analysis based on miniaturized MEMS spectrometers.

Alfnoor: Assessing the Information Content of Ariel's Low-resolution Spectra with Planetary Population Studies

The Ariel Space Telescope will provide a large and diverse sample of exoplanet spectra, performing spectroscopic observations of about 1000 exoplanets in the wavelength range 0.5–7.8 μm. In this paper, we investigate the information content of Ariel’s Reconnaissance Survey low-resolution transmission spectra. Among the goals of the Ariel Reconnaissance Survey is also to identify planets without molecular features in their atmosphere. In this work, (1) we present a strategy that will allow us to select candidate planets to be reobserved in Ariel’s higher-resolution tier, (2) we propose a metric to preliminary classify exoplanets by their atmospheric composition without performing an atmospheric retrieval, and (3) we introduce the possibility to find other methods to better exploit the data scientific content.

The influence of the surface density of oriented nickel networks on the conducting electrode’s optical transparency

This study is part of the work on the creation of a transparent conductive coating based on oriented nanonetwork and submicron nickel fibres. It is devoted to finding the optimal values of electrical conductivity and optical transparency of the developed coating. In this work, we study the transmission spectra of oriented nickel networks on a glass substrate in the UV, visible and near-IR regions at different amounts of deposited metal. An exciting feature of the coating was discovered: in the range of 950 nm and above, there is a "bend" of the transmission spectrum downward. This bend (increased absorption of radiation in the near-IR region) is observed only in the presence of nickel nanonetwork and is not typical for a pure submicron network.

Transmission spectra of transparent electrodes based on oriented platinum nanowires at various concentrations of the metal used

The paper investigates the optical transparency dependence of a coating based on an oriented network of platinum nanowires on the amount of metal used. Oriented platinum nanowires on a glass surface are produced by chemical deposition from an aqueous hexachloroplatinic acid solution. The topography of the deposited metal layer on glass is visualized using atomic force microscopy. Optical transparency was investigated with a spectrophotometer. In almost the entire region of optical radiation, the transparency is approximately 98%. The absorption spectrum shows that the absorption coefficient increases sharply in the near UV region.