Influence of sodium silicate on the rheological behaviour of clay suspensions—Application of the ternary Bingham model

1988 ◽  
Vol 3 (4) ◽  
pp. 323-335 ◽  
Author(s):  
L. Garrido ◽  
J. Gainza ◽  
E. Pereira
2017 ◽  
Vol 43 (5) ◽  
pp. 2562 ◽  
Author(s):  
G.E Christidis ◽  
P. Katsiki ◽  
A. Pratikakis ◽  
G. Kacandes

In this contribution we examine the rheological properties of palygorskite rich clays from the Ventzia Basin, W. Macedonia, Greece. The clays consist of palygorskite and/or dioctahedral Fe-rich smectite (nontronite) and quartz as main components, and serpentine, amphibole and sepiolite as minor constituents. The apparent and plastic viscosity and yield point increase with increasing concentration of clay in the suspension. Flow is Newtonian for 1% suspensions, becoming gradually Bingham plastic (3% clay suspensions) and then pseudoplastic with yield point described by the Herschel Bulckley flow model. In the case of suspensions cf smectite-free clays Bingham plastic flow behaviour was not observed. Addition of 1M NaCl electrolyte deteriorates the rheological behaviour of the smectite-bearing palygorskite clays but it does not affect significantly the smectite-free, palygorskite rich clays. The different rheological properties of the palygorskite compared to smectite is due to the different morphological and crystal-chemical properties of these two minerals. It is suggested that the palygorskite-rich clays can be used successfully as drilling muds in seawater based drilling fluids, in which smectite-based drilling muds tend to flocculate.


Author(s):  
Piotr Izak ◽  
Longin Ogłaza ◽  
Włodzimierz Mozgawa ◽  
Joanna Mastalska-Popławska ◽  
Agata Stempkowska

2020 ◽  
Author(s):  
Abdelhakim Benhamouda ◽  
João Castro-Gomes ◽  
Luiz Pereira-de-Oliveira

To determine the properties of paste, mortar or concrete, it is necessary to understand its rheological behaviour first. This study discusses the effect of the activator/precursor ratio on the rheological properties of the alkali-activated paste. The pastes consisted of a mix of 70 % of tungsten mining waste mud, 15% waste glass and 15% of metakaolin. This mix was activated by combining sodium hydroxide and sodium silicate. Five activator/precursor (a/p) ratios were studied: 0.37, 0.38, 0.39, 0.40 and 0.41. The result obtained shows that the rheology of the pastes is affected by the activator/precursor ratio. The rheological behaviour of the paste fits the Bingham model. The yield stress (τ0) and plastic viscosity (μ) increase inversely with the activator/precursor ratio (e.g. a/p=0.37 gives τ0=84.19 and μ=0.4185; a/p=0.41 gives τ0=30.389 and μ=0.2937). The workability increases proportionally with the activator/precursor ratio (e.g. a/p=0.37 gives a slump=133 mm; a/p=0.41 gives a slump=158 mm). The compressive strength decreases when the activator/precursor ratio increases (e.g. at 28 days for a/p=0.37, the compressive strength was 19.6 MPa; for a/p=0.41, the compressive strength was 13 MPa). Finally, the ideal ratios were 0.38 and 0.39.


2005 ◽  
Vol 123 ◽  
pp. 341-344
Author(s):  
A. Khaldoun ◽  
F. González-Caballero ◽  
J. G. López-Durán ◽  
N. Mahrach ◽  
M. L. Kerkeb

TAPPI Journal ◽  
2010 ◽  
Vol 9 (2) ◽  
pp. 23-29 ◽  
Author(s):  
Wei-ming Wang ◽  
Zai-sheng Cai ◽  
Jian-yong Yu

Degumming of pre-chlorite treated jute fiber was studied in this paper. The effects of sodium hydroxide concentration, treatment time, temperature, sodium silicate concentration, fiber-to-liquor ratio, penetrating agent TF-107B concentration, and degumming agent TF-125A concentration were the process conditions examined. With respect to gum decomposition, fineness and mechanical properties, sodium hydroxide concentration, sodium silicate concentration, and treatment time were found to be the most important parameters. An orthogonal L9(34) experiment designed to optimize the conditions for degumming resulted in the selection of the following procedure: sodium hydroxide of 12g/L, sodium silicate of 3g/L, TF-107B of 2g/L, TF-125A of 2g/L, treatment time of 105 min, temperature of 100°C and fiber to liquor ratio of 1:20. The effect of the above degumming process on the removal of impurities was also examined and the results showed that degumming was an effective method for removing impurities, especially hemicellulose.


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