Recycling of Mining Waste in the Production of Masonry Units

Masonry units made of clay or Autoclaved Aerated Concrete (AAC) are widely used in constructions from Romania and other countries. Masonry units with superior mechanical and thermal characteristics can improve the energy efficiency of buildings, especially when they are used as the main solutions for building envelope construction. Their production in recent years has increased vertiginously to meet the increased demand. Manufactured with diversified geometries, different mechanical and/or thermal characteristics have a high volume in the mass of the building and a major influence in their carbon footprint. Starting from the current context regarding the target imposed by the long-term strategy of built environment decarbonization, the aim of the paper is to analyze the potential of reusing mining waste in the production of masonry units. Mining waste represents the highest share of waste generated at national level and may represent a valuable resource for the construction industry, facilitating the creation of new jobs and support for economic development. This review presents the interest in integrating mining wastes in masonry unit production and the technical characteristics of the masonry units in which they have been used as raw materials in different percentages. Critical assessment framework using SWOT analysis highlights the key sustainability aspects (technical, environmental, social, economic) providing a comprehensive and systematic analysis of the advantages and disadvantages regarding the integration of mining waste as secondary raw materials into masonry units production.

Simulation of Contaminants Transport in Groundwater From Nickel Mining Waste Dump Southeast Sulawesi

The irregularities of nickel resource mining in Indonesia cause many serious environmental problems. Piles of leftover rocks on nickel mining waste dumps have the potential to be a source of heavy metal seepage into the water. This study was conducted to assess the impact of nickel mining in the Langgikima Subdistrict of the North Konawe Regency of Southeast Sulawesi Province. The focus is to assess the migration of hexavalent chromium (Cr6+) and iron (Fe) using MT3DMS to model the transport of solutes. The study's goal was to identify cr6+ and Fe concentrations in waste dumps and predict the spread of contaminants over a 20-year period of time. XRF (X-Ray Fluorescence) is done to determine the content of elements and minerals in rocks. Toxicity Characteristics Leaching Procedure (TCLP) is performed to estimate the concentration of Cr6+ and Fe in waste dumps. AAS (Atomic Absorption Spectrophotometer) to find out the content of Cr6+ and Fe in surface water and land water samples. The results showed the highest concentrations of Cr6+ of 0.0462 mg/L and Feat 0.8709 mg/L. Simulations without compacted clay coatings, Cr6+ and Fe contaminants could be transported consecutively by 2.7 km and 2.42 km while simulations used compacted clay layers with a hydraulic conductivity of 1 × 10−9 m/s of Cr6+ and Fe contaminants could be transported consecutively by 0.412 km and 0.467 km. It can therefore be concluded that heavy metals in the remaining rock piles from the waste dump can be transported into groundwater, and the action of using a compacted layer of clay must be taken to prevent contaminant migration into groundwater.

Mining Waste as a Potential Additional Source of HREE and U for the European Green Deal: A Case Study of Bangka Island (Indonesia)

The European Commission has adopted the European Green Deal strategy, which aims to achieve climate neutrality in the EU by 2050. To achieve this goal, it is necessary to shift the economy toward the use of green and renewable energy. Critical raw materials (CRMs), Li, Co, REE, Te, Sc and others, are used in renewable energy sources (RES) production. The EU lacks its own CRM deposits, and additionally, the access to already identified deposits is limited, which is making the EU countries search for alternative CRM sources. One such source of CRMs may be mining waste generated on the Indonesian island of Bangka as a result of processing cassiterite-bearing sands. Studies of the mineral composition of the waste using the XRD method reveal rich contents of xenotime (0.79–17.55 wt%), monazite (1.55–21.23 wt%), zircon (1.87–64.35 wt%) and other minerals, carriers of valuable metals, such as Sn, Ti, Nb, Ta. The point mineral chemistry analyses were performed using EPMA. Xenotime is the main carrier of heavy rare earth elements (HREE), especially the “most critical” HREEs: Gd2O3 (1.42–7.16 wt%), Dy2O3 (2.28–11.21 wt%), Er2O3 (2.44–7.85 wt%), and Yb2O3 (1.71–7.10 wt%). Xenotime is characterized by a complex internal structure resulting from metasomatic processes occurring during their formation. In SEM-BSE imaging, they show zonation of internal structure, which is the effect of an HREE, Y, Si and U substitution in the crystal structure. On the other hand, thorite ThSiO4 and uranothorite (Th,U)SiO4 inclusions are present in xenotimes. The ICP-MS/ES studies of tailings reveal very high contents of HREE + Y (up to 7.58 wt%), U (up to 0.11), Th (up to 0.75 wt%) and Sc (132 ppm). A CRM source diversification is part of the strategy to ensure the security of raw materials for countries of the European Union and the green transformation of the continent. Bilateral EU–Indonesia cooperation in the geological exploration and development of primary and secondary sources may contribute to an increase in the supply of HREEs to the global market.

Studying the mineral composition of gold mining waste

The experimental research and analysis of the various technological schemes for processing of refractory gold ores allowed to be considered one of the most promising proposed autoclave-thiourea and autoclave-hypochlorite technological schemes.