Compared with the traditional air spraying technique and electroplate method, the coating defects of bonded NdFeB magnet, such as the workpiece hanging point, the pinhole, the bubble, have been solved by using the composite powder electrostatic spraying as surface treatment technology, along with the EE epoxy paint as primer coating and PU polyurethane paint as surface coating. The coating of this composite powder electrostatic spraying is uniform and compact, and the coating has strong adhesion and corrosion resistance. This paper gives a detailed introduction to the composite powder electrostatic spraying, including the choice of some important parameters and the unique hanging tools of composite powder electrostatic spraying.