Propene hydrogenation on low-temperature reduced Pt/TiO2. Effects of TiO2 phases and H2 treatment on specific catalytic activity

1994 ◽  
Vol 94 (3) ◽  
pp. 299-310 ◽  
Author(s):  
G. Cocco ◽  
R. Campostrini ◽  
M.A. Cabras ◽  
G. Carturan
Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 641
Author(s):  
Lukasz Wolski ◽  
Grzegorz Nowaczyk ◽  
Stefan Jurga ◽  
Maria Ziolek

The aim of the study was to establish the influence of a co-precipitation agent (i.e., NaOH–immediate precipitation; hexamethylenetetramine/urea–gradual precipitation and growth of nanostructures) on the properties and catalytic activity of as-synthesized Au-CeO2 nanocomposites. All catalysts were fully characterized with the use of XRD, nitrogen physisorption, ICP-OES, SEM, HR-TEM, UV-vis, XPS, and tested in low-temperature oxidation of benzyl alcohol as a model oxidation reaction. The results obtained in this study indicated that the type of co-precipitation agent has a significant impact on the growth of gold species. Immediate co-precipitation of Au-CeO2 nanostructures with the use of NaOH allowed obtainment of considerably smaller and more homogeneous in size gold nanoparticles than those formed by gradual co-precipitation and growth of Au-CeO2 nanostructures in the presence of hexamethylenetetramine or urea. In the catalytic tests, it was established that the key factor promoting high activity in low-temperature oxidation of benzyl alcohol was size of gold nanoparticles. The highest conversion of the alcohol was observed for the catalyst containing the smallest Au particle size (i.e., Au-CeO2 nanocomposite prepared with the use of NaOH as a co-precipitation agent).


1986 ◽  
Vol 51 (8) ◽  
pp. 1571-1578 ◽  
Author(s):  
Alois Motl

The radiation catalytic properties of the BASF K-3-10 catalyst were studied, namely the dependence of these effects on the time interval between the catalyst irradiation and the reaction itself and also on the length of the catalyst use. The catalytic effects decrease exponentially with the interval between the irradiation and the reaction if the catalyst is kept in the presence of air. The stability of effects induced by various types of radiations increases in the sequence beta radiation - gamma radiation - fast neutrons. The radiation catalytic effect stability in the reaction increases in the same sequence.


2021 ◽  
Vol 784 ◽  
pp. 139107
Author(s):  
Xiongjian Li ◽  
Hao Hu ◽  
Piao Chen ◽  
Fang Chen ◽  
Shuijin Yang

2015 ◽  
Vol 5 (7) ◽  
pp. 3706-3713 ◽  
Author(s):  
Dae-Woon Jeong ◽  
Hyun-Suk Na ◽  
Jae-Oh Shim ◽  
Won-Jun Jang ◽  
Hyun-Seog Roh

The catalytic activity of Cu based catalysts is correlated to its amount of defect oxygen which strongly depends on the ratio of CeO2–ZrO2.


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