Effect of translation on the prediction of saturated densities of binary mixtures with a peng-robinson equation of state

A review of methods is presented which allow to determine the P-V-T behaviour of gas mixtures. This review is based on the computations performed for about 2 200 P-V-T-X data of 12 binary mixtures. The method of combination of the equation-of-state constants, the Joffe method and the modified Bartlett rule proved to be the most suitable.

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Critical consolute point in hard-sphere binary mixtures: Effect of the value of the eighth and higher virial coefficients on its location

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc2009510 ◽

2010 ◽

Vol 75 (3) ◽

pp. 359-369 ◽

Cited By ~ 6

Author(s):

Mariano López De Haro ◽

Anatol Malijevský ◽

Stanislav Labík

Keyword(s):

Equation Of State ◽

Binary Mixtures ◽

Hard Sphere ◽

Hard Spheres ◽

Virial Coefficients ◽

Fluid Mixture ◽

Binary Fluid ◽

Virial Series ◽

Consolute Point ◽

Critical Constants

Various truncations for the virial series of a binary fluid mixture of additive hard spheres are used to analyze the location of the critical consolute point of this system for different size asymmetries. The effect of uncertainties in the values of the eighth virial coefficients on the resulting critical constants is assessed. It is also shown that a replacement of the exact virial coefficients in lieu of the corresponding coefficients in the virial expansion of the analytical Boublík–Mansoori–Carnahan–Starling–Leland equation of state, which still leads to an analytical equation of state, may lead to a critical consolute point in the system.

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New volume translation functions for biodiesel density prediction with the Peng-Robinson Equation of state in terms of its raw materials

Fuel ◽

10.1016/j.fuel.2021.120254 ◽

2021 ◽

Vol 293 ◽

pp. 120254

Author(s):

Gutierri Salgueiro ◽

Marcellus de Moraes ◽

Fernando Pessoa ◽

Raquel Cavalcante ◽

André Young

Keyword(s):

Equation Of State ◽

Raw Materials ◽

Density Prediction ◽

Volume Translation ◽

Robinson Equation

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Revisiting Kelvin equation and Peng–Robinson equation of state for accurate modeling of hydrocarbon phase behavior in nano capillaries

Scientific Reports ◽

10.1038/s41598-021-86075-8 ◽

2021 ◽

Vol 11 (1) ◽

Author(s):

Ilyas Al-Kindi ◽

Tayfun Babadagli

Keyword(s):

Experimental Data ◽

Surface Tension ◽

Equation Of State ◽

Phase Behavior ◽

Pore Radius ◽

Microfluidic Chips ◽

Tight Sandstone ◽

Kelvin Equation ◽

Rock Samples ◽

Robinson Equation

AbstractThe thermodynamics of fluids in confined (capillary) media is different from the bulk conditions due to the effects of the surface tension, wettability, and pore radius as described by the classical Kelvin equation. This study provides experimental data showing the deviation of propane vapour pressures in capillary media from the bulk conditions. Comparisons were also made with the vapour pressures calculated by the Peng–Robinson equation-of-state (PR-EOS). While the propane vapour pressures measured using synthetic capillary medium models (Hele–Shaw cells and microfluidic chips) were comparable with those measured at bulk conditions, the measured vapour pressures in the rock samples (sandstone, limestone, tight sandstone, and shale) were 15% (on average) less than those modelled by PR-EOS.

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