Raman spectroscopic study of silver nitrate solutions in acrylonitrile at different temperatures (238–343 K)

Author(s):  
J.M. Alía ◽  
H.G.M. Edwards ◽  
J. Moore
1991 ◽  
Vol 56 (10) ◽  
pp. 2142-2147
Author(s):  
Ivo Sláma

The dependence of the induction period of crystallization on supercooling was examined for the silver nitrate-ethylene glycol system over the concentration region of silver nitrate lome fraction of 0 to 0.12. Addition of AgNO3 to ethylene glycol was found to increase considerably the critical induction period of crystallization, although to a lesser extent than Ca(NO3)2, CaCl2, ZnCl2, LiCl and LiNO3 do. The effect of these salts on the critical induction period of crystallization in dimethylsulfoxide, dimethylformamide, dimethylacetamide and methanol was compared in terms of the solvent-rich composition limit of the glass-forming ability. By using the TTT(Time-Temperature-Transformation) theory, it has been deduced that the effect of the salts on the critical induction period of crystallization of ethylene glycol is probably due to the different dependences of viscosity on their concentration in ethylene glyco in the supercooling region.


2021 ◽  
Vol 118 (13) ◽  
pp. 133101
Author(s):  
Sanghyun Kim ◽  
Donghyeon Lee ◽  
Binbin Wang ◽  
Shang-Jie Yu ◽  
Kenji Watanabe ◽  
...  

2021 ◽  
Vol 22 (10) ◽  
pp. 5380
Author(s):  
Boris A. Kolesov

The work outlines general ideas on how the frequency and the intensity of proton vibrations of X–H×××Y hydrogen bonding are formed as the bond evolves from weak to maximally strong bonding. For this purpose, the Raman spectra of different chemical compounds with moderate, strong, and extremely strong hydrogen bonds were obtained in the temperature region of 5 K–300 K. The dependence of the proton vibrational frequency is schematically presented as a function of the rigidity of O-H×××O bonding. The problems of proton dynamics on tautomeric O–H···O bonds are considered. A brief description of the N–H···O and C–H···Y hydrogen bonds is given.


1978 ◽  
Vol 9 (40) ◽  
Author(s):  
J. MEDEMA ◽  
C. VAN STAM ◽  
V. H. J. DE BEER ◽  
A. J. A. KONINGS ◽  
D. C. KONINGSBERGER

2014 ◽  
Vol 66 ◽  
pp. 123-131 ◽  
Author(s):  
Daniel T. Berhe ◽  
Søren B. Engelsen ◽  
Marchen S. Hviid ◽  
René Lametsch

Sign in / Sign up

Export Citation Format

Share Document