Volume-specific surface area by gas adsorption analysis with the BET method

One of the main applications of ceria-based (CeO2) ceramics is the manufacturing of Intermediate Temperature Solid Oxide Fuel Cells electrolytes. In order to improve ionic conductivity and densification of these materials various powder synthesis routes have been studied. In this work powders with composition Ce0.8(SmGd)0.2O1.9 have been synthesized by coprecipitation and hydrothermal treatment. A concentrate of rare earths containing 90wt% of CeO2 and other containing 51% of Sm2O3 and 30% of Gd2O3, both prepared from monazite processing, were used as precursor materials. The powders were characterized by X-ray diffraction, scanning and transmission electron microscopy, agglomerate size distribution by laser scattering and specific surface area by gas adsorption. Ceramic sinterability was evaluated by dilatometry and density measurements by Archimedes method. High specific surface area powders (~100m2/g) and cubic fluorite structure were obtained after hydrothermal treatment around 200°C. Ceramic densification was improved when compared to the one prepared from powders calcined at 800°C.

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Measurement of the specific surface area of fine powders. A comparison of the ‘gas-adsorption’ and ‘air-permeability’ methods

Journal of Applied Chemistry ◽

10.1002/jctb.5010071107 ◽

2007 ◽

Vol 7 (11) ◽

pp. 610-613 ◽

Cited By ~ 5

Author(s):

D. H. Mathews

Keyword(s):

Specific Surface ◽

Surface Area ◽

Specific Surface Area ◽

Gas Adsorption ◽

Air Permeability ◽

Fine Powders

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Preparation of Zirconia Nanofibers by Electrospinning and Calcination with Zirconium Acetylacetonate as Precursor

Polymers ◽

10.3390/polym11061067 ◽

2019 ◽

Vol 11 (6) ◽

pp. 1067 ◽

Cited By ~ 5

Author(s):

Vyacheslav V. Rodaev ◽

Svetlana S. Razlivalova ◽

Andrey O. Zhigachev ◽

Vladimir M. Vasyukov ◽

Yuri I. Golovin

Keyword(s):

Specific Surface ◽

Surface Area ◽

Specific Surface Area ◽

Heterogeneous Catalysts ◽

Tetragonal Zirconia ◽

Nitrogen Adsorption ◽

Average Diameter ◽

High Specific Surface Area ◽

X Ray ◽

Adsorption Analysis

For the first time, zirconia nanofibers with an average diameter of about 75 nm have been fabricated by calcination of electrospun zirconium acetylacetonate/polyacrylonitrile fibers in the range of 500–1100 °C. Composite and ceramic filaments have been characterized by scanning electron microscopy, thermogravimetric analysis, nitrogen adsorption analysis, energy-dispersive X-ray spectroscopy, and X-ray diffractometry. The stages of the transition of zirconium acetylacetonate to zirconia have been revealed. It has been found out that a rise in calcination temperature from 500 to 1100 °C induces transformation of mesoporous tetragonal zirconia nanofibers with a high specific surface area (102.3 m2/g) to non-porous monoclinic zirconia nanofibers of almost the same diameter with a low value of specific surface area (8.3 m2/g). The tetragonal zirconia nanofibers with high specific surface area prepared at 500 °C can be considered, for instance, as promising supports for heterogeneous catalysts, enhancing their activity.

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Influence of Acid Treatment on the Loading and Release Behavior of Halloysite with 2-Mercaptobenzothiazole

Journal of Nanoscience and Nanotechnology ◽

10.1166/jnn.2019.16616 ◽

2019 ◽

Vol 19 (11) ◽

pp. 7178-7184 ◽

Cited By ~ 2

Author(s):

Xuteng Xing ◽

Jihui Wang ◽

Qiushi Li ◽

Wenbin Hu

Keyword(s):

Specific Surface ◽

Surface Area ◽

Specific Surface Area ◽

Acid Treatment ◽

Gas Adsorption ◽

Treatment Time ◽

Halloysite Nanotubes ◽

Tubular Structure ◽

Internal Diameter ◽

Release Behavior

Halloysite nanotubes (HNTs) are natural clay minerals with a tubular structure. They have attracted considerable attention as a potential nanocontainer due to their abundance, biocompatibility and nontoxicity. In this study, HNTs were handled with H2SO4 at 70 °C. The morphology and structure of these acid-treated and original HNTs were investigated by scanning electron microscopy (SEM), energy dispersion spectrum (EDS), transmission electron microscope (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR), and their specific surface area was determined by automatic gas adsorption analyzer. The loading efficiency and release behavior of acid-treated HNTs for 2-Mercaptobenzothiazole (MBT) were investigated by UV-vis spectrophotometer. Results show that acid-treated HNTs retained their tubular structure, but their internal diameter expanded by 35–37 nm after 32 h of acid treatment. After 72 h of acid treatment, HNTs can be transferred into amorphous silica nanotubes. Moreover, the specific surface area of these HNTs samples initially increased with the increase in acid treatment time but then started to decrease after 32 h. The specific surface area of acid-treated HNTs at 32 h can reach 251.6 m2/g, which was much higher than that for untreated HNTs (55.3 m2/g). In addition, the loading capacity of acid-treated HNTs can reach 32.1% for HNTs-32, which is about three times higher than that of original HNTs. The acid treatment has slight effect on the release behavior.

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The whole-aperture pore-structure characteristics of marine-continental transitional shale facies of the Taiyuan and Shanxi Formations in the Qinshui Basin, North China

Interpretation ◽

10.1190/int-2018-0157.1 ◽

2019 ◽

Vol 7 (2) ◽

pp. T547-T563 ◽

Cited By ~ 2

Author(s):

Jiyuan Wang ◽

Shaobin Guo

Keyword(s):

High Pressure ◽

Specific Surface ◽

Pore Structure ◽

Surface Area ◽

Specific Surface Area ◽

Gas Adsorption ◽

Pore Morphology ◽

Qinshui Basin ◽

Mercury Intrusion ◽

Structure Characteristics

To systematically study the whole-aperture pore-structure characteristics of the marine-continental transitional shale facies in the Upper Palaeozoic Taiyuan and Shanxi Formations of the Qinshui Basin, we have collected a total of 11 samples for high-pressure mercury intrusion, low-pressure gas adsorption ([Formula: see text] and [Formula: see text]), nuclear magnetic resonance (NMR), and field-emission scanning electron microscopy with argon-ion polishing experiments to determine the pore morphology and distribution characteristics of shale samples in detail and to perform quantitative analyses. Then compared the pore-development characteristics of the Taiyuan Formation samples with those of the Shanxi Formation to determine which is preferable. The experimental results indicate that the shale samples of the Qinshui Basin mainly develop three types of pores: organic pores, intergranular pores, and microfractures. High-pressure mercury intrusion and gas-adsorption experiments indicate that the pore-size distributions exhibit multiple peaks. The samples contained varying proportions of macropores, mesopores, and micropores, among which the former two are dominant, accounting for approximately 85% of the total pore volume, whereas micropores account for only 15%. However, mesopores and micropores dominate the specific surface area; between them, the micropores are much more prevalent, accounting for more than 99% of the total specific surface area. Macropores contribute less than 1% of the specific surface area and therefore can be neglected. The pore morphology resembles the slit type parallel platy pores with a ballpoint pen structure. The NMR [Formula: see text] spectra have multiple-peak values. In addition, the large difference between the curved areas before and after centrifugation indicates that the samples contain a large proportion of mesopores and macropores, which is consistent with the results presented above. The results demonstrate that the development of pores in the Taiyuan Formation is better than that in the Shanxi Formation.

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