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<p>The earliest secondary atmosphere of a rocky planet originates from extensive volatile release during one or more magma ocean epochs that occur during and after the assembly of the planet. Magma oceans set the stage for the long-term evolution of terrestrial planets by establishing the major chemical reservoirs of the iron core and silicate mantle, chemical stratification within the mantle, and outgassed atmosphere. Furthermore, current and future exoplanet observations will favour the detection and characterisation of hot and warm planets, potentially with large outgassed atmospheres. In this study, we highlight the potential to combine models of coupled interior&#8211;atmosphere evolution with static structure calculations and modelled atmospheric spectra (transmission and emission). By combining these components in a common modelling framework, we acknowledge planets as dynamic entities and leverage their evolution to bridge planet formation, interior-atmosphere interaction, and observations.</p>
<p>An interior&#8211;atmosphere model is combined with static structure calculations to track the evolving radius of a hot rocky mantle that is outgassing volatiles. We consider oxidised species CO2 and H2O and generate synthetic emission and transmission spectra for CO2 and H2O dominated atmospheres. Atmospheres dominated by CO2 suppress the outgassing of H2O to a greater extent than previously realised, since previous studies have applied an erroneous relationship between volatile mass and partial pressure. Furthermore, formation of a lid at the surface can tie the outgassing of H2O to the efficiency of heat transport through the lid, rather than the radiative timescale of the atmosphere. We extend this work to explore the speciation of a primary atmosphere that is constrained using meteoritic materials as proxies for the planetary building blocks, and find that a range of reducing and oxidising atmospheres are possible.</p>
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<p>Our results demonstrate that a hot molten planet can have a radius several percent larger (about 5%, assuming Earth-like core size) than its equivalent solid counterpart, which may explain the larger radii of some close-in exoplanets. Outgassing of a low molar mass species (such as H2O, compared to CO2) can combat the continual contraction of a planetary mantle and even marginally increase the planetary radius. We further use our models to generate synthetic transmission and emission data to aid in the detection and characterisation of rocky planets via transits and secondary eclipses. Atmospheres of terrestrial planets around M-stars that are dominated by CO2 versus H2O could be distinguished by future observing facilities that have extended wavelength coverage (e.g., JWST). Incomplete magma ocean crystallisation, as may be the case for close-in terrestrial planets, or full or part retention of an early outgassed atmosphere, should be considered in the interpretation of observational data from current and future observing facilities.</p>
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Water Partitioning in Planetary Embryos and Protoplanets with Magma Oceans
