The Economic Impact of Climate Change on the Agricultural System in Fiji

Climate change is one of the most crucial challenges identified in this century for the Pacific Region, such as Fiji, Samoa, Solomon Islands and many more. Citizens of Fiji have gone through peculiarly climatic and weather conditions over the past years like globalization, which had led to many consequences, especially in the agricultural sector which is the main income of many livelihoods not only in Fiji but in other Pacific countries as well. Climatic conditions have been changing adversely from past decades, such as temperature, rise in the sea level, precipitation changes, atmospheric composition changes, flooding, and tropical cyclones. These changes have led to alterations in the environment, thus, affecting crop and livestock production in the agricultural system. For instance, crops that require specific soil and temperature situations are vastly influenced when the temperature level changes suddenly, making the crops vulnerable to adapt to the alterations and therefore, the crops eventually die. Likewise, animal species also get affected by temperature changes, such as heat stress which specifically affects the fertility of male and female livestock. Due to these events, Fiji’s economies have also been affected since agriculture plays a vital role in boosting our economy through local market sales and exporting. Thereby, this review illustrates the impacts of climate change and ways to move forward/ solutions, for example, FAO (Food and Agriculture Organization) and Pacific Islands Climate Change Assistance Program (PICCAP) have supported Fiji in bringing adaptation programs for preparing farmers and all other individuals on the upcoming climatic conditions such as adapting tolerant crops that can handle droughts and other adverse weather conditions.

CASPA-ADM: a mission concept for observing thermospheric mass density

Cold Atom technology has undergone rapid development in recent years and has been demonstrated in space in the form of cold atom scientific experiments and technology demonstrators, but has so far not been used as the fundamental sensor technology in a science mission. The European Space Agency therefore funded a 7-month project to define the CASPA-ADM mission concept, which serves to demonstrate cold-atom interferometer (CAI) accelerometer technology in space. To make the mission concept useful beyond the technology demonstration, it aims at providing observations of thermosphere mass density in the altitude region of 300–400 km, which is presently not well covered with observations by other missions. The goal for the accuracy of the thermosphere density observations is 1% of the signal, which will enable the study of gas–surface interactions as well as the observation of atmospheric waves. To reach this accuracy, the CAI accelerometer is complemented with a neutral mass spectrometer, ram wind sensor, and a star sensor. The neutral mass spectrometer data is considered valuable on its own since the last measurements of atmospheric composition and temperature in the targeted altitude range date back to 1980s. A multi-frequency GNSS receiver provides not only precise positions, but also thermosphere density observations with a lower resolution along the orbit, which can be used to validate the CAI accelerometer measurements. In this paper, we provide an overview of the mission concept and its objectives, the orbit selection, and derive first requirements for the scientific payload.

Estimation of mechanistic parameters in the gas-phase reactions of ozone with alkenes for use in automated mechanism construction

Reaction with ozone is an important atmospheric removal process for alkenes. The ozonolysis reaction produces carbonyls, and carbonyl oxides (Criegee intermediates, CI), which can rapidly decompose to yield a range of closed shell and radical products, including OH radicals. Consequently, it is essential to accurately represent the complex chemistry of Criegee intermediates in atmospheric models in order to fully understand the impact of alkene ozonolysis on atmospheric composition. A mechanism construction protocol is presented which is suitable for use in automatic mechanism generation. The protocol defines the critical parameters for describing the chemistry following the initial reaction, namely: the primary carbonyl / CI yields from the primary ozonide fragmentation; the amount of stabilisation of the excited CI (CI*); the unimolecular decomposition pathways, rates and products of the CI; the bimolecular rates and products of atmospherically important reactions of the stabilised CI (SCI). This analysis implicitly predicts the yield of OH from the alkene-ozone reaction. A comprehensive database of experimental OH, SCI and carbonyl yields has been collated using reported values in the literature and used to assess the reliability of the protocol. The protocol provides estimates OH, SCI and carbonyl yields with a root mean square error of 0.13 and 0.12 and 0.14, respectively. Areas where new experimental and theoretical data would improve the protocol and its assessment are identified and discussed.

Linking chemical composition and optical properties of biomass burning aerosols in Amazonia

Biomass burning emissions in Amazonia changes the atmospheric composition and aerosol properties during the dry season. We investigated fine-mode aerosol chemical composition and optical properties at an intensive field experiment...

Key challenges for tropospheric chemistry in the Southern Hemisphere

This commentary paper from the recently formed International Global Atmospheric Chemistry (IGAC) Southern Hemisphere Working Group outlines key issues in atmospheric composition research that particularly impact the Southern Hemisphere. In this article, we present a broad overview of many of the challenges for understanding atmospheric chemistry in the Southern Hemisphere, before focusing in on the most significant factors that differentiate it from the Northern Hemisphere. We present sections on the importance of biogenic emissions and fires in the Southern Hemisphere, showing that these emissions often dominate over anthropogenic emissions in many regions. We then describe how these and other factors influence air quality in different parts of the Southern Hemisphere. Finally, we describe the key role of the Southern Ocean in influencing atmospheric chemistry and conclude with a description of the aims and scope of the newly formed IGAC Southern Hemisphere Working Group.

Ground Validation Experiment and Spectral Detection Capability Evaluation of Mars Mineralogical Spectrometer (MMS) Aboard HX-1 Orbiter

As a hyperspectral imager aboard the orbiter “HX-1” of China’s first Mars mission, the Mars Mineralogical Spectrometer (MMS) is designed with hyperspectral and multispectral operation modes to survey the mineral types and their distribution on the surface of Mars, and to study the overall chemical composition and evolution history of Mars. The multispectral modes of MMS are different from hyperspectral modes on the bands selection, spatial and spectral resolution, Signal-to-Noise Ratio (SNR) etc. So the spectral detection capability of each mode of MMS is also different. The ground validation experiment of MMS is conducted to evaluate the hyperspectral and multispectral data quality and detection capabilities. The main conclusions include: (1) The measured hyperspectra of typical mineral samples obtained by MMS agree well with the data acquired by the Standard Comparison Spectrometers (SCS) under the same measurement conditions, and the spectral uncertainty between MMS and SCS is less than 7% in the key spectral ranges ($0.7\sim2.2~\upmu \text{m}$ 0.7 ∼ 2.2 μm ). For some typical minerals, the absorption band positions deviation between MMS and SCS are within $0.69\sim14.86~\text{nm}$ 0.69 ∼ 14.86 nm , which are within the spectral resolution limits of MMS. (2) The six sets of band combinations designed for MMS multispectral modes are slightly superior to CRISM’s multispectral mode in terms of spectral resolutions and bands selection, the water-containing minerals will be more accurately distinguished and identified, such as montmorillonite and kaolinite. Besides, the SNR of each multispectral mode is greater than 400 in the 500–2600 nm spectral range, which meets the requirements for the subtle spectral characteristics of water-containing minerals. (3) Benefiting from the MMS ground validation experiment and the experience of the OMEGA and CRISM, it is recommended that MMS first adopt the spatial continuous 52-sample or 104-sample (spatial resolution is about $0.53\sim1.06~\text{km}$ 0.53 ∼ 1.06 km ) multispectral operation mode for typical minerals global mapping and finding target areas of interest. Then the 208-sample multispectral mode (spatial resolution is about $\sim265~\text{m}$ ∼ 265 m ) or 26-sample hyperspectral mode can be used to survey target areas of interest for the subtle mineral types characteristics and distribution. At last, 26-sample hyperspectral mode could be used to monitor the atmospheric composition of Mars by limb observations.

Reactive species from aviation in the multi-scale climate-chemistry model system MECO(n)

<p>Aviation aims to reduce its climate impact by identifying promising mitigation options which are able to reduce the overall climate effects of aviation considering CO<sub>2</sub> and non-CO<sub>2</sub> effects. While aiming to identify fuel optimal trajectories, aviation also aims to reduce the non-CO<sub>2</sub> effects comprising NO<sub>x</sub>-induced changes of atmospheric ozone and methane. Here climate-chemistry models are required which are able to quantify perturbations in atmospheric composition of reactive species (NO<sub>x</sub>, O<sub>3</sub>) and the associated radiative forcings of aviation emissions relying on advanced modelling capabilities, realistic emission inventory data and global-scale observational datasets from research infrastructures like IAGOS and DLR aircraft measurement campaign data.</p> <p>We use the multi-scale climate-chemistry MECO(n) system which is a “MESSy-fied ECHAM and COSMO nested n-times”, relying on the Modular Earth Submodel System (MESSy) framework. For this purpose, both models have been equipped with the MESSy infrastructure, implying that the same process formulations (MESSy submodels) are available for both models. Modelled atmospheric distributions are systematically compared to observational data from aircraft measurements in the upper troposphere and lower stratosphere. Nudging of meteorology to ERA5 interim data, and special diagnostics available within the modular MESSy infrastructure are implemented in the numerical simulations. Online sampling along aircraft trajectories allows to extract model data with a high temporal resolution (MESSy submodel S4D), in order to evaluate model representation and key processes.</p> <p>Beyond systematic evaluation with IAGOS scheduled aircraft measurements, episodes will be evaluated where dedicated measurements from aircraft campaigns are available, comprising Spring 2014 (ML-CIRRUS campaign), early summer 2020 (Blue Sky campaign) and summer 2021 (Cirrus-HL campaign). Our analysis of reactive species, NO<sub>y</sub> and ozone, identifies those weather pattern and synoptic situations where aviation contributes strong signals, resulting in recommendations on measurement strategies to detect aviation signal in the atmosphere. We evaluate model representation of the NO<sub>x</sub>-induces effect on radiatively active species ozone and methane in both model instances, ECHAM5 and COSMO. This is key for advancing the scientific understanding of NO<sub>x</sub>-induced effects from aviation which is required in order to quantify potential compensation and trade-offs when identifying robust mitigation options for sustainable aviation.</p> <p>This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 875036 (ACACIA, Advancing the Science for Aviation and Climate) and has been supported by the DLR-Projekt Eco2Fly. This work uses measurement data from the European Research Infrastructure IAGOS/CARIBIC. High-Performance Super Computing simulations have been performed by the Deutsches Klima-Rechenzentrum (DKRZ, Hamburg) and the Leibniz-Rechenzentrum (LRZ, München).</p>

Source identification of aerosol chemical composition in the Atlas region of North Africa.

<p>Aerosol particles are important constituents of the atmosphere due to their role in controlling climate-related processes. In addition, their impacts on air quality and human health make it essential to study. However, the characterization and the identification of natural and anthropogenic atmospheric particles can be challenging due to the complex mixture occurring during atmospheric transport. Background locations such as high-altitude sites provide valuable infrastructure for obtaining representative data for understanding various pathways for aerosol interactions useful in assessing atmospheric composition. However, information about aerosol characteristics at high-altitude in the African regions and their relation to urban aerosol composition is still not well understood. In the present study, PM<sub>10</sub> and PM<sub>2.5</sub> particulate matter was characterized at two different sites in the North African region of Morocco. A background site located at the newly established AM5 research station in the Middle Atlas region at an altitude of 2100 m and an urban site situated in a polluted city, Fez. The goal was to determine chemical components, evaluate Saharan dust’s role on the PM10 concentrations between the sites, and assess the impact of urban pollution on background aerosol composition. The results indicate that the background aerosol composition is influenced by both regional and trans-regional transport. Despite the site's proximity to the Sahara Desert, the deserts influence on the atmospheric composition was observed for only 22% of the time and this was mainly seasonal. Marine air masses were more dominant with a mixture of sea salt and polluted aerosol from the coastal regions especially during wintertime. Furthermore, high concentrations of mineral dust were observed during the daytime due to the resuspension of road dust. At the same time, an increase of PAHs and anthropogenic metals such as Pb, Ni, and Cu were found during the nighttime because of the boundary layer variation. The Fez's urban site is characterized by a high contribution of elemental carbon (6%) and organic biomass tracers (3%) such as Levoglucosane and 4-nitrophenol.</p>

ARISE - Atmospheric Dynamics Research InfraStructure in Europe

<p>The Atmospheric dynamics Research InfraStructure in Europe (ARISE) project has integrated different meteorological and geophysical station networks and technologies providing observations from the ground to the lower thermosphere. A particular emphasis is on improving observations in the middle atmosphere, as this is a crucial region affecting tropospheric weather and climate. Besides supporting innovative prototypes of mobile lidars and microwave radiometers, ARISE utilized the global infrasound network developed for the Comprehensive Nuclear-Test-Ban Treaty (CTBT) verification, the lidar Network for the Detection of Atmospheric Composition Change (NDACC), meteor radars, wind radiometers, ionospheric sounders and satellites.</p> <p>This presentation highlights the objectives and results as well as perspectives of the first two project phases – one within the European Union’s 7th Framework Programme and the second within the Horizon 2020 programme. ARISE has facilitated multi-instrument stations and collocated measurement campaigns at different latitudes in Europe, including the observatories ALOMAR in northern Norway, OHP in southern France and Maïdo on Reunion Island (France), as well as the infrasound station in southern Germany. One ARISE study, for instance, analyzed different ground-based and space-borne observation technologies, revealing systematic biases for temperature and wind in both analysis and reanalysis models. Such biases are critical to the CTBT verification when validating infrasound signal detections by propagation modelling. Also, the potential of infrasound to be assimilated in weather or climate models was proposed, as infrasound can be used to probe winds and cross-wind effects in the middle atmosphere. Meanwhile, offline assimilation tests relying on infrasound data from ground-truth explosion events and wind data of ECMWF’s ERA5 model have been conducted. Overall, the interest of ARISE is to provide atmospheric data products and services for both scientific and civilian-security applications, including the monitoring of extreme events that have an atmospheric signature, such as meteors, thunderstorms or volcanic eruptions. For early warnings on volcanic eruptions, the Volcano Information System (VIS) was proposed as an ARISE product in cooperation with the CTBT organization and the Toulouse Volcanic Ash Advisory Center (VAAC).</p>