Biodiesel production assisted by 4-allyl-4-methylmorpholin-4-ium bromine ionic liquid and a microwave heating system

2013 ◽  
Vol 61 (2) ◽  
pp. 570-576 ◽  
Author(s):  
Yuan-Chung Lin ◽  
Po-Ming Yang ◽  
Shang-Cyuan Chen ◽  
Yao-Ting Tu ◽  
Jia-Fang Lin
Author(s):  
Prima Astuti Handayani ◽  
Abdullah Abdullah ◽  
Hadiyanto Hadiyanto

Nyamplung (Calophyllum inophyllum) is a typical Indonesian plant. Its seed contains abundant inedible oil, and therefore it is potential for biodiesel feedstock. The current issues of biodiesel are longer  reaction time of oil to biodiesel through transesterification reaction and lower biodiesel yield due to ineffective use of a homogenous catalyst. This work was aimed to use an ionic liquid as a catalyst and equipped with microwave heating as the heating system in order to increase the biodiesel yield and accelerate the process. Effects of the catalyst concentration and power of microwave irradiation to the biodiesel yield were studied. The ionic liquid of 1-butyl-3-methylimidazolium hydrogen sulfate (BMIMHSO4) was used as a catalyst. The results showed that the highest biodiesel yield was achieved of 92.81% which was catalyzed by IL0.5NaOH0.5 (0.5 wt.% (BMIMHSO4) + 0.5 wt.% NaOH) with a methanol-to-oil molar ratio of 9, a reaction time of 6 minutes, and the microwave temperature was 60 °C. Copyright © 2017 BCREC Group. All rights reservedReceived: 21st November 2016; Revised: 7th March 2017; Accepted: 9th March 2017How to Cite: Handayani, P.A., Abdullah, A., Hadiyanto, H. (2017). Biodiesel Production from Nyamplung (Calophyllum inophyllum) Oil using Ionic Liquid as A Catalyst and Microwave Heating System. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (2): 293-298 (doi:10.9767/bcrec.12.2.807.293-298)Permalink/DOI: http://dx.doi.org/10.9767/bcrec.12.2.807.293-298 


Catalysts ◽  
2018 ◽  
Vol 8 (2) ◽  
pp. 81 ◽  
Author(s):  
Yen-Ping Peng ◽  
Kassian Amesho ◽  
Chin-En Chen ◽  
Syu-Ruei Jhang ◽  
Feng-Chih Chou ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 30
Author(s):  
Han Lee ◽  
Wen-Hao Wu ◽  
Bing-Hung Chen ◽  
Jiunn-Der Liao

Strontium oxide (SrO) is an effective catalyst for transesterification. SrO powder that is firmly deposited onto a light titanium plate (TiO2_P), denoted as SrO/TiO2_P, can be reinforced by forming strontium titanate (SrTiO3) at the interface. Exposed SrO agglomerates can promote subsequent continuous transesterification process. In this work, conversion efficiency and production of biodiesel from olive oil on SrO/TiO2_P is investigated. The as-designed SrO/TiO2_P was followed by dip-coating and heat treatment. The physical properties of SrO/TiO2_P were verified through ASTM D3359; the chemical structures before and after transesterification, were respectively identified by X-ray photoelectron spectroscopy and Raman spectroscopy. A focused microwave heating system was utilized for transesterification. In the optimized sample SrO/TiO2_P (x) (x = 0.5 M), SrO firmly bonds with TiO2_P and forms the SrTiO3 structure. With the support of TiO2_P, the tested oil with SrO agglomerates subsequently reacts with SrO under microwave heating. The biodiesel conversion rate reaches 87.7% after a reaction time of 4 min, while the biodiesel product has an average of 39.37 MJ/kg of combustion heat and less than 1 vol% of water content. The as-designed SrO/TiO2_P (0.5) thus has great potential for biodiesel production and is promising with high stability in particular for a continuous fluid flow system.


Author(s):  
Yuan-Chung Lin ◽  
Shang-Cyuan Chen ◽  
Tzi-Yi Wu ◽  
Po-Ming Yang ◽  
Syu-Ruei Jhang ◽  
...  

2016 ◽  
Vol 20 (7) ◽  
pp. 752-760 ◽  
Author(s):  
Pingbo Zhang ◽  
Hui Liu ◽  
Mingming Fan ◽  
Yanlei Liu ◽  
Jianglei Huang

2013 ◽  
Vol 108 ◽  
pp. 333-339 ◽  
Author(s):  
Mingming Fan ◽  
Jianglei Huang ◽  
Jing Yang ◽  
Pingbo Zhang

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