Modulation of refractive index and thickness of poly(methyl methacrylate) thin films with UV irradiation and heat treatment

2005 ◽  
Vol 252 (5) ◽  
pp. 1283-1292 ◽  
Author(s):  
JianMing Yu ◽  
XiaoMing Tao ◽  
HwaYaw Tam ◽  
M. Suleyman Demokan
Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1348
Author(s):  
Hiroki Nagai ◽  
Naoki Ogawa ◽  
Mitsunobu Sato

Deep-ultraviolet (DUV) light-transparent conductive composite thin films, consisting of dispersed multiwalled carbon nanotubes (MWCNTs) and SiO2 matrix composites, were fabricated on a quartz glass substrate. Transparent and well-adhered amorphous thin films, with a thickness of 220 nm, were obtained by weak ultraviolet (UV) irradiation (4 mW cm−2 at 254 nm) for more than 6 h at 20−40 °C onto the precursor films, which were obtained by spin coating with a mixed solution of MWCNT in water and Si(IV) complex in ethanol. The electrical resistivity of MWCNT/SiO2 composite thin film is 0.7 Ω·cm, and transmittance in the wavelength region from DUV to visible light is higher than 80%. The MWCNT/SiO2 composite thin film showed scratch resistance at pencil hardness of 8H. Importantly, the resistivity of the MWCNT/SiO2 composite thin film was maintained at the original level even after heat treatment at 500 °C for 1 h. It was observed that the heat treatment of the composite thin film improved durability against both aqueous solutions involving a strong acid (HCl) and a strong base (NaOH).


1997 ◽  
Vol 501 ◽  
Author(s):  
Naohisa Yanagihara ◽  
Kazutaka Uchida ◽  
Muyuki Wakabayashi ◽  
Toru Hara

ABSTRACTSolid sol of silver in poly(methyl methacrylate), Ag/PMMA, was prepared by bulk polymerization of methyl methacrylate solution of silver (I) triflluoroacetate (AgTfa) and followed by postheating. The formation of the metallic Ag nanocluster was characterized by visible spectroscopy, and effects of the concentrations of AIBN and AgTfa and the heat-treatment duration on the formation of Ag cluster were investigated. Furthermore, based on the kinetic study of MMA in the presence of AgTfa, possible mechanism for the reduction and agglomeration of silver is proposed.


2015 ◽  
Vol 340 ◽  
pp. 72-77 ◽  
Author(s):  
S. Zongo ◽  
A.P. Kerasidou ◽  
B.T. Sone ◽  
A. Diallo ◽  
P. Mthunzi ◽  
...  

1999 ◽  
Vol 81 (4) ◽  
pp. 285-291 ◽  
Author(s):  
Jinman Huang ◽  
Vlasoula Bekiari ◽  
Panagiotis Lianos ◽  
Stelios Couris

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