Alkali metal doping and energy level shift in organic semiconductors

2006 ◽  
Vol 252 (11) ◽  
pp. 3943-3947 ◽  
Author(s):  
Huanjun Ding ◽  
Yongli Gao
2007 ◽  
Vol 06 (02) ◽  
pp. 125-129 ◽  
Author(s):  
HUANJUN DING ◽  
YONGLI GAO

We have investigated the electronic structure of the interface formed by depositing Au on Cs -doped and Na -doped tris(8-hydroxyquinoline) aluminum (Alq) film using ultraviolet and X-ray photoemission spectroscopy (UPS and XPS). The initial Au deposition quenches the Al q gap state caused by the alkali metal doping. Further Au depositions shift gradually the energy levels opposite to that induced by Cs doping, especially the highest occupied molecular orbital (HOMO) that shows approximately full recovery to the pristine Al q position. However, the recovery is only partial for other levels, most noticeably the C 1s core level. The results indicate that the gap state and energy level positions can be decoupled in the organic semiconductors, and that it is possible to fine tune the electronic structure by selective doping in the interface region.


2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Xiaoxia Duan ◽  
Lixin Yi ◽  
Xiqing Zhang ◽  
Shihua Huang

Nanoscale long persistent phosphor SrAl2O4:Eu2+, Dy3+was prepared by autocombustion of citrate gel. The energy level shift of activator Eu2+and coactivator Dy3+was analyzed according to the emission and the excitation spectra. The band gap change of SrAl2O4and the resulting trap depth change with particle size were discussed on the basis of analyzing the visible spectra, the vacuum ultraviolet (VUV) excitation spectra, and the thermoluminescence (TL) spectra. The fluorescence quenching and the shallow traps originating from surface adsorption or surface defects explain the weak initial persistent phosphorescence and the fast phosphorescence decay in nanometer SrAl2O4:Eu2+, Dy3+. It is confirmed that energy level, band gap, trap depth, defect, and surface adsorption are deeply related with each other in this nanoscale long persistent phosphor.


2006 ◽  
Vol 73 (3) ◽  
Author(s):  
A. N. Ivanov ◽  
M. Faber ◽  
V. A. Ivanova ◽  
J. Marton ◽  
N. I. Troitskaya

2003 ◽  
Vol 380 (3-4) ◽  
pp. 451-455 ◽  
Author(s):  
Yongli Gao ◽  
Li Yan

1989 ◽  
Vol 142 (8-9) ◽  
pp. 511-513 ◽  
Author(s):  
V.V. Dodonov ◽  
A.B. Klimov ◽  
V.I. Man'ko

2012 ◽  
Vol 81 (10) ◽  
pp. 104301 ◽  
Author(s):  
Zhonghua Ji ◽  
Yanting Zhao ◽  
Jie Ma ◽  
Liantuan Xiao ◽  
Suotang Jia

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