Heteroepitaxial growth on the air-solid interface: A large matching tolerance between nonpolar organic molecules on polar inorganic substrates

2020 ◽  
Vol 521 ◽  
pp. 146394
Author(s):  
Mingxia Yuan ◽  
Ming Yuan ◽  
Zhi Zhu ◽  
Bo Song ◽  
Feng Zhang
Keyword(s):  
Organic Molecules ◽  
Heteroepitaxial Growth ◽  
Solid Interface ◽  
Inorganic Substrates ◽  
Nonpolar Organic

2D Co-crystallization of molecular homologues promoted by size complementarity of the alkyl chains at the liquid/solid interface

2019 ◽  
Vol 21 (32) ◽  
pp. 17846-17851 ◽  
Author(s):  
Shu-Ying Li ◽  
Xue-Qing Yang ◽  
Ting Chen ◽  
Dong Wang ◽  
Guang-Shan Zhu ◽  
...  
Keyword(s):  
Organic Molecules ◽  
Molecular Materials ◽  
Alkyl Chains ◽  
Solid Interface

Co-crystallization of organic molecules is an important strategy for the fabrication of molecular materials.

Relation between van der Waals and Partial Molal Volumes of Organic Molecules in Water

1975 ◽  
Vol 53 (19) ◽  
pp. 2965-2970 ◽  
Author(s):  
John T. Edward ◽  
Patrick G. Farrell
Keyword(s):  
Organic Molecules ◽  
Van Der Waals ◽  
Polar Compounds ◽  
Total Surface Area ◽  
Polar Group ◽  
Partial Molal Volumes ◽  
Aliphatic Carbon ◽  
Urea Group ◽  
Molal Volumes ◽  
Nonpolar Organic

The partial molal volumes [Formula: see text] of nonpolar organic molecules (i.e. those having more than three aliphatic carbon atoms per polar hydroxyl, ether, amine, amide, or urea group) in water at 25 °C are given by their van der Waals volumes υw plus the additional empty volume provided by an enclosing shell 0.53 Å thick. An equation relates [Formula: see text] to υw More polar compounds (i.e. those having fewer than two or three aliphatic carbon atoms per polar group) have [Formula: see text] smaller than calculated by the equation; the shrinkage in [Formula: see text] from that computed is linearly related to the fraction of the total surface area of the molecule occupied by the polar group.

scholarly journals Polarization Reversal in AlPO4-5 Crystals Containing Polar or Nonpolar Organic Molecules:  A Scanning Pyroelectric Microscopy Study

1998 ◽  
Vol 102 (47) ◽  
pp. 9518-9524 ◽  
Author(s):  
G. J. Klap ◽  
S. M. van Klooster ◽  
M. Wübbenhorst ◽  
J. C. Jansen ◽  
H. van Bekkum ◽  
...  
Keyword(s):  
Organic Molecules ◽  
Microscopy Study ◽  
Polarization Reversal ◽  
Nonpolar Organic

Supramolecular Chemistry at the Liquid/Solid Interface a Scanning Tunneling Microscopy Approach

2007 ◽  
Vol 121-123 ◽  
pp. 369-372
Author(s):  
S. de Feyter ◽  
A. Miura ◽  
H. Uji-i ◽  
P. Jonkheijm ◽  
A.P.H.J. Schenning ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Scanning Tunneling Microscopy ◽  
Supramolecular Chemistry ◽  
Organic Molecules ◽  
Molecular Conformation ◽  
Scanning Tunneling ◽  
Conjugated Oligomers ◽  
Two Dimensional ◽  
Tunneling Microscopy ◽  
Solid Interface

With scanning tunneling microscopy (STM), the intramolecular conformational and intermolecular ordering aspects have been investigated of a variety of organic molecules physisorbed at the liquid-solid interface. By balancing the interplay between intramolecular and intermolecular interactions (hydrogen bonding), leading to control of the molecular conformation, foldamers were created which order into well-defined two-dimensional crystals. The nature of the hydrogen bonding groups in conjugated oligomers leads to the formation of infinite stacks and cyclic multimers, expressing the chiral nature of the molecules.

scholarly journals Erratum: Ferroelectricity near room temperature in co-crystals of nonpolar organic molecules

2008 ◽  
Vol 7 (11) ◽  
pp. 922-922 ◽  
Author(s):  
Sachio Horiuchi ◽  
Fumiyuki Ishii ◽  
Reiji Kumai ◽  
Yoichi Okimoto ◽  
Hiroaki Tachibana ◽  
...  
Keyword(s):  
Room Temperature ◽  
Organic Molecules ◽  
Nonpolar Organic

STM Investigations of Organic Molecules Physisorbed at the Liquid−Solid Interface

1996 ◽  
Vol 8 (8) ◽  
pp. 1600-1615 ◽  
Author(s):  
Donna M. Cyr ◽  
Bhawani Venkataraman ◽  
George W. Flynn
Keyword(s):  
Organic Molecules ◽  
Solid Interface

Ferroelectricity near room temperature in co-crystals of nonpolar organic molecules

2005 ◽  
Vol 4 (2) ◽  
pp. 163-166 ◽  
Author(s):  
Sachio Horiuchi ◽  
Fumiyuki Ishii ◽  
Reiji Kumai ◽  
Yoichi Okimoto ◽  
Hiroaki Tachibana ◽  
...  
Keyword(s):  
Room Temperature ◽  
Organic Molecules ◽  
Nonpolar Organic

The epitaxial growth of lead phthalocyanine on copper halogen compounds as the origin of templating effects

2014 ◽  
Vol 2 (23) ◽  
pp. 8730-8735 ◽  
Author(s):  
Tae-Min Kim ◽  
Hyo Jung Kim ◽  
Hyun-Sub Shim ◽  
Min-Soo Choi ◽  
Ji Whan Kim ◽  
...  
Keyword(s):  
Epitaxial Growth ◽  
Organic Molecules ◽  
Heteroepitaxial Growth ◽  
Halogen Compounds ◽  
Effect Of Copper ◽  
Templating Effect

The templating effect of copper halogen compounds on the growth of lead phthalocyanine was described by heteroepitaxial growth of organic molecules on the templating layers.

Functional Group Adsorption on Calcite: I. Oxygen Containing and Nonpolar Organic Molecules

2016 ◽  
Vol 120 (30) ◽  
pp. 16586-16596 ◽  
Author(s):  
E. Ataman ◽  
M. P. Andersson ◽  
M. Ceccato ◽  
N. Bovet ◽  
S. L. S. Stipp
Keyword(s):  
Organic Molecules ◽  
Functional Group ◽  
Nonpolar Organic
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