Iron and Nitrogen doped Carbon derived from Ferrocene and ZIF-8 as Proton Exchange Membrane Fuel Cell Cathode Catalyst

2021 ◽  
pp. 151607
Author(s):  
Jinchang Xu ◽  
Guofeng Liang ◽  
Di Chen ◽  
Zilong Li ◽  
Hao Zhang ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Cathode Catalyst ◽  
Nitrogen Doped ◽  
Fuel Cell Cathode ◽  
Nitrogen Doped Carbon ◽  
Exchange Membrane ◽  
Cell Cathode

scholarly journals MOF Derived Catalysts for Oxygen Reduction Reaction in Proton Exchange Membrane Fuel Cell

2018 ◽  
Vol 778 ◽  
pp. 275-282
Author(s):  
Noaman Khan ◽  
Saim Saher ◽  
Xuan Shi ◽  
Muhammad Noman ◽  
Mujahid Wasim Durani ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Membrane Electrode Assembly ◽  
Reduction Reaction ◽  
Proton Exchange ◽  
Membrane Electrode ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon ◽  
Exchange Membrane

Highly porous ZIF-67 (Zeolitic imidazole framework) has a conductive crystalline metal organic framework (MOF) structure which was served as a precursor and template for the preparation of nitrogen-doped carbon nanotubes (NCNTs) electrocatalysts. As a first step, the chloroplatinic acid, a platinum (Pt) precursor was infiltrated in ZIF-67 with a precise amount to obtain 0.12 mg.cm-2 Pt loading. Later, the infiltrated structure was calcined at 700°C in Ar:H2 (90:10 vol%) gas mixture. Multi-walled nitrogen-doped carbon nanotubes were grown on the surface of ZIF-67 crystals following thermal activation at 700°C. The resulting PtCo-NCNTs electrocatalysts were deposited on Nafion-212 solid electrolyte membrane by spray technique to study the oxygen reduction reaction (ORR) in the presence of H2/O2 gases in a temperature range of 50-70°C. The present study elucidates the performance of nitrogen-doped carbon nanotubes ORR electrocatalysts derived from ZIF-67 and the effects of membrane electrode assembly (MEA) steaming on the performance of proton exchange membrane fuel cell (PEMFC) employing PtCo-NCNTs as ORR electrocatalysts. We observed that the peak power density at 70°C was 450 mW/cm2 for steamed membrane electrode assembly (MEA) compared to 392 mW/cm2 for an identical MEA without steaming.

Liquid water flooding in a proton exchange membrane fuel cell cathode with an interdigitated design

2011 ◽  
Vol 35 (15) ◽  
pp. 1292-1311 ◽  
Author(s):  
Simo Kang ◽  
Biao Zhou ◽  
Chin-Hsiang Cheng ◽  
Huan-Ruei Shiu ◽  
Chun-I Lee
Keyword(s):  
Fuel Cell ◽  
Liquid Water ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Water Flooding ◽  
Fuel Cell Cathode ◽  
Exchange Membrane ◽  
Cell Cathode
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