Electro catalytic oxidation reactions for harvesting alternative energy over non noble metal oxides: Are we a step closer to sustainable energy solution?

Author(s):  
Preetha Chandrasekharan Meenu ◽  
Saraswati Roy ◽  
Chanchal Chakraborty ◽  
Sounak Roy
2005 ◽  
Vol 486-487 ◽  
pp. 530-533 ◽  
Author(s):  
Yamato Hayashi ◽  
Hirotsugu Takizawa ◽  
Yoshitaka Saijo ◽  
Tohru Sekino ◽  
Katsuaki Suganuma ◽  
...  

Applications of silver nano-sized metal particles were investigated for a new, ecologically friendly and economical liquid-solid (silver oxide-alcohol) system. Silver metal oxides as starting materials have merits in metal particles fabrication because these materials are decomposed only by heating in air. That is, noble metal oxide does not use thestrong reduction atmosphere. This reduction is ecologically clean because many noble metal oxides are not toxic, and because O2 is evolved during decomposition. We reduced silver metal oxides by ultrasound and fabricated silver nano metal nanoparticles at room temperature, and various applications were investigated. By choosing a suitable process and conditions, it is reasonable to expect that ultrasonic eco-fabrications can be extended to obtain various silver nano-particles containing materials.


2017 ◽  
Vol 62 (2) ◽  
pp. 1019-1022 ◽  
Author(s):  
Seong Ho Son ◽  
Sung Cheol Park ◽  
Man Seung Lee

Abstract In order to enhance the long-term stability of DSA for copper electroplating process, in the present study, noble metal oxides with excellent electrochemical properties was used and optimum condition was determined the ratio of noble metal oxides, surface pre-treatment of titanium substrate and heat treatment. The effect of the surface pretreatment of titanium substrate and ratio of noble metal oxides were estimated by accelerated test at the highly current density conditions. The lifetime of DSA increase six-fold higher as the oxide thickness of Ta 7 : Ir 3 composition ratio. Under the optimal condition, surface pretreatment led to dramatic increase in the lifetime of DSA.


2013 ◽  
Vol 78 (12) ◽  
pp. 2141-2164 ◽  
Author(s):  
Vladimir Panic ◽  
Aleksandar Dekanski ◽  
Branislav Nikolic

Porous electrochemical supercapacitive materials, as an important type of new-generation energy storage devices, require a detailed analysis and knowledge of their capacitive performances upon different charging/discharging regimes. The investigation of the responses to dynamic perturbations of typical representatives, noble metal oxides, carbonaceous materials and RuO2-impregnated carbon blacks, by electrochemical impedance spectroscopy (EIS) is presented. This presentation follows a brief description of supercapacitive behavior and origin of pseudocapacitive response of noble metal oxides. For all investigated materials, the electrical charging/discharging equivalent of the EIS response was found to obey the transmission line model envisaged as so-called ?resistor/capacitor (RC) ladder?. The ladder features are correlated to material physicochemical properties, its composition and the composition of the electrolyte. Fitting of the EIS data of different supercapacitive materials to appropriate RC ladders enables the in-depth profiling of the capacitance and pore resistance of their porous thin-layers and finally the complete revelation of capacitive energy storage issues.


1971 ◽  
Vol 10 (4) ◽  
pp. 713-718 ◽  
Author(s):  
Robert D. Shannon ◽  
Donald Burl Rogers ◽  
Charles T. Prewitt

CORROSION ◽  
1967 ◽  
Vol 23 (6) ◽  
pp. 151-153 ◽  
Author(s):  
RICHARD L. EVERY ◽  
WILLIAM P. BANKS

Abstract Several electrodes were screened for possible use as reference electrodes for anodic corrosion control systems. Mercury-mercury salts, noble metal-noble metal oxides and molybdenum-molybdenum oxide were examined extensively and found to be useful reference electrodes in sodium hydroxide and phosphoric acid. A chromium carbide electrode was found to be a useful reference electrode in sodium hydroxide. The emf of these electrodes as a function of concentration and of temperature is described. The emf behavior of the noble metal-noble metal oxides in chromic acid cleaning solution and the emf of stainless steel in nitric acid are described briefly.


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