NO removal in chemical absorption–biological reduction integrated system: Process rate and rate-limiting step

2013 ◽  
Vol 149 ◽  
pp. 184-190 ◽  
Author(s):  
Yin-Feng Xia ◽  
Bi-Hong Lu ◽  
Nan Liu ◽  
Qiao-Li Chen ◽  
Su-Jing Li ◽  
...  
2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Tianjiao Guo ◽  
Chunyan Zhang ◽  
Jingkai Zhao ◽  
Cunhao Ma ◽  
Sujing Li ◽  
...  

Abstract A Chemical absorption-bioelectrochemical reduction (CABER) system is based on Chemical absorption-biological reduction (CABR) system, which aims at NO removal and has been studied in many of our previous works. In this paper, we applied polypyrrole (PPy) on the electrode of bioelectrochemical reactor (BER) of CABER system, which induced a much higher current density in the cyclic voltammetry (CV) curve for the electrode itself and better NO removal rate in the system. In addition, a Microbial Electrolysis Cell (MEC) is constructed to study its strengthening mechanism. Results shows that PPy-MEC has a greater Faraday efficiency and higher reduction rate of Fe(III)EDTA and Fe(II)EDTA-NO in the solution when compared to original Carbon MEC, which confirms the advantage of PPy-modified electrode(s) in the CABER system. The results of this study are reported for illustration of potential of CABER technology and design of low-cost high-efficiency NOx control equipment in the future.


1978 ◽  
Vol 39 (02) ◽  
pp. 496-503 ◽  
Author(s):  
P A D’Amore ◽  
H B Hechtman ◽  
D Shepro

SummaryOrnithine decarboxylase (ODC) activity, the rate-limiting step in the synthesis of polyamines, can be demonstrated in cultured, bovine, aortic endothelial cells (EC). Serum, serotonin and thrombin produce a rise in ODC activity. The serotonin-induced ODC activity is significantly blocked by imipramine (10-5 M) or Lilly 11 0140 (10-6M). Preincubation of EC with these blockers together almost completely depresses the 5-HT-stimulated ODC activity. These observations suggest a manner by which platelets may maintain EC structural and metabolic soundness.


Diabetes ◽  
1993 ◽  
Vol 42 (2) ◽  
pp. 296-306 ◽  
Author(s):  
D. C. Bradley ◽  
R. A. Poulin ◽  
R. N. Bergman

1979 ◽  
Vol 44 (3) ◽  
pp. 912-917 ◽  
Author(s):  
Vladimír Macháček ◽  
Said A. El-bahai ◽  
Vojeslav Štěrba

Kinetics of formation of 2-imino-4-thiazolidone from S-ethoxycarbonylmethylisothiouronium chloride has been studied in aqueous buffers and dilute hydrochloric acid. The reaction is subject to general base catalysis, the β value being 0.65. Its rate limiting step consists in acid-catalyzed splitting off of ethoxide ion from dipolar tetrahedral intermediate. At pH < 2 formation of this intermediate becomes rate-limiting; rate constant of its formation is 2 . 104 s-1.


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