A parametric study of the large scale production of multi-walled carbon nanotubes by fluidized bed catalytic chemical vapor deposition

Carbon ◽  
2007 ◽  
Vol 45 (3) ◽  
pp. 624-635 ◽  
Author(s):  
Aurore Morançais ◽  
Brigitte Caussat ◽  
Yolande Kihn ◽  
Philippe Kalck ◽  
Dominique Plee ◽  
...  
2016 ◽  
Vol 852 ◽  
pp. 514-519 ◽  
Author(s):  
Xiao Gang Sun ◽  
Zhi Wen Qiu ◽  
Long Chen ◽  
Man Yuan Cai ◽  
Zhi Peng Pang ◽  
...  

Since the first observation of carbon nanotubes (CNTs) in 1991, their synthesis techniques has been extensively investigated. The chemical vapor deposition (CVD) process have attracted much attention because of both their versatility and easy large scale production for CNTs . This paper is focused on a catalytic CVD-based method for synthesis of whisker multiwalled carbon nanotubes (WMWCNTs). The new type of carbon nanotube is similar to the whisker. The morphology of the WMWCNTs are very different from traditional carbon nanotubes prepared by traditional chemical vapor deposition process. The traditional CNTs were twisted and entangled with each other. These suggested that there are a lot of deficiencies on the CNTs and are difficult to disperse in matrix materials. The as-produced WMWCNTs are very straight and not entangled with each other. The line structure means that WMWCNTs are easily dispersed in matrix materials than traditional CNTs which are twined together. The crystallinity of WMWCNTs increased to 96% which was much higher than traditional CNTs after graphitization treatment at 2800°C.


2007 ◽  
Vol 24 (2) ◽  
pp. 347-349 ◽  
Author(s):  
Jaehyeon Park ◽  
Dal Hee Bae ◽  
Seung Yong Lee ◽  
Jini Kwak ◽  
Hai Woong Park ◽  
...  

2010 ◽  
Vol 133 (3) ◽  
Author(s):  
Myung Gwan Hahm ◽  
Young-Kyun Kwon ◽  
Ahmed Busnaina ◽  
Yung Joon Jung

Due to their unique one-dimensional nanostructure along with excellent mechanical, electrical, and optical properties, carbon nanotubes (CNTs) become a promising material for diverse nanotechnology applications. However, large-scale and structure controlled synthesis of CNTs still have many difficulties due to the lack of understanding of the fundamental growth mechanism of CNTs, as well as the difficulty of controlling atomic-scale physical and chemical reactions during the nanotube growth process. Especially, controlling the number of graphene wall, diameter, and chirality of CNTs are the most important issues that need to be solved to harness the full potential of CNTs. Here we report the large-scale selective synthesis of vertically aligned single walled carbon nanotubes (SWNTs) and double walled carbon nanotubes (DWNTs) by controlling the size of catalyst nanoparticles in the highly effective oxygen assisted thermal chemical vapor deposition (CVD) process. We also demonstrate a simple but powerful strategy for synthesizing ultrahigh density and diameter selected vertically aligned SWNTs through the precise control of carbon flow during a thermal CVD process.


2008 ◽  
Vol 14 (S2) ◽  
pp. 304-305
Author(s):  
M Ellis ◽  
T Jutarosaga ◽  
S Smith ◽  
Y Wei ◽  
S Seraphin

Extended abstract of a paper presented at Microscopy and Microanalysis 2008 in Albuquerque, New Mexico, USA, August 3 – August 7, 2008


2006 ◽  
Vol 320 ◽  
pp. 163-166 ◽  
Author(s):  
Koji Yamada ◽  
Kentaro Abe ◽  
Masafumi Mikami ◽  
Morihiro Saito ◽  
Jun Kuwano

Multi-walled carbon nanotubes (MWCNTs) were synthesized from camphor by a chemical vapor deposition (CVD) method in a range of 750-900. The catalyst was fed in three ways: (a) a sputtered Fe-film on a quartz substrate (b) vaporized ferrocene in an Ar flow; (c) both of (a) and (b). In the case (c), highly pure, dense and aligned MWCNT arrays formed on the quartz substrate at 850, whereas nonaligned MWCNTs formed in the cases (a) and (b).


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