Soft-template synthesis of ordered mesoporous carbon/nanoparticle nickel composites with a high surface area

Carbon ◽  
2011 ◽  
Vol 49 (2) ◽  
pp. 545-555 ◽  
Author(s):  
Yunpu Zhai ◽  
Yuqian Dou ◽  
Xiaoxia Liu ◽  
Sung Soo Park ◽  
Chang-Sik Ha ◽  
...  
2018 ◽  
Vol 268 ◽  
pp. 162-169 ◽  
Author(s):  
Yan Xiong ◽  
Dong Gu ◽  
Xiaohui Deng ◽  
Harun Tüysüz ◽  
Maurice van Gastel ◽  
...  

2020 ◽  
Vol 21 (1) ◽  
pp. 77
Author(s):  
Putri Nurul Amalia ◽  
Iman Abdullah ◽  
Dyah Utami Cahyaning Rahayu ◽  
Yuni Krisyuningsih Krisnandi

Carbon dioxide (CO2) is a compound that can potentially be used as a carbon source in the synthesis of fine chemicals. However, the utilization of CO2 is still constrained due to its inert and stable nature. Therefore, the presence of a catalyst is needed in CO2 conversion. This study aims to synthesize copper impregnated mesoporous carbon (Cu/MC) as a catalyst for phenylacetylene carboxylation reaction with CO2 to produce phenylpropiolic acid. The synthesis of mesoporous carbon was performed via the soft template method. The as-synthesized Cu/MC material was characterized by FTIR, SAA, XRD, and SEM-EDX. BET surface area analysis of mesoporous carbon showed that the material has a high surface area of 405.8 m2/g with an average pore diameter of 7.2 nm. XRD pattern of Cu/MC indicates that Cu has been successfully impregnated in the form of Cu(0) and Cu(I). Phenylacetylene carboxylation reaction with CO2 was carried out by varying reaction temperatures (25, 50, and 75 °C), amount of catalyst (28.6, 57.2, and 85.8 mg), type of base (Cs2CO3, K2CO3, and Na2CO3), and variation of support. The reaction mixtures were analyzed by HPLC and showed that the highest phenylacetylene conversion of 41% was obtained for the reaction at 75 °C using Cs2CO3 as a base.


2018 ◽  
Vol 43 (1) ◽  
pp. 523-534 ◽  
Author(s):  
Prabhakaran Selvaraj ◽  
Anurag Roy ◽  
Habib Ullah ◽  
Parukuttyamma Sujatha Devi ◽  
Asif Ali Tahir ◽  
...  

2006 ◽  
Vol 11-12 ◽  
pp. 543-546 ◽  
Author(s):  
Chun Fu Lin ◽  
X. Zhang ◽  
Hong Lin ◽  
Ning Wang ◽  
Jian Bao Li ◽  
...  

Mesoporous carbon with high surface area and ordered structure was synthesized via a nanocasting process using mesoprous MCM-41 silica as a template and sucrose as a carbon precursor. Sample was characterized by XRD, SEM, TEM and nitrogen adsorption. The results show that the templated carbon has a BTE surface area ∼1200 m2/g, a pore volume ∼1.0 cm3/g, and a bimodal porosity centered at around 4 nm and 46 nm.


2013 ◽  
Vol 48 (22) ◽  
pp. 8003-8013 ◽  
Author(s):  
Pranav K. Tripathi ◽  
Mingxian Liu ◽  
Lihua Gan ◽  
Jiasheng Qian ◽  
Zijie Xu ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (45) ◽  
pp. 23853-23860 ◽  
Author(s):  
Pranav K. Tripathi ◽  
Mingxian Liu ◽  
Lihua Gan

High surface area ordered mesoporous carbons were fabricated as superior adsorbents for ultrahigh decontamination of di(2-ethylhexyl)phthalate from a model water pollutant.


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